9-Fluorenone
- CAS No.
- 486-25-9
- Chemical Name:
- 9-Fluorenone
- Synonyms
- 9H-FLUOREN-9-ONE;FLUORENONE;FLUOREN-9-ONE;9H-fluorene-9-one;uorenone;9-FLUORENON;9-FLUORENONE;Dluoren-9-one;9-Fluoreneone;9-oxofluorene
- CBNumber:
- CB2304953
- Molecular Formula:
- C13H8O
- Molecular Weight:
- 180.2
- MDL Number:
- MFCD00001141
- MOL File:
- 486-25-9.mol
- MSDS File:
- SDS
| Melting point | 80-83 °C (lit.) |
|---|---|
| Boiling point | 342 °C (lit.) |
| Density | 0,9 g/cm3 |
| vapor pressure | 0.005-0.2Pa at 20-50℃ |
| refractive index | 1.6309 (estimate) |
| Flash point | 163 °C |
| storage temp. | Store below +30°C. |
| solubility | DMSO (Slightly), Methanol (Slightly) |
| form | Crystalline Powder or Flakes |
| color | Yellow |
| Water Solubility | insoluble |
| BRN | 1636531 |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents. |
| InChIKey | YLQWCDOCJODRMT-UHFFFAOYSA-N |
| LogP | 3.25 at 25℃ and pH7.7 |
| CAS DataBase Reference | 486-25-9(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | AZ9T83S2AQ |
| NIST Chemistry Reference | 9H-Fluoren-9-one(486-25-9) |
| EPA Substance Registry System | 9-Fluorenone (486-25-9) |
| UNSPSC Code | 12352115 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H319-H411 | |||||||||
| Precautionary statements | P273-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 24/25-36/37/39-27-26 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | LL8925000 | |||||||||
| Autoignition Temperature | 608 °C | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29143900 | |||||||||
| Hazardous Substances Data | 486-25-9(Hazardous Substances Data) | |||||||||
| Toxicity | LD50 orally in Rabbit: > 3900 mg/kg | |||||||||
| NFPA 704 |
|
9-Fluorenone price More Price(26)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | F1506 | 9-Fluorenone 98% | 486-25-9 | 5G | $26 | 2024-03-01 | Buy |
| Sigma-Aldrich | F1506 | 9-Fluorenone 98% | 486-25-9 | 100g | $76.2 | 2024-03-01 | Buy |
| Sigma-Aldrich | F1506 | 9-Fluorenone 98% | 486-25-9 | 500g | $129 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.03977 | 9-Fluorenone for synthesis | 486-25-9 | 250g | $117 | 2024-03-01 | Buy |
| TCI Chemical | F0021 | 9-Fluorenone >98.0%(GC) | 486-25-9 | 25g | $19 | 2024-03-01 | Buy |
9-Fluorenone Chemical Properties,Uses,Production
Description
9-fluorenone is an important intermediate for organic synthesis. It can be used to manufacture a variety of fine chemicals, mainly used as a modifier for the production of polymer materials, bisphenol fluorene, fluorenyl benzoxazine resin, acrylic resin, polyester, polycarbonate and epoxy resin. In the laboratory, fluorene was used as the raw material, dimethyl sulfoxide as the solvent, sodium hydroxide as the catalyst and oxygen as the oxidant. The oxidizing reaction was carried out by a tower packing reactor. The reaction solution was cooled and filtered to obtain a crude fluorenone. The content of crude fluorenone is 93%. We can recover 94% of the solvent and part of the crude fluorenone through distillation of the filtrate. The crude fluorenone is purified by directional crystallization to obtain yellow flaky fluorenone that have a purity of 99.8% or more.
Chemical Properties
yellow flakes, chips or crystalline powder; Soluble in ethanol and ether, insoluble in water.
Uses
9-Fluorenone is used in the preparation of antimalarial drugs. It is a fluorene derivative. Further, it is used in functional polymer and in dyes.
Application
9-Fluorenone has been extensively used as a precursor to synthesize a variety of organic electronic materials. Some of the general examples are:
Synthesis of host for the blue and green phosphorescent organic light emitting diodes (PHOLEDs).
Synthesis of fluorene-based molecular motors.
Synthesis of open-shell Chichibabin′s hydrocarbons as potential organic spintronic materials.
It also acts as a sensitizer in the formation of picene via photosensitization of 1,2-di(1-naphthyl)ethane.
Definition
ChEBI: Fluoren-9-one is the simplest member of the class fluoren-9-ones that is 9H-fluorene bearing an oxo substituent at position 9. It has a role as a fungal xenobiotic metabolite.
Preparation
Fluorenone can be produced by catalytic oxidation of fluorene, or of fluorene fractions in the presence of a quarternary ammonium salt, or by catalytic oxidative cracking (oxicracking) of a suitable aromatic.
Synthesis Reference(s)
The Journal of Organic Chemistry, 60, p. 3934, 1995 DOI: 10.1021/jo00118a002
Synthetic Communications, 6, p. 285, 1976 DOI: 10.1080/00397917608063524
Purification Methods
Crystallise 9-fluorenone from absolute EtOH, MeOH or *benzene/pentane. [Ikezawa J Am Chem Soc 108 1589 1986.] Also recrystallise it twice from toluene and sublime it in a vacuum [Saltiel J Am Chem Soc 108 2674 1986]. It can be distilled under high vacuum. [Beilstein 7 H 465, 7 III 2330, 7 IV 1629.]
9-Fluorenone Preparation Products And Raw materials
Raw materials
Preparation Products
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| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Chengdu Yuanda Chemical Co., Ltd | 28-85356300 +8618980937689 | sales@ydachem.com | CHINA | 94 | 58 |
| Hu Bei Jiutian Bio-medical Technology CO.,Ltd | 027-88013699 17354350817 | Ryan@jiutian-bio.com | China | 6001 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8804 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5887 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8617732866630 | bess@weibangbio.com | China | 18147 | 58 |
| Anhui Ruihan Technology Co., Ltd | +8617756083858 | daisy@anhuiruihan.com | China | 973 | 58 |
| HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD | +8615350851019 | admin@86-ss.com | China | 1001 | 58 |
| Hebei Zhuanglai Chemical Trading Co Ltd | +86-16264648883 +86-16264648883 | niki@zlchemi.com | China | 3712 | 58 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 19902 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21632 | 55 |
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View Lastest Price from 9-Fluorenone manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-02-21 | 9-Fluorenone
486-25-9
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mujin Biotechnology Co.,Ltd | |
 |
2025-02-21 | 9-Fluorenone
486-25-9
|
US $0.00 / kg | 1kg | 99.5% | 500mt | Jinan Finer Chemical Co., Ltd | |
 |
2025-02-21 | 9-Fluorenone
486-25-9
|
US $10.00 / kg | 1kg | 99% | 20 ton | Hebei Zhuanglai Chemical Trading Co Ltd |
-
- 9-Fluorenone
486-25-9
- US $0.00 / KG
- 99%
- Hebei Mujin Biotechnology Co.,Ltd
-
- 9-Fluorenone
486-25-9
- US $0.00 / kg
- 99.5%
- Jinan Finer Chemical Co., Ltd
-
- 9-Fluorenone
486-25-9
- US $10.00 / kg
- 99%
- Hebei Zhuanglai Chemical Trading Co Ltd
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