2β,14β-Ethano-15,20-didehydro-15,20-dideethyl-2,7α-dihydro-11-methoxycorynan-14-acetic acid methyl ester

CAS No.
2447-60-1
Chemical Name:
2β,14β-Ethano-15,20-didehydro-15,20-dideethyl-2,7α-dihydro-11-methoxycorynan-14-acetic acid methyl ester
Synonyms
Schizophyllin;Schizophylline;2β,14β-Ethano-15,20-didehydro-15,20-dideethyl-2,7α-dihydro-11-methoxycorynan-14-acetic acid methyl ester;3H-Cyclopent[ij]indolo[2,3-a]quinolizine-13a(13bH)-acetic acid, 5,6,6a,11,12,13-hexahydro-9-methoxy-, methyl ester, (6aR,11aR,13aS,13bS)-
CBNumber:
CB32136627
Molecular Formula:
C21H26N2O3
Molecular Weight:
354.44
MDL Number:
MOL File:
2447-60-1.mol

2β,14β-Ethano-15,20-didehydro-15,20-dideethyl-2,7α-dihydro-11-methoxycorynan-14-acetic acid methyl ester Properties

Melting point 129-130°C

2β,14β-Ethano-15,20-didehydro-15,20-dideethyl-2,7α-dihydro-11-methoxycorynan-14-acetic acid methyl ester Chemical Properties,Uses,Production

Description

The roots and bark of Schizozygia caffaeoides (Boj.) Baili. also furnish this alkaloid which has the structure given above. It is 1aevorotatory with [α]24D - 64° (c 1.0, CHCI3) and gives an ultraviolet spectrum consisting of two absorption maxima at 251 and 299 mil.

References

Renner, Kernweisz., Experientia, 19,244 (1963)
Structure:
Renner., Lloydia, 27,406 (1964)

2β,14β-Ethano-15,20-didehydro-15,20-dideethyl-2,7α-dihydro-11-methoxycorynan-14-acetic acid methyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

2β,14β-Ethano-15,20-didehydro-15,20-dideethyl-2,7α-dihydro-11-methoxycorynan-14-acetic acid methyl ester Schizophyllin Schizophylline 3H-Cyclopent[ij]indolo[2,3-a]quinolizine-13a(13bH)-acetic acid, 5,6,6a,11,12,13-hexahydro-9-methoxy-, methyl ester, (6aR,11aR,13aS,13bS)- 2447-60-1