Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate
- CAS No.
- 147531-11-1
- Chemical Name:
- Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate
- Synonyms
- Diphenyl(trifluoromethyl);diphenyl(trifluoromethyl)sulfanium;sulfonium trifluoromethanesulfonate;diphenyl-(trifluoroMethyl)-sulfoniuM;(S)-(trifluoroMethyl)diphenylsulfoniuM triflate;Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfot;Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonat;diphenyl(trifluoromethyl)sulfanium trifluoromethanesulfonate;diphenyl-(trifluoromethyl)-sulfonium trifluoromethanesulfonate;Diphenyl-(trifluoroMethyle)-sulfoniuM trifluoroMethancesulfonate
- CBNumber:
- CB22470708
- Molecular Formula:
- C13H10F3S.CF3O3S
- Molecular Weight:
- 404.35
- MDL Number:
- MFCD12912173
- MOL File:
- 147531-11-1.mol
- MSDS File:
- SDS
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H302 |
| Precautionary statements | P264-P270-P301+P312-P330-P501 |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| HS Code | 29339900 |
Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate price
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| TRC | D492063 | Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate | 147531-11-1 | 100mg | $60 | 2021-12-16 | Buy |
| TRC | D492063 | Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate | 147531-11-1 | 500mg | $220 | 2021-12-16 | Buy |
| ChemScene | CS-0049606 | Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate >97.0% | 147531-11-1 | 5g | $409 | 2021-12-16 | Buy |
| Apolloscientific | PC905034 | Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate 98% | 147531-11-1 | 250mg | $77 | 2021-12-16 | Buy |
| Frontier Specialty Chemicals | JK1415797 | Diphenyl(trifluoromethyl)sulfoniumtrifluoromethanesulfonate 99% | 147531-11-1 | 100mg | $120 | 2021-12-16 | Buy |
Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Chemical Properties,Uses,Production
Uses
Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate can be used as a raw material for organic synthesis with styrene derivatives to synthesise 2-arylazo pyridine at low temperature[1].
Synthesis
Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate is synthesised using phenyl trifluoromethyl sulfoxide as a raw material by chemical reaction. The specific synthesis steps are as follows:
Trifluoromethyl sulfoxide (0.4 g, 2.1 mmol) and then benzene (4.9 g, 64 mmol) are introduced, under an inert atmosphere and at approximately 0° C. (lower limit below which benzene crystallizes), into a Schlenck tube purged beforehand with argon. Five equivalents of triflic anhydride (2.82 g, 10 mmol) are gradually added. The mixture is stirred for 1 h at 0° C. and then for 24 h at ambient temperature. The medium is evaporated and the residue is purified by chromatography with the CH3CN/CH2Cl2 (1/4) mixture as eluent. White crystals (Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate), having a melting point of 69-70° C., are obtained with a yield of 40%.
References
[1] J. MATSUO. A Convenient Method for the Synthesis of 2-Arylaziridines from Styrene Derivatives via 2-Arylethenyl(diphenyl)sulfonium Salts[J]. Chemistry Letters, 2003. DOI:10.1246/CL.2003.392.
Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 16208 | 58 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9337 | 55 |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63711 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49391 | 58 |
| Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21149 | 58 |
| Allfluoro pharmaceutical co. ltd. | 021-26137118 +8615821363818 | sales@allfluoro.com | China | 5791 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | laboratory@coreychem.com | China | 30253 | 58 |
| ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | eric@witopchemical.com | China | 23556 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52861 | 58 |
View Lastest Price from Diphenyl(trifluoromethyl)sulfonium trifluoromethanesulfonate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2022-10-10 | diphenyl-(trifluoromethyl)-sulfonium trifluoromethanesulfonate
147531-11-1
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. |
-
- diphenyl-(trifluoromethyl)-sulfonium trifluoromethanesulfonate
147531-11-1
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
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