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((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE

((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE structure

CAS No.: 116399-78-1

Chemical Name:: ((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE

Synonyms: (E)-(4-Chlorobut-2-en-2-yl)trimethylsilane;((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE;(E)-(3-Chloro-1-methyl-1-propenyl)trimethylsilane;Silane, (3-chloro-1-methyl-1-propen-1-yl)trimethyl-

CBNumber:: CB2838869

Molecular Formula:: C7H15ClSi

Molecular Weight:: 162.73

MDL Number:: MFCD09030104

MOL File:: 116399-78-1.mol

Last updated:2023-04-23 13:52:06

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((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE Properties

Boiling point	167.7±15.0 °C(Predicted)
Density	0.881±0.06 g/cm3(Predicted)
solubility	freely sol organic solvents.

((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE price

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
American Custom Chemicals Corporation	ORS0001263	((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE 95.00%	116399-78-1	5MG	$497.83	2021-12-16	Buy

Product number	Packaging	Price	Buy
ORS0001263	5MG	$497.83	Buy

((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE Chemical Properties,Uses,Production

Physical properties

bp 92–94°C/74 mmHg.

Uses

(E)-(3-Chloro-1-methyl-1-propenyl)- trimethylsilane acts as the alkylative equivalent of 3-buten-2-one (methyl vinyl ketone), permitting regiospecific enolate alkylation under nonequilibrating conditions. As a vinylsilane it can be converted,via the corresponding α,β-epoxy silane, into a 3-oxobutyl moiety, and hence used in an alkylative equivalent of Robinson annulation.Application of such methodology can be seen (eq 1) in the preparation of bicyclodecenones via the alkylation of dihydrocarvone with this reagent.Apart from this application, and its use in combination with potassium iodide, it has seen little use so far. ((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE

((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE Suppliers

Global( 4)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63711	58

Supplier	Advantage
Alchem Pharmtech,Inc.	58

116399-78-1(((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE)Related Search:

((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE 2-PROPENYLTRIMETHYLSILANE

((E)-3-CHLORO-1-METHYLPROPENYL)TRIMETHYLSILANE (E)-(3-Chloro-1-methyl-1-propenyl)trimethylsilane (E)-(4-Chlorobut-2-en-2-yl)trimethylsilane Silane, (3-chloro-1-methyl-1-propen-1-yl)trimethyl- 116399-78-1