ChemicalBook >> CAS DataBase List >>COBALTOCENE HEXAFLUOROPHOSPHATE
COBALTOCENE HEXAFLUOROPHOSPHATE
- CAS No.
- 12427-42-8
- Chemical Name:
- COBALTOCENE HEXAFLUOROPHOSPHATE
- Synonyms
- COBALTOCENE HEXAFLUOROPHOSPHATE;BIS(CYCLOPENTADIENYL)COBALT(III);COBALTOCENIUM HEXAFLUOROPHOSPHATE;COBALTICINIUM HEXAFLUOROPHOSPHATE;Cobalticiniumhexafluorophosphate,98%;Cobaltocenium hexafluorophosphate,98%;cobaltocenium hexafluorophosphate(1-);Dicyclopentadienylcobalt hexafluorophosphate;BIS(CYCLOPENTADIENYL)COBALT HEXAFLUOROPHOSPHATE;Bis(cyclopentadienyl)cobalt(1+) hexafluorophosphate
- CBNumber:
- CB2314446
- Molecular Formula:
- C10H10CoF6P10*
- Molecular Weight:
- 334.08
- MDL Number:
- MFCD00011874
- MOL File:
- 12427-42-8.mol
- MSDS File:
- SDS
Last updated:2025-01-27 09:38:02
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302+H312+H332-H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338 | |||||||||
| Hazard Codes | Xn | |||||||||
| Risk Statements | 20/21/22-36/37/38 | |||||||||
| Safety Statements | 26-37/39 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 2931.90.9051 | |||||||||
| NFPA 704 |
|
COBALTOCENE HEXAFLUOROPHOSPHATE price More Price(18)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 279811 | Bis(cyclopentadienyl)cobalt(III) hexafluorophosphate 98% | 12427-42-8 | 1g | $67.3 | 2024-03-01 | Buy |
| TCI Chemical | C1589 | Bis(cyclopentadienyl)cobalt(III) Hexafluorophosphate >96.0%(T) | 12427-42-8 | 1g | $207 | 2024-03-01 | Buy |
| Strem Chemicals | 27-0410 | Cobalticinium hexafluorophosphate, 98% | 12427-42-8 | 1g | $76 | 2024-03-01 | Buy |
| Strem Chemicals | 27-0410 | Cobalticinium hexafluorophosphate, 98% | 12427-42-8 | 5g | $303 | 2024-03-01 | Buy |
| TRC | B424105 | Bis(cyclopentadienyl)cobalt(III) Hexafluorophosphate | 12427-42-8 | 1g | $45 | 2021-12-16 | Buy |
COBALTOCENE HEXAFLUOROPHOSPHATE Chemical Properties,Uses,Production
Chemical Properties
yellow powder
Uses
Uses:
- Cocatalyst for Heck reaction of aryl iodides with alkenes using palladium as catalyst in water
- Reactant for modification of organometallic electrodes surfaces through cathodic reduction
- Reactant in synthesis and solution self-assembly of side-chain cobaltocenium-containing block copolymers
Synthesis Reference(s)
[1](a) Gmelin, Handbuch der Anorganischen Chemie, 8th ed; Verlag Chemie: Weinheim, 1973; Supplement, Vol. 5, part 1. (b) Sheats, J. E. JOM Libr. 1979, 7, 461.
reaction suitability
core: cobalt
reagent type: catalyst
Synthesis
Cobaltocene hexafluorophosphate is readily synthesized from cobalt(II) salts + CpNa, followed by air + HPF6 or NH4PF6. Salts with a wide range of other counterions may be obtained similarly. The cobaltocenium ion[1] may be precipitated from aqueous solution by a variety of large anions. In addition to PF6 -, convenient counterions include Br3 - and I3 -. The simple halides are hygroscopic, but may be obtained in anhydrous form by removal of water under vacuum.
Precautions
COBALTOCENE HEXAFLUOROPHOSPHATE is very stable; irritant.
COBALTOCENE HEXAFLUOROPHOSPHATE Preparation Products And Raw materials
Raw materials
Preparation Products
COBALTOCENE HEXAFLUOROPHOSPHATE Suppliers
Global( 70)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49476 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 7724 | 58 |
| ShanDong Look Chemical Co.,Ltd. | +8617653113219 | sales01@sdlookchemical.com | China | 2737 | 58 |
| Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 57505 | 58 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 021-61259108 18621169109 | market03@meryer.com | China | 40228 | 62 |
| INTATRADE GmbH | +49 3493/605464 | sales@intatrade.de | Germany | 3572 | 66 |
| TCI (Shanghai) Development Co., Ltd. | 021-67121386 | Sales-CN@TCIchemicals.com | China | 24529 | 81 |
| Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44689 | 61 |
12427-42-8(COBALTOCENE HEXAFLUOROPHOSPHATE)Related Search:
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BIS(CYCLOPENTADIENYL)COBALT(III)
Cobalticiniumhexafluorophosphate,98%
Bis(cyclopentadienyl)cobalt (II) hexafluorophosphate
Cobaltocenium hexafluorophosphate,98%
Bis(cyclopentadienyl)cobalt(1+) hexafluorophosphate
Bis(cyclopentadienyl)cobalt(1+) hexafluorophosphate(1-)
Dicyclopentadienylcobalt hexafluorophosphate
Dicyclopentadienylcobalt(1+) hexafluorophosphate(1-)
COBALTICINIUM HEXAFLUOROPHOSPHATE
COBALTOCENE HEXAFLUOROPHOSPHATE
COBALTOCENIUM HEXAFLUOROPHOSPHATE
BIS(CYCLOPENTADIENYL)COBALT HEXAFLUOROPHOSPHATE
BIS(CYCLOPENTADIENYL)COBALT(III) HEXAFLUOROPHOSPHATE
cobaltocenium hexafluorophosphate(1-)
Bis(cyclopentadienyl)cobalt(III)Hexafluorophosphate>
COBALTOCENE HEXAFLUOROPHOSPHATE ISO 9001：2015 REACH
12427-42-8
C10H10CoF6P10
C5H52CoPF6
C10H10CoF6P
C10H10CoPF6
Classes of Metal Compounds
Titanocene, etc.
Transition Metal Compounds
Co (Cobalt) Compounds
Metallocenes
Catalysis and Inorganic Chemistry
halometallate salts
Classes of Metal Compounds
Co (Cobalt) Compounds
Metallocenes
Titanocene, etc.
Transition Metal Compounds
Catalysis and Inorganic Chemistry
Chemical Synthesis
Cobalt