11-Methoxy-1-methyl-9,10-[methylenebis(oxy)]lycorenan-5α,7α-diol

CAS No.
905-37-3
Chemical Name:
11-Methoxy-1-methyl-9,10-[methylenebis(oxy)]lycorenan-5α,7α-diol
Synonyms
Krigeine;11-Methoxy-1-methyl-9,10-[methylenebis(oxy)]lycorenan-5α,7α-diol;9,10-methanediyldioxy-11-methoxy-1-methyl-lycoran-4(12)-ene-5α,7α-diol
CBNumber:
CB32246821
Molecular Formula:
C18H21NO6
Molecular Weight:
347.36244
MDL Number:
MOL File:
905-37-3.mol

11-Methoxy-1-methyl-9,10-[methylenebis(oxy)]lycorenan-5α,7α-diol Properties

Melting point 209-210° (dec.).

11-Methoxy-1-methyl-9,10-[methylenebis(oxy)]lycorenan-5α,7α-diol Chemical Properties,Uses,Production

Description

This alkaloid, which forms colourless crystals from Me2CO, occurs widely among the Amaryllidaceous species. It is dextrorotatory with [α]25D+ 234° (c 0.15, CHCI3). It contains a methylenedioxy groups, a methoxyl, two hydroxyl and a methylimino group in the molecule.

References

Briggs et al., J. Amer. Chem. Soc., 78, 2899 (1956)
Jeffs, Hawksworth., Tetrahedron Lett., 217 (1963)

11-Methoxy-1-methyl-9,10-[methylenebis(oxy)]lycorenan-5α,7α-diol Preparation Products And Raw materials

Raw materials

Preparation Products

11-Methoxy-1-methyl-9,10-[methylenebis(oxy)]lycorenan-5α,7α-diol Krigeine 9,10-methanediyldioxy-11-methoxy-1-methyl-lycoran-4(12)-ene-5α,7α-diol 905-37-3