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Potassium bismuthate

CAS No.
12589-75-2
Chemical Name:
Potassium bismuthate
Synonyms
Potassium bismuthate;bismuth,potassium,oxygen(2-)
CBNumber:
CB21855889
Molecular Formula:
BiH3KO
Molecular Weight:
267.1
MDL Number:
MFCD00799816
MOL File:
12589-75-2.mol
Last updated:2024-07-09 09:46:39

Potassium bismuthate Properties

FDA UNII ZPQ23ZEK9P

Potassium bismuthate Chemical Properties,Uses,Production

Synthesis

A suspension of 165 g. of Bi2O3 in 1.5 liters of 50% potassium hydroxide is oxidized at the boiling point (as described above for NaBiO3) with small portions of Br2 (total 500 g.). A dark violet precipitate results. Now, an additional 500 ml. of hot 40% potassium hydroxide is added and the material is filtered after settling. The precipitate is washed with 40% potassium hydroxide, suspended in 3-5 liters of H2O, and agitated for a while. The liquid is decanted after some hours; the solid is washed with cold H2O and filtered. The bright red precipitate is dried over H2SO4 in a desiccator. The yield is 205 g. of KBiO3 ? 1/3 H2O. Formula weight (anhydrous) 296.1.
Bi2O3 + 6KOH + 2Br2 = 2 KBiO3 + 4KBr + 3H2O.

Potassium bismuthate Preparation Products And Raw materials

Raw materials

Preparation Products

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Potassium bismuthate bismuth,potassium,oxygen(2-) 12589-75-2 BiKO3