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Magnesium acetate

CAS No.
142-72-3
Chemical Name:
Magnesium acetate
Synonyms
Nu-Mag;Cromosan;Cromosan*;Mg Acetate;MAGNESIUM ACETATE;MagnesiumAcetateBp;acetatedemagnesium;magnesiumdiacetate;Magnesium diacetate;MagnesiumAcetate>98%
CBNumber:
CB2160485
Molecular Formula:
C4H6MgO4
Molecular Weight:
142.39
MDL Number:
MFCD00003539
MOL File:
142-72-3.mol
MSDS File:
SDS
Last updated:2024-11-18 17:43:10

Magnesium acetate Properties

Melting point 72-75 °C(lit.)
Density 1.5000
refractive index n20/D 1.358
solubility H2O: 1 M at 20 °C, clear, colorless
pka 4.756[at 20 ℃]
form Liquid
color white orthorhombic/monoclinic crystals, crystalline
PH 7.95(1 mM solution);8.23(10 mM solution);8.41(100 mM solution);8.78(1000 mM solution)
Water Solubility Not miscible or difficult to mix with water.
λmax λ: 260 nm Amax: 0.04
λ: 280 nm Amax: 0.02
Merck 13,5676
BRN 3692530
Stability Stable. Incompatible with strong oxidizing agents. Avoid moisture.
InChIKey UEGPKNKPLBYCNK-UHFFFAOYSA-L
LogP -1.38
CAS DataBase Reference 142-72-3(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 0E95JZY48K
NIST Chemistry Reference Magnesium acetate(142-72-3)
EPA Substance Registry System Magnesium acetate (142-72-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H312-H226-H332
Precautionary statements  P280-P302+P352-P312-P322-P363-P501-P261-P271-P304+P340-P312
Safety Statements  22-24/25
WGK Germany  3
RTECS  AI5600000
3
TSCA  Yes

Magnesium acetate price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 63052 Magnesium acetate solution BioUltra, for molecular biology, ~1 M in H2O 142-72-3 100ml $129 2024-03-01 Buy
Sigma-Aldrich 63052 Magnesium acetate solution BioUltra, for molecular biology, ~1 M in H2O 142-72-3 500ml $464 2024-03-01 Buy
Alfa Aesar J60041 Magnesium acetate, 1M aq. soln. 142-72-3 50ml $57 2024-03-01 Buy
Alfa Aesar J60041 Magnesium acetate, 1M aq. soln. 142-72-3 100ml $84.1 2024-03-01 Buy
TRC M110468 MagnesiumAcetateAnhydrous 142-72-3 10g $60 2021-12-16 Buy
Product number Packaging Price Buy
63052 100ml $129 Buy
63052 500ml $464 Buy
J60041 50ml $57 Buy
J60041 100ml $84.1 Buy
M110468 10g $60 Buy

Magnesium acetate Chemical Properties,Uses,Production

Uses

Magnesium acetate is used in the manufacture of rayon fiber for cigarette filters; and as a fixative for dyes in textile printing. It also is used as an antiseptic and disinfectant.

Preparation

Magnesium acetate is prepared by treating magnesium oxide with acetic acid. Magnesium oxide reacts with concentrated acetic acid in boiling ethyl acetate to produce the alpha form of anhydrous magnesium acetate. The beta form is obtained by treating the oxide with 5–6% acetic acid. In slightly hydrated isobutyl alcohol medium the product is a monohydrate, Mg(OOCCH3)2•H2O. In aqueous solution magnesium acetate crystallizes as a tetrahydrate, the commercial product. The tetrahydrate dehydrates to anhydrous salt at 134°C.

Description

Anhydrous Magnesium Acetate has the chemical formula Mg(CH3COO)2 and in its hydrous form, Magnesium Acetate Tetrahydrate, it has the chemical formula Mg(CH3COO)2.4H2O. In this compound the magnesium metal has an oxidation state of 2+.
Anhydrous Magnesium Acetate
Magnesium acetate is the magnesium salt of acetic acid.It is deliquescent and upon heating, it decomposes to form magnesium oxide.Magnesium acetate is commonly used as a source of magnesium or as a chemical reagent.

Chemical Properties

Anhydrous magnesium acetate, a white, crystalline, deliquescent solid, occurs in two forms: α-Mg(C2H3O2)2, formed by the reaction of MgO and concentrated acetic acid (13–33%) in boiling ethyl acetate, an and β-Mg(C2H3O2)2 which is formed using 5–6% acetic acid.

Chemical Properties

white deliquescent crystals

Physical properties

Magnesium acetate appears as white hygroscopic crystals. It smells like acetic acid and is soluble in water. When it is in an aqueous solution its pH can be considered to be neutral.

Characteristics

In 1881 Charles Clamond invented the Clamond basket, one of the first effective gas mantles. The reagents used in this invention included magnesium acetate, magnesium hydroxide and water.
Magnesium acetate is commonly used as a source of magnesium or for the acetate ion in chemistry experiments. One example of this is when magnesium acetate and magnesium nitrate were both used to perform molecular dynamics simulations and surface tension measurements. In the experiment the authors found that the acetate had a stronger affinity for the surface compared to the nitrate ion and that the Mg2+ strongly repelled away from the air/liquid interference. They also found that the Mg2+ had a stronger tendency to bind with the acetate ion compared to the nitrate.
One of the more prevalent uses of magnesium acetate is in the mixture called calcium magnesium acetate (CMA). It is a mixture of calcium acetate and magnesium acetate. CMA is thought of as an environmentally friendly alternative deicer to NaCl and CaCl2. CMA also acts as a powerful SO2, NOx, and toxic particulate emission control agent in coal combustion processes to reduce acid rain, and as an effective catalyst for the facilitation of coal combustion.

Uses

Magnesium acetate is used in molecular biology applications such as batch in vitro transcription of RNA and the crystallization of transcription factor:DNA complexes and proteins via the sitting-drop vapor-diffusion method. Also used as a buffer and to detect sodium and as a catalyst for sulfuric acid.

Uses

The largest use for magnesium acetate is in the production of rayon fiber, which is used for cigarette filter tow. Magnesium acetate also has uses as a dye fixative in textile printing, as a deodorant, disinfectant, an antiseptic in medicine, and as a reagent chemical.

Uses

Dye fixative in textile printing, deodorant, disinfectant, and antiseptic.
Magnesium acetate is used in chemistry and molecular biology as a reagent and a source of magnesium. Magnesium has a variety of biological roles in enzymology, cell membrane and wall structural integrity, muscle cell physiology, and nucleic acid structure.Magnesium is an essential co-factor in many enzymes, including deoxyribonuclease (DNase), the restriction enzymes EcoR I and EcoR V, and Ribonuclease H. Magnesium also stabilizes polymeric nucleic acids such as transfer RNA and ribozymes.
Magnesium acetate has been widely used in the crystallization of proteins. A protocol for the separation of MB and BB isoenzymes of creatine kinase and the LD1 isoenzyme of lactate dehydrogenase that involves elution with magnesium acetate has been published.

Definition

ChEBI: The magnesium salt of acetic acid.

Flammability and Explosibility

Non flammable

Safety

Magnesium Acetate is a relatively safe compound to handle and has been given a health hazard rating of zero. However, it should always be handled with gloves and safety goggles. If it is gets in the eyes, the skin, ingested, or inhaled it will cause irritation in the respective areas: eyes, skin, gastrointestinal system, and lungs.

Synthesis

Synthesis of magnesium acetate from the reaction of magnesium hydroxide with acetic acid.
2CH3COOH + Mg(OH)2 → (CH3COO)2Mg + 2H2O
Magnesium carbonate suspended in distilled water with 20 % acetic acid solution.
2CH3COOH + MgCO3 → Mg(CH3COO)2
Reacting metallic magnesium with acetic acid dissolved in dry nitrogen benzene causes Magnesium Acetate to form along with the release a gas, presumably hydrogen.
Mg +2CH3COOH → Mg(CH3COO)2 + H2.

storage

Due to the fact that it is very hygroscopic, it must be stored away from water. It is also incompatible with strong oxidizers and should not be mixed with them.

Purification Methods

Crystallise it from anhydrous acetic acid, then dry it under vacuum for 24hours at 100o. [Nencollas J Chem Soc 744 1956, Beilstein 2 IV 113.]

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View Lastest Price from Magnesium acetate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Magnesium acetate pictures 2024-12-03 Magnesium acetate
142-72-3
US $6.00 / kg 1kg 99% 2000KG/Month HebeiShuoshengImportandExportco.,Ltd
Magnesium acetate pictures 2024-12-03 Magnesium acetate
142-72-3
US $7.00 / KG 1KG 99% 20TONS Hebei Longbang Technology Co., Ltd
Magnesium acetate pictures 2024-12-02 Magnesium acetate
142-72-3
US $50.00-30.00 / kg 1kg 99% 5000kg/Month Hebei Zhuanglai Chemical Trading Co.,Ltd
  • Magnesium acetate pictures
  • Magnesium acetate
    142-72-3
  • US $50.00-30.00 / kg
  • 99%
  • Hebei Zhuanglai Chemical Trading Co.,Ltd

Magnesium acetate Spectrum

MAGNESIUM ACETATE MAGNESIUM ACETATE, 4-HYDRATE MAGNESIUM ACETATE, HYDROUS magnesium acetate solution Acetic acid magnesium salt MAGNESIUM ACETATE SOLUTION, FOR MOL. BIO L., 1 M IN H2O MAGNESIUM ACETATE ANHYDROUS, EXTRA PURE 98-102% MagnesiumAcetate>98% MagnesiumAcetateBp MagnesiumAcetateA.R. magnesium diethanoate 99.997% (Metals basis) Magnesium acetate (6CI,7CI) Magnesium acetate (magnesium acetate) Magnesium acetate solution, 1M in water MAGNESIUM ACETATE SOLUTION, FOR MOL. acetatedemagnesium Acetic acid magnesium salt tetrahydrate Cromosan Cromosan* Magnesium diacetate Magnesiumacetate,anhydrous magnesiumdiacetate Mg Acetate Magnesium acetate solution BioUltra, for molecular biology, ~1 M in H2O Nu-Mag Acetic acid (magnesium) 142-72-3 C2H6O4Mg4H2O CH3COO2Mg Molecular Biology Reagents Molecular Biology Puriss p.a. ACS Cell Biology BioChemika Ultra Biochemicals BioChemical Analytical Chromatography Product Catalog Biochemicals and Reagents Analytical Reagents Antibodies Antibodies to Chemokines Antibodies to Cytokines and Growth Factors Reagents Primary Antibodies Inorganic Salts Synthetic Reagents General Use DNA & RNA Purification Crystallization organic intermediates Snow-Melting Agent AlphabeticalMolecular Biology Biological Buffers BioUltra Buffers BioUltraBiological Buffers Buffer SolutionsProtein Structural Analysis DNA&RNA Purification