1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan-2β-ol
- CAS No.
- 21030-71-7
- Chemical Name:
- 1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan-2β-ol
- Synonyms
- Schelhammerine;1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan-2β-ol;2H,4H-[1,3]Dioxolo[4,5-h]indolo[7a,1-a][2]benzazepin-14-ol, 1,5,6,12,13,14-hexahydro-13-methoxy-, (11bS,13S,14S)-
- CBNumber:
- CB22266693
- Molecular Formula:
- C19H23NO4
- Molecular Weight:
- 329.39
- MDL Number:
- MOL File:
- 21030-71-7.mol
1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan-2β-ol Chemical Properties,Uses,Production
Description
A third homoerythrina alkaloid found in Schelharnmera pedunculata F. Muell., the structure has been shown to be 2-hydroxysche1hammericine. It has [α]D + 186° (CHC13) and forms a crystalline hydrobromide, m.p. 276°C and the acetate, m.p. 143-4°C; [α]D + 242° (CHC13).
References
Johns et al., Chern. Commun., 1102 (1968)
1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan-2β-ol Preparation Products And Raw materials
Raw materials
Preparation Products
1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan-2β-ol
Schelhammerine
2H,4H-[1,3]Dioxolo[4,5-h]indolo[7a,1-a][2]benzazepin-14-ol, 1,5,6,12,13,14-hexahydro-13-methoxy-, (11bS,13S,14S)-
21030-71-7