Methyl propiolate
- CAS No.
- 922-67-8
- Chemical Name:
- Methyl propiolate
- Synonyms
- 4-Methoxy-4-oxobut-2-ynoic acid;PROPYNOIC ACID, METHYL ESTER;HCequivCCOOCH3;METHYL PROPYNOATE;METHYL PROPIOLATE;Methyl propinoate;METHYPROPIOLATE,99%;Methyl propargylate;MethylPropiolate>Sucrose Impurity 14
- CBNumber:
- CB3155439
- Molecular Formula:
- C4H4O2
- Molecular Weight:
- 84.07
- MDL Number:
- MFCD00008572
- MOL File:
- 922-67-8.mol
- MSDS File:
- SDS
Melting point | 171-173 °C |
---|---|
Boiling point | 103-105 °C (lit.) |
Density | 0.945 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | 50 °F |
storage temp. | Inert atmosphere,2-8°C |
solubility | Chloroform (Sparingly), Methanol (Sparingly) |
form | Liquid |
Specific Gravity | 0.9450 |
color | Clear colorless |
Water Solubility | Not miscible in water. |
BRN | 605462 |
Stability | Stable. Highly flammable. Incompatible with strong oxidizing agents, bases, acids. |
InChIKey | IMAKHNTVDGLIRY-UHFFFAOYSA-N |
CAS DataBase Reference | 922-67-8(CAS DataBase Reference) |
FDA UNII | T88NXO102K |
NIST Chemistry Reference | 2-Propynoic acid, methyl ester(922-67-8) |
UNSPSC Code | 12352100 |
NACRES | NA.22 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS02,GHS07 |
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Signal word | Danger | |||||||||
Hazard statements | H225-H315-H319-H335 | |||||||||
Precautionary statements | P210-P233-P240-P241-P303+P361+P353-P305+P351+P338 | |||||||||
Hazard Codes | F,Xi | |||||||||
Risk Statements | 11-36/37/38-36 | |||||||||
Safety Statements | 26-36-36/37/39-23-16-33-7/9 | |||||||||
RIDADR | UN 3272 3/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | UE0050000 | |||||||||
F | 19 | |||||||||
Hazard Note | Highly Flammable/Harmful | |||||||||
HazardClass | 3 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29161980 | |||||||||
NFPA 704 |
|
Methyl propiolate price More Price(38)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 171859 | Methyl propiolate 99% | 922-67-8 | 2.5g | $55.6 | 2024-03-01 | Buy |
Sigma-Aldrich | 171859 | Methyl propiolate 99% | 922-67-8 | 10g | $110 | 2024-03-01 | Buy |
TCI Chemical | P0528 | Methyl Propiolate >98.0%(GC) | 922-67-8 | 5mL | $40 | 2024-03-01 | Buy |
TCI Chemical | P0528 | Methyl Propiolate >98.0%(GC) | 922-67-8 | 25mL | $162 | 2024-03-01 | Buy |
Alfa Aesar | A14743 | Methyl propiolate, 99% | 922-67-8 | 5g | $59.1 | 2024-03-01 | Buy |
Methyl propiolate Chemical Properties,Uses,Production
Chemical Properties
colourless to light yellow liquid
Uses
Methyl propiolate was used in the synthesis of polysubstituted 3-arylaminoacrylate and tetrahydropyrimidin-2-one derivatives. It was also used as a thiol derivatizing agent for capillary electrophoresis.
General Description
Methyl Propiolate is an α,β-unsaturated ester that can undergo Diels-Alder and various other cycloaddition reactions, Michael additions, acetylide formation, halogen addition, as well as a range of cyclization reactions to produce heterocycles and aromatic compounds.
storage
methyl and ethyl propiolate are lachrymatory liquids; handle in a well-ventilated fume hood.
Purification Methods
Purify the propiolate by fractional distillation and collecting the middle fraction, note that propiolic acid has a high b [144o(dec)/760mm]. [Beilstein 2 IV 1688.] LACHRYMATORY.
Methyl propiolate Preparation Products And Raw materials
Raw materials
Preparation Products
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Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Chuanghai Biotechnology Co., Ltd | +8615531157085 | abby@chuanghaibio.com | China | 8808 | 58 |
Hebei Mujin Biotechnology Co.,Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12809 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5868 | 58 |
Hebei Chuanghai Biotechnology Co., Ltd | +8615531151365 | mina@chuanghaibio.com | China | 18137 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29730 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21628 | 55 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +8618949832763 | info@tnjchem.com | China | 2986 | 55 |
Changzhou Ansciep Chemical Co., Ltd. | +86 519 86305871 | sales@ansciepchem.com | CHINA | 4241 | 58 |
Chengdu Feibo Pharm Technology Co., Ltd | +86 028-84641798 15982321820 | abby@arkpharm.com | China | 10922 | 58 |
Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
Related articles
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- Methyl propiolate(MP) is an organic compound with the formula HC2CO2CH3. It is the methyl ester of propiolic acid, the simples....
- Nov 15,2019
View Lastest Price from Methyl propiolate manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2025-04-23 | Methyl propiolate
922-67-8
|
US $1.00 / KG | 1KG | 99% | 10 mt | Hebei Chuanghai Biotechnology Co., Ltd | |
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2025-04-15 | Methyl propiolate
922-67-8
|
US $0.00-0.00 / KG | 1KG | 99% | 500000kg | Hebei Chuanghai Biotechnology Co., Ltd | |
![]() |
2025-03-21 | Methyl propiolate
922-67-8
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mujin Biotechnology Co.,Ltd |
-
- Methyl propiolate
922-67-8
- US $1.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- Methyl propiolate
922-67-8
- US $0.00-0.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co., Ltd
-
- Methyl propiolate
922-67-8
- US $0.00 / KG
- 99%
- Hebei Mujin Biotechnology Co.,Ltd
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