tert-Butyl methyl ether
- CAS No.
- 1634-04-4
- Chemical Name:
- tert-Butyl methyl ether
- Synonyms
- MTBE;TBME;METHYL TERT-BUTYL ETHER;MTB;2-Methoxy-2-methylpropane;BOC-ARG(MTR)-OH;T-BUTYL METHYL ETHER;Methyl tert-butyl ether, for residue analysis;METHYL-T-BUTYL ETHER;2-methoxy-2-methyl
- CBNumber:
- CB2853178
- Molecular Formula:
- C5H12O
- Molecular Weight:
- 88.15
- MDL Number:
- MFCD00008812
- MOL File:
- 1634-04-4.mol
- MSDS File:
- SDS
| Melting point | -110 °C |
|---|---|
| Boiling point | 55-56 °C(lit.) |
| Density | 0.7404 |
| vapor density | 3.1 (vs air) |
| vapor pressure | 4.05 psi ( 20 °C) |
| refractive index |
n |
| Flash point | -27 °F |
| storage temp. | Store at +2°C to +25°C. |
| solubility | 42g/l |
| form | Powder or Needles |
| color | APHA: ≤10 |
| Specific Gravity | 0.740 |
| Relative polarity | 0.124 |
| Odor | Characteristic ethereal odor |
| Relative density, gas (air=1) | 0.74 g/cm3 at 25 °C |
| Viscosity | 0.464mm2/s |
| explosive limit | 1.5-8.5%(V) |
| Water Solubility | 51 g/L (20 ºC) |
| FreezingPoint | -108.6℃ |
| λmax |
λ: 210 nm Amax: 1.0 λ: 225 nm Amax: 0.50 λ: 250 nm Amax: 0.10 λ: 300-400 nm Amax: 0.005 |
| Merck | 14,6032 |
| BRN | 1730942 |
| Exposure limits | ACGIH: TWA 50 ppm |
| Dielectric constant | 4.5 |
| Stability | Stable, but may form explosive peroxides in contact with air. Extremely flammable - note low flash point. Incompatible with strong oxidizing agents. |
| InChIKey | BZLVMXJERCGZMT-UHFFFAOYSA-N |
| LogP | 1.06 at 20℃ |
| CAS DataBase Reference | 1634-04-4(CAS DataBase Reference) |
| EWG's Food Scores | 5 |
| FDA UNII | 29I4YB3S89 |
| NIST Chemistry Reference | Propane, 2-methoxy-2-methyl-(1634-04-4) |
| IARC | 3 (Vol. 73) 1999 |
| EPA Substance Registry System | Methyl tert-butyl ether (1634-04-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H225-H315 | |||||||||
| Precautionary statements | P210-P233-P240-P241-P242-P303+P361+P353 | |||||||||
| Hazard Codes | Xn,F,Xi,T | |||||||||
| Risk Statements | 36/37/38-40-38-11-39/23/24/25-23/24/25 | |||||||||
| Safety Statements | 9-16-24-45-36/37-7 | |||||||||
| RIDADR | UN 2398 3/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | KN5250000 | |||||||||
| F | 3-10 | |||||||||
| Autoignition Temperature | 705 °F | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 2909 19 90 | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | II | |||||||||
| Toxicity | . LC50 in mice (15 min): 1.6 mmol/liter of atmosphere (Marsh) | |||||||||
| NFPA 704 |
|
tert-Butyl methyl ether price More Price(79)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | MX0826 | Methyl-t-Butyl Ether OmniSolv? | 1634-04-4 | 1L | $159 | 2024-03-01 | Buy |
| Sigma-Aldrich | MX0819 | Methyl-t-Butyl Ether Meets ACS Specifications GR ACS | 1634-04-4 | 4L | $385 | 2024-03-01 | Buy |
| Sigma-Aldrich | MX0826 | Methyl-t-Butyl Ether OmniSolv? | 1634-04-4 | 4L | $503 | 2024-03-01 | Buy |
| Sigma-Aldrich | MX0819 | Methyl-t-Butyl Ether Meets ACS Specifications GR ACS | 1634-04-4 | 20L | $1080 | 2024-03-01 | Buy |
| Sigma-Aldrich | MX0819 | Methyl-t-Butyl Ether Meets ACS Specifications GR ACS | 1634-04-4 | 200L | $5460 | 2024-03-01 | Buy |
tert-Butyl methyl ether Chemical Properties,Uses,Production
Description
Methyl tert-butyl ether (MTBE) is a colorless liquid with a distinctive, disagreeable odor. It is made from blending chemicals such as isobutylene and methanol, and has been used since the 1980s as an additive for unleaded gasolines to achieve more efficient burning.MTBE is also used to dissolve gallstones. Patients treated in this way have MTBE delivered directly to their gall bladders through special tubes that are surgically inserted.
Chemical Properties
tert-Butyl methyl ether, also known as MTBE or Methyl tert-butyl ether, is a clear, colorless liquid with a low viscosity that is combustible and has a distinct, turpentine-like odor. It is miscible with organic solvents, but only slightly soluble in water. Methyl tert-butyl ether is very stable under alkaline, neutral, and weakly acidic conditions. In the presence of strong acids, it is cleaved to methanol and isobutene. Depending on reaction conditions the latter can form isobutene oligomers. MTBE does not undergo autoxidation and, in contrast to other ethers, it does not form peroxides with atmospheric oxygen. It improves the antiknock properties when added to motor gasoline.
History
tert-Butyl methyl ether was first synthesized (by the classical Williamson ether synthesis) and characterized in 1904. Extensive studies in the United States during World War II demonstrated the outstanding qualities of MTBE as a high-octane fuel component. It was first commercially produced in Italy in 1973 for use as an octane enhancer in gasoline. U.S. production of MTBE started in 1979 after Atlantic Richfield Co. (ARCO) was granted a waiver by the U.S. Environmental Protection Agency (EPA) that allowed MTBE to be blended up to 7 vol % in U.S. unleaded gasoline. The use of other aliphatic ethers was allowed when the U.S. EPA issued its “substantially similar” definition for unleaded gasoline specifications in 1981. Under this definition, any aliphatic ether or ether mixture could be blended in unleaded gasoline as long as the total oxygen contribution from the ethers does not exceed 2.0% oxygen by weight in the gasoline. This allowed MTBE to be blended up to approximately 11 vol % in gasoline.
Uses
Methyl tert-butyl ether (MTBE) was primarily used as a gasoline additive in unleaded gasoline in the United States prior to 2005, in the manufacture of isobutene, and as a chromatographic eluent especially in high pressure liquid chromatography. It is also a pharmaceutical agent and can be injected into the gallbladder to dissolve gallstones (ATSDR, 1996). tert-Butyl methyl ether is also used in the petrochemical industry. By reversal of its formation reaction, MTBE can be cracked to isobutene and methanol on acidic catalysts at higher temperature than MTBE synthesis.
Preparation
tert-butyl methyl ether can be prepared by the reaction of potassium tert-butoxide and bromomethane. Methyl tert-butyl ether also can be obtained by the acid-catalyzed addition of methanol to isobutene. Suitable catalysts are solid acids such as bentonites, zeolites and – commonly used in industrial world scale MTBE-production units – macroporous acidic ion-exchange resins. The reaction is weakly exothermic with a heat of reaction of -37.7 kJ/mol.
Definition
ChEBI: Methyl tert-butyl ether is an ether having methyl and tert-butyl as the two alkyl components. It has a role as a non-polar solvent, a fuel additive and a metabolite.
General Description
Methyl tert-butyl ether appears as a colorless liquid with a distinctive anesthetic-like odor. Vapors are heavier than air and narcotic (cause drowsiness when inhaled). This liquid has a flash point lower than most ambient temperatures, so it will readily ignite under most conditions. It is less dense than water and moderately soluble in water. Used as a octane booster in gasoline.
Air & Water Reactions
Highly flammable. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick 1979. p.151-154, 164]. A mixture of liquid air and diethyl ether exploded spontaneously [MCA Case History 616. 1960].
Reactivity Profile
Tert-Butyl methyl ether is a kind of Ethers, it form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.
Hazard
Tert-Butyl methyl ether is slightly toxic by ingestion and inhalation. Flammable when exposed to heat or flame. Upper respiratory tract irritant and kidney damage. Questionable carcinogen.
Health Hazard
INHALATION: May cause dizziness or suffocation. Contact may irritate or burn eyes or skin. May be harmful if swallowed.
Industrial uses
Methyl tert-butyl ether (MTBE) is used as an octane enhancer in gasoline. EPA regulations allow up to 2.7 wt.% oxygen in gasoline which allows 15 vol.% MTBE in gasoline. Other alkyl ethers can also be blended into gasoline up to the 2.7 wt% oxygen requirement. The stability of MTBE to oxidation and peroxide formation gives this unsymmetrical ether an advantage over other ethers in various extraction and reaction solvent applications.
Safety Profile
Poison by intravenous route. Slightly toxic by ingestion and inhalation. Flammable when exposed to heat or flame. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.
Potential Exposure
Tert-Butyl methyl ether is used as an organic solvent; as an octane booster in unleaded gasolines; in making other chemicals; and in medicine to dissolve gall stones
First aid
If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
Carcinogenicity
EPA has not classified methyl tert-butyl ether with respect to potential carcinogenicity. There is evidence for the carcinogenicity of MTBE in animals. MTBE causes leukemias/lymphomas in female rats, renal tubular tumors and Leydig cell tumors in male rats, and hepatocellular tumors in mice. Positive animal carcinogenicity data and some further concordance in tumor sites for formaldehyde and TBA, metabolites of MTBE, provide support for this conclusion. However, uncertainties remain about the nature and extent of risk at very low doses, and about the particular tumor sites that are most relevant to humans.
Environmental Fate
tert-Butyl Methyl Ether can be released during manufacturing or blending with gasoline; during the storage, distribution, and transfer of MTBE-blended gasoline; and from spills or leaks or fugitive emissions at automotive service stations (U.S. EPA, 1994a). Vapor emissions from MTBE-blended gasoline may also contribute to atmospheric levels (U.S. EPA, 1988). It is not expected to persist in the atmosphere because it undergoes destruction from reactions with hydroxyl radicals. A total atmospheric lifetime for MTBE of approximately 3 and 6.1 days has been reported in polluted urban air and in nonpolluted rural air, respectively (U.S. EPA, 1993a). Based upon its vapor pressure and Henry s law constant, MTBE is highly volatile and would be expected to evaporate rapidly from soil surfaces or water. It may be fairly persistent when introduced into subsurface soils or to groundwater since volatilization to the atmosphere is reduced or eliminated. It does not readily degrade in surface waters due to hydrolysis or other abiotic processes. It is also resistant to biodegradation (U.S. EPA, 1993a). It is usually removed from surface waters very rapidly because of its high volatility. If released as part of a gasoline mixture from leaking underground storage tanks, its relatively high water solubility combined with little tendency to sorb to soil particles encourages migration to local groundwater supplies (U.S. EPA, 1993a).
Shipping
UN2398 Methyl tert-butyl ether, Hazard Class: 3; Labels: 3-Flammable liquid.
Purification Methods
Purify as for n-butyl methyl ether. [Beilstein 1 IV 1615.]
Incompatibilities
May form explosive mixture with air. May be able to form unstable peroxides. Much less likely to form peroxides than other ethers. Incompatible with strong acids. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. May accumulate static electrical charges, and cause ignition of its vapors.
Waste Disposal
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
tert-Butyl methyl ether Preparation Products And Raw materials
Raw materials
Preparation Products
1of8
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shandong Quark Chemical Co., Ltd. | +8613325218432 | sales@quarkchem.com | China | 57 | 58 |
| AS WATER CO., LTD. | +86-18994963526 +8618994963526 | 1346073549@qq.com | United Kingdom | 176 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8812 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5893 | 58 |
| Yujiang Chemical (Shandong) Co.,Ltd. | +86-17736087130 +86-18633844644 | catherine@yjchem.com.cn | China | 985 | 58 |
| Qingdao RENAS Polymer Material Co., Ltd. | +86-0532-86867058 +86-18562606086 | sales@qdrenas.com | China | 476 | 58 |
| Hebei Youfeidi Trading Co., LTD | +8615530197691 | admin@yfdchem.cn | China | 105 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
| Tianjin Zhongxin Chemtech Co., Ltd. | +86-022-66880623 +8618622897568 | sales@tjzxchem.com | China | 563 | 58 |
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View Lastest Price from tert-Butyl methyl ether manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-11-13 | tert-Butyl methyl ether
1634-04-4
|
US $10.00 / KG | 1KG | 99% | 10 mt | Hebei Weibang Biotechnology Co., Ltd | |
 |
2024-10-29 | Methyl tert-butyl ether
1634-04-4
|
US $0.00 / kg | 20kg | 99.0% | 20 tons | Qingdao RENAS Polymer Material Co., Ltd. | |
 |
2024-10-11 | Tert-Butyl Methyl Ether
1634-04-4
|
US $3.70 / kg | 10kg | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD |
-
- tert-Butyl methyl ether
1634-04-4
- US $10.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
-
- Methyl tert-butyl ether
1634-04-4
- US $0.00 / kg
- 99.0%
- Qingdao RENAS Polymer Material Co., Ltd.
-
- Tert-Butyl Methyl Ether
1634-04-4
- US $3.70 / kg
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD