5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one
- CAS No.
- 2292-20-8
- Chemical Name:
- 5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one
- Synonyms
- Muramine;Cryptopalmatine;5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one;Dibenz[c,g]azecin-13(6H)-one, 5,7,8,14-tetrahydro-3,4,10,11-tetramethoxy-6-methyl-
- CBNumber:
- CB22286497
- Molecular Formula:
- C22H27NO5
- Molecular Weight:
- 385.45
- MDL Number:
- MOL File:
- 2292-20-8.mol
Melting point | 148-150 °C |
---|---|
Boiling point | 555.6±50.0 °C(Predicted) |
Density | 1.131±0.06 g/cm3(Predicted) |
pka | 7.86±0.20(Predicted) |
FDA UNII | EL76JUL1BM |
5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one Chemical Properties,Uses,Production
Description
This alkaloid, sometimes referred to as cryptopalmine, occurs in Papaver nudi-cauZe L. and in Argernone rnunita Dur. & Hilg. subsp. rotunda. When crystallized from Me2CO it forms clusters of colourless crystals. It furnishes a crystalline hydriodide, m.p. 176-7°C (dec.) and a methiodide, m.p. 192-4°C. The struc_x0002_ture has been deduced from the mass spectrum and confirmed by synthesis.
Definition
ChEBI: Muramine is a dibenzazecine alkaloid that is 5,7,8,14-tetrahydrodibenzo[c,g]azecin-13(6H)-one substituted by a methyl group at position 6 and by methoxy groups at positions 3, 4, 10, and 11. It has a role as a plant metabolite. It is a dibenzazecine alkaloid, a tertiary amino compound and an aromatic ether.
References
Boit, Flentje., Naturwiss., 47, 180 (1960)
Preininger et aZ., PZanta Med., 10, 124 (1962)
Mass spectrum:
Cross et aZ., Collect. Czech. Chern. Cornrnun., 30, 1335 (1965)
Synthesis:
Haworth, Koepfli, Perkin., 1. Chern. Soc., 2261 (1927)
Giacopello, Deulofeu., Tetrahedron Lett., 2859 (1966)
5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one Preparation Products And Raw materials
Raw materials
Preparation Products
5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
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