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4-Nitrophenylboronic acid

4-Nitrophenylboronic acid structure

CAS No.: 24067-17-2

Chemical Name:: 4-Nitrophenylboronic acid

Synonyms: RARECHEM AH PB 0141;4-Borononitrobenzene;4-nitrophenylboric acid;P-NITROPHENYLBORONIC ACID;4-NITROPHENYLBORONIC ACID;(4-Nitrophenyl)boronicaci;4-NITROBENZENEBORONIC ACID;p-nitro-benzeneboronic acid;B-(4-nitrophenyl)boronic acid;4-Nitrophenylboronic acid ,97%

CBNumber:: CB3116883

Molecular Formula:: C6H6BNO4

Molecular Weight:: 166.93

MDL Number:: MFCD00161360

MOL File:: 24067-17-2.mol

MSDS File:: SDS

Last updated:2023-12-25 13:23:17

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4-Nitrophenylboronic acid Properties

Melting point	285-290°C (dec.)
Boiling point	373.7±44.0 °C(Predicted)
Density	1.40±0.1 g/cm3(Predicted)
storage temp.	Inert atmosphere,Room Temperature
solubility	DMF: 15 mg/ml; DMSO: 15 mg/ml; Ethanol: 15 mg/ml; Ethanol:PBS (pH 7.2) (1:5): 0.16 mg/ml
pka	7.04±0.10(Predicted)
form	Crystalline Powder
color	White to yellow
Water Solubility	Slightly soluble in water.
InChIKey	NSFJAFZHYOAMHL-UHFFFAOYSA-N
CAS DataBase Reference	24067-17-2(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335-H302

Precautionary statements

P261-P280a-P304+P340-P305+P351+P338-P405-P501a

Hazard Codes

Risk Statements

Safety Statements

26-36/37/39-24/25

WGK Germany

Hazard Note

Harmful

HS Code

29319090

NFPA 704

	1
2		0

4-Nitrophenylboronic acid price More Price(41)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	673854	4-Nitrophenylboronic acid ≥95.0%	24067-17-2	1g	$83.1	2024-03-01	Buy
Sigma-Aldrich	673854	4-Nitrophenylboronic acid ≥95.0%	24067-17-2	5g	$191	2024-03-01	Buy
TCI Chemical	N0812	4-Nitrophenylboronic Acid (contains varying amounts of Anhydride)	24067-17-2	1g	$28	2024-03-01	Buy
TCI Chemical	N0812	4-Nitrophenylboronic Acid (contains varying amounts of Anhydride)	24067-17-2	5g	$110	2024-03-01	Buy
Alfa Aesar	H27767	4-Nitrobenzeneboronic acid, 95%	24067-17-2	1g	$63.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
673854	1g	$83.1	Buy
673854	5g	$191	Buy
N0812	1g	$28	Buy
N0812	5g	$110	Buy
H27767	1g	$63.65	Buy

4-Nitrophenylboronic acid Chemical Properties,Uses,Production

Description

4-Nitrobenzeneboronic acid is an arylboronic acid building block that has been used in the synthesis of phenols.

Chemical Properties

White to brown powder or crystal

Uses

Reagent used for

Ligand-free palladium-catalyzed Suzuki-Miyaura cross-couplings
Ruthenium catalyzed direct arylation of benzylic sp³ carbons of acyclic amines
Diels-Alder or C-H activation reactions
Regioselective Suzuki-Miyaura coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulations
N-arylation of phenylurea using copper acetylacetonate catalyst
Environmentally benign one-pot synthesis through a double arylation process
Copper-mediated cyanations
copper-catalyzed arylations
Regioselective glycosylations
Suzuki couplings followed by arylations
X-ray absorption on rhodium-grafted hydrotalcite catalyst for heterogeneous 1,4-addition reaction of organoboron reagents to electron deficient olefins

Reagent used in Preparation of

Combretastatin analogs as potential antitumor agents
Human immunodeficiency virus (HIV) protease inhibitors with antiviral activities against drug-resistant viruses

Uses

suzuki reaction

Uses

4-Nitrophenylboronic Acid is a useful synthetic intermediate. It is a reagent used for ligand-free palladium-catalyzed Suzuki-Miyaura cross-couplings, Ruthenium catalyzed direct arylation of benzylic sp3 carbons of acyclic amines and Diels-Alder or C-H activation reactions.

4-Nitrophenylboronic acid synthesis

Synthesis of 4-Nitrophenylboronic acid from Methanol and BORANE-DIISOPROPYLAMINE and 1-Bromo-4-nitrobenzene

4-Nitrophenylboronic acid Preparation Products And Raw materials

Raw materials

1-Bromo-4-nitrobenzene [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Cuprous iodide Toluene Bis(pinacolato)diboron

Tetrahydrofuran Hydrochloric acid Triisopropyl borate Sodium periodate Potassium Acetate

n-Butyllithium 1-Iodo-4-nitrobenzene

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Preparation Products

4-Nitrophenylboronic acid pinacol ester 4-Nitrobiphenyl 5-(4-NITRO-PHENYL)-2H-TETRAZOLE

4-Nitrophenylboronic acid Suppliers

Global( 268)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Xinsheng New Material Technology Co., LTD.	+86-16632316109	xinshengkeji@xsmaterial.com	China	1085	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20284	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29791	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18751	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21634	55
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1803	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32957	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29880	58
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	17777	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22963	58

Supplier	Advantage
Hebei Xinsheng New Material Technology Co., LTD.	58
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Shanghai Time Chemicals CO., Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Accela ChemBio Inc.	58
Hubei xin bonus chemical co. LTD	58

View Lastest Price from 4-Nitrophenylboronic acid manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-12-26	4-Nitrophenylboronic acid 24067-17-2	US $100.00-1.00 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2023-12-02	4-Nitrophenylboronic acid 24067-17-2	US $0.00-0.00 / kg	1kg	99.9%	30000 Kg	Hebei Xinsheng New Material Technology Co., LTD.
2023-10-31	4-Nitrophenylboronic acid 24067-17-2	US $35.00-25.00 / kg	1kg	99%	20 Ton	Hebei Xinsheng New Material Technology Co., LTD.

4-Nitrophenylboronic acid
24067-17-2
US $100.00-1.00 / KG
99%
Henan Fengda Chemical Co., Ltd

4-Nitrophenylboronic acid
24067-17-2
US $0.00-0.00 / kg
99.9%
Hebei Xinsheng New Material Technology Co., LTD.

4-Nitrophenylboronic acid
24067-17-2
US $35.00-25.00 / kg
99%
Hebei Xinsheng New Material Technology Co., LTD.

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Boronic acid, B-(4-nitrophenyl)- p-nitro-benzeneboronic acid 4-Nitrophenylboronic acid >=95.0% B-(4-nitrophenyl)boronic acid 4-NITROPHENYLBORONIC ACID 4-NITROBENZENEBORONIC ACID RARECHEM AH PB 0141 P-NITROPHENYLBORONIC ACID 4-Nitrophenylboronic Acid (contains varying amounts of Anhydride) 4-Nitrophenylboronic acid ,97% 4-Borononitrobenzene VLOOKUP(C11,[1]Export!$D:$H,5,0) (4-Nitrophenyl)boronicaci 4-Nitrophenylboronic acid ISO 9001：2015 REACH 4-nitrophenylboric acid 24067-17-2 171634-83-3 4067-17-2 Aryl Boronic Acids and Derivatives Boronic Acids Organometallic Reagents Boronate Ester Boronic Acid Potassium Trifluoroborate blocks BoronicAcids B (Classes of Boron Compounds) Aryl Boronic Acids Boronic Acids and Derivatives Substituted Boronic Acids Boronic acids