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12-Bromo-1-dodecanol

CAS No.
3344-77-2
Chemical Name:
12-Bromo-1-dodecanol
Synonyms
12-BROMO-1-DODECANOL;12-Bromododecane-1-ol;12-Bromododecanol;12-BROMO-DODECAN-1-OL;1-Dodecanol, 12-bromo-;12-Bromododecyl alcohol;12-Bromo-1-dodecanol 99%;12-Bromo-1-dodecanol >12-BROMO-1-DODECANOL 98+%;12-BroMo-1-dodecanol , 98.0%(GC)
CBNumber:
CB2336572
Molecular Formula:
C12H25BrO
Molecular Weight:
265.23
MDL Number:
MFCD00004754
MOL File:
3344-77-2.mol
MSDS File:
SDS
Last updated:2024-07-18 18:48:51

12-Bromo-1-dodecanol Properties

Melting point 34-36 °C (lit.)
Boiling point 155 °C/4 mmHg (lit.)
Density 1.1771 (rough estimate)
refractive index 1.5130 (estimate)
Flash point >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Chloroform, Methanol (Slightly)
form Solid
pka 15.20±0.10(Predicted)
color Off-White to Pale Yellow
BRN 1742764
InChI InChI=1S/C12H25BrO/c13-11-9-7-5-3-1-2-4-6-8-10-12-14/h14H,1-12H2
InChIKey ASIDMJNTHJYVQJ-UHFFFAOYSA-N
SMILES C(O)CCCCCCCCCCCBr
CAS DataBase Reference 3344-77-2(CAS DataBase Reference)
FDA UNII L7CYF0086V

SAFETY

Risk and Safety Statements

Safety Statements  22-24/25
WGK Germany  3
HS Code  2905.59.1000
NFPA 704
1
0 0

12-Bromo-1-dodecanol price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 224677 12-Bromo-1-dodecanol 99% 3344-77-2 5g $82.3 2024-03-01 Buy
Sigma-Aldrich 224677 12-Bromo-1-dodecanol 99% 3344-77-2 1g $42 2023-06-20 Buy
TCI Chemical B1731 12-Bromo-1-dodecanol >98.0%(GC) 3344-77-2 5g $144 2024-03-01 Buy
TCI Chemical B1731 12-Bromo-1-dodecanol >98.0%(GC) 3344-77-2 25g $490 2024-03-01 Buy
TRC B684222 12-Bromo-1-dodecanol 3344-77-2 1g $45 2021-12-16 Buy
Product number Packaging Price Buy
224677 5g $82.3 Buy
224677 1g $42 Buy
B1731 5g $144 Buy
B1731 25g $490 Buy
B684222 1g $45 Buy

12-Bromo-1-dodecanol Chemical Properties,Uses,Production

Uses

12-Bromo-1-dodecanol is a skin sensitizer.

Synthesis Reference(s)

Synthesis, p. 1161, 1985 DOI: 10.1055/s-1985-31464

Synthesis

To a solution of 1,12-Dodecanediol (28 g, 0.14 mol) in toluene (600 mL) was added concentrated HBr [27.5 mL of a 48 % (9 M) aqueous solution, 0.162 mol]. The heterogeneous mixture was heated at reflux for 36 h, after which TLC analysis showed that 20 % of the diol remained. Thus, a further quantity of HBr (10 mL, 0.09 mol) was added, and the mixture was heated at reflux for 12 h, after which TLC analysis showed no remaining diol. The reaction mixture was allowed to return to room temperature, and the phases were separated. The organic layer was diluted with ether (200 mL) and washed with 1 M NaOH solution (200 mL) and brine solution (300 mL). Drying over anhydrous Na2SO4, filtration, and concentration of the organic layer gave a yellow oil, which was purified by column chromatography using hexane/ether as eluent (7:3) to provide 12-Bromo-1-dodecanol as a pale yellow oil.

12-Bromo-1-dodecanol Preparation Products And Raw materials

Global( 164)Suppliers
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View Lastest Price from 12-Bromo-1-dodecanol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
12-Bromo-1-dodecanol pictures 2024-07-18 12-Bromo-1-dodecanol
3344-77-2
US $1.00 / KG 1KG 99% 20T Shaanxi Dideu Medichem Co. Ltd
12-Bromododecanol pictures 2019-09-03 12-Bromododecanol
3344-77-2
US $1.00 / KG 1KG 95-99% 1MT Career Henan Chemical Co
12-Bromododecanol 12-BROMO-DODECAN-1-OL 12-BROMO-1-DODECANOL 98+% 12-Bromododecyl alcohol 12-Bromo-1-dodecanol 99% 1-Dodecanol, 12-bromo- 12-BroMo-1-dodecanol , 98.0%(GC) 12-Bromo-1-dodecanol > 12-BROMO-1-DODECANOL 12-Bromododecane-1-ol 3344-77-2 BrCH212OH C12H25BrO 蠅-Functional Alkanols, Carboxylic Acids, Amines & Halides 蠅-Bromoalkanols Alcohols Building Blocks C9 to C30 Oxygen Compounds Organic Building Blocks OLED materials,pharm chemical,electronic pharmacetical omega-Bromoalkanols omega-Functional Alkanols, Carboxylic Acids, Amines & Halides Alcohols C9 to C30 Oxygen Compounds