1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan-2β-ol

CAS No.
21030-71-7
Chemical Name:
1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan-2β-ol
Synonyms
Schelhammerine;1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan-2β-ol;2H,4H-[1,3]Dioxolo[4,5-h]indolo[7a,1-a][2]benzazepin-14-ol, 1,5,6,12,13,14-hexahydro-13-methoxy-, (11bS,13S,14S)-
CBNumber:
CB22266693
Molecular Formula:
C19H23NO4
Molecular Weight:
329.39
MDL Number:
MOL File:
21030-71-7.mol

1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan-2β-ol Properties

Melting point 173-4°C

1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan-2β-ol Chemical Properties,Uses,Production

Description

A third homoerythrina alkaloid found in Schelharnmera pedunculata F. Muell., the structure has been shown to be 2-hydroxysche1hammericine. It has [α]D + 186° (CHC13) and forms a crystalline hydrobromide, m.p. 276°C and the acetate, m.p. 143-4°C; [α]D + 242° (CHC13).

References

Johns et al., Chern. Commun., 1102 (1968)

1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan-2β-ol Preparation Products And Raw materials

Raw materials

Preparation Products

1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan-2β-ol Schelhammerine 2H,4H-[1,3]Dioxolo[4,5-h]indolo[7a,1-a][2]benzazepin-14-ol, 1,5,6,12,13,14-hexahydro-13-methoxy-, (11bS,13S,14S)- 21030-71-7