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Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate

CAS No.
147531-11-1
Chemical Name:
Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate
Synonyms
Diphenyl(trifluoromethyl);diphenyl(trifluoromethyl)sulfanium;sulfonium trifluoromethanesulfonate;diphenyl-(trifluoroMethyl)-sulfoniuM;(S)-(trifluoroMethyl)diphenylsulfoniuM triflate;Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfot;Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonat;diphenyl(trifluoromethyl)sulfanium trifluoromethanesulfonate;diphenyl-(trifluoromethyl)-sulfonium trifluoromethanesulfonate;Diphenyl-(trifluoroMethyle)-sulfoniuM trifluoroMethancesulfonate
CBNumber:
CB22470708
Molecular Formula:
C13H10F3S.CF3O3S
Molecular Weight:
404.35
MDL Number:
MFCD12912173
MOL File:
147531-11-1.mol
MSDS File:
SDS
Last updated:2023-05-04 15:15:31

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Properties

Melting point 84-85 °C
storage temp. under inert gas (nitrogen or Argon) at 2-8°C

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302
Precautionary statements  P264-P270-P301+P312-P330-P501
Risk Statements  36/37/38
Safety Statements  26-36
HS Code  29339900

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC D492063 Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate 147531-11-1 100mg $60 2021-12-16 Buy
TRC D492063 Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate 147531-11-1 500mg $220 2021-12-16 Buy
ChemScene CS-0049606 Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate >97.0% 147531-11-1 5g $409 2021-12-16 Buy
Apolloscientific PC905034 Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate 98% 147531-11-1 250mg $77 2021-12-16 Buy
Frontier Specialty Chemicals JK1415797 Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate 99% 147531-11-1 100mg $120 2021-12-16 Buy
Product number Packaging Price Buy
D492063 100mg $60 Buy
D492063 500mg $220 Buy
CS-0049606 5g $409 Buy
PC905034 250mg $77 Buy
JK1415797 100mg $120 Buy

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Chemical Properties,Uses,Production

Uses

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate can be used as a raw material for organic synthesis with styrene derivatives to synthesise 2-arylazo pyridine at low temperature[1].

Synthesis

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate is synthesised using phenyl trifluoromethyl sulfoxide as a raw material by chemical reaction. The specific synthesis steps are as follows:
Trifluoromethyl sulfoxide (0.4 g, 2.1 mmol) and then benzene (4.9 g, 64 mmol) are introduced, under an inert atmosphere and at approximately 0° C. (lower limit below which benzene crystallizes), into a Schlenck tube purged beforehand with argon. Five equivalents of triflic anhydride (2.82 g, 10 mmol) are gradually added. The mixture is stirred for 1 h at 0° C. and then for 24 h at ambient temperature. The medium is evaporated and the residue is purified by chromatography with the CH3CN/CH2Cl2 (1/4) mixture as eluent. White crystals (Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate), having a melting point of 69-70° C., are obtained with a yield of 40%.
Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate synthesis

References

[1] J. MATSUO. A Convenient Method for the Synthesis of 2-Arylaziridines from Styrene Derivatives via 2-Arylethenyl(diphenyl)sulfonium Salts[J]. Chemistry Letters, 2003. DOI:10.1246/CL.2003.392.

Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 87)Suppliers
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Shanghai Daken Advanced Materials Co.,Ltd
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Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
CONIER CHEM AND PHARMA LIMITED
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Guangzhou Yuheng Pharmaceutical Technology Co., Ltd
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Allfluoro pharmaceutical co. ltd.
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Career Henan Chemica Co
+86-0371-86658258 15093356674; laboratory@coreychem.com China 30254 58
ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23556 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com China 52861 58

View Lastest Price from Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
diphenyl-(trifluoromethyl)-sulfonium trifluoromethanesulfonate pictures 2022-10-10 diphenyl-(trifluoromethyl)-sulfonium trifluoromethanesulfonate
147531-11-1
US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
diphenyl-(trifluoromethyl)-sulfonium trifluoromethanesulfonate diphenyl-(trifluoroMethyl)-sulfoniuM Diphenyl-(trifluoroMethyle)-sulfoniuM trifluoroMethancesulfonate (S)-(trifluoroMethyl)diphenylsulfoniuM triflate diphenyl(trifluoromethyl)sulfanium trifluoromethanesulfonate Diphenyl(trifluoromethyl) sulfonium trifluoromethanesulfonate diphenyl(trifluoromethyl)sulfanium Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonat Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfot Sulfonium, diphenyl(trifluoromethyl)-, 1,1,1-trifluoromethanesulfonate (1:1) 147531-11-1 C14H10F6O3S2