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Biphenyl-4,4'-dicarboxylic acid

CAS No.
787-70-2
Chemical Name:
Biphenyl-4,4'-dicarboxylic acid
Synonyms
DK7488;usafdo-69;Biphenyl-4,4;BIBENZOIC ACID;-4,4’-dicarboxyL;4,4'-DIPHENIC ACID;4,4'-Diphenit acid;P,P'-DIPHENIC ACID;4,4'-BIBENZOIC ACID;4,4'-DIBENZOIC ACID
CBNumber:
CB3236752
Molecular Formula:
C14H10O4
Molecular Weight:
242.23
MDL Number:
MFCD00002554
MOL File:
787-70-2.mol
MSDS File:
SDS
Last updated:2024-12-18 14:08:52

Biphenyl-4,4'-dicarboxylic acid Properties

Melting point >300 °C(lit.)
Boiling point 482.5±38.0 °C(Predicted)
Density 1.347±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
pka 3.77±0.10(Predicted)
form Powder
color White to light beige
BRN 523308
InChI InChI=1S/C14H10O4/c15-13(16)11-5-1-9(2-6-11)10-3-7-12(8-4-10)14(17)18/h1-8H,(H,15,16)(H,17,18)
InChIKey NEQFBGHQPUXOFH-UHFFFAOYSA-N
SMILES C1(C2=CC=C(C(O)=O)C=C2)=CC=C(C(O)=O)C=C1
CAS DataBase Reference 787-70-2(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 5D8ABY24N2
EPA Substance Registry System [1,1'-Biphenyl]-4,4'-dicarboxylic acid (787-70-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-20/21/22
Safety Statements  26-37/39-36
WGK Germany  3
RTECS  DV2975000
HS Code  29173990
NFPA 704
1
2 0

Biphenyl-4,4'-dicarboxylic acid price More Price(38)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 225266 Biphenyl-4,4′-dicarboxylic acid 97% 787-70-2 5g $117 2024-03-01 Buy
Sigma-Aldrich 225266 Biphenyl-4,4′-dicarboxylic acid 97% 787-70-2 25g $402 2024-03-01 Buy
TCI Chemical B1191 4,4'-Biphenyldicarboxylic Acid >97.0%(T) 787-70-2 5g $83 2024-03-01 Buy
TCI Chemical B1191 4,4'-Biphenyldicarboxylic Acid >97.0%(T) 787-70-2 25g $245 2024-03-01 Buy
Strem Chemicals 08-0175 [1,1'-Biphenyl]-4,4'-dicarboxylic acid, min. 98% 787-70-2 5g $68 2024-03-01 Buy
Product number Packaging Price Buy
225266 5g $117 Buy
225266 25g $402 Buy
B1191 5g $83 Buy
B1191 25g $245 Buy
08-0175 5g $68 Buy

Biphenyl-4,4'-dicarboxylic acid Chemical Properties,Uses,Production

Chemical Properties

White to light beige powder

Uses

Dendrimer building block.

Purification Methods

The dicarboxylic acid is a white amorphous or microcrystalline substance which does not melt or sublime. It is best purified by precipitation of an aqueous alkaline solution with mineral acid, washing well with H2O and drying in vacuo at 100o. It is characterized by conversion to diphenyl-4,4’-dicarbonyl chloride (with PCl5 [Work J Chem Soc 1317 1940], or by phase transfer catalysis with SOCl2 + BuEt3N+Cl-in 1,2-dichloroethane [Burdett Synthesis 441 1991]) which crystallises from *C6H6 with m 184o. The di-acid chloride gives the dimethyl ester with MeOH, and has m 215-217o (plates from MeOH, m’s of 214o and 224o were also reported). The diethyl ester is similarly prepared with EtOH and has m 122o (from EtOH). [Beilstein 9 II 665, 9 III 4519, 9 IV 3563.]

613-33-2
787-70-2
Synthesis of Biphenyl-4,4'-dicarboxylic acid from 4,4'-Dimethylbiphenyl

Biphenyl-4,4'-dicarboxylic acid Preparation Products And Raw materials

Global( 452)Suppliers
Supplier Tel Email Country ProdList Advantage
Dalian Richfortune Chemicals Co., Ltd
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+8618071643627 rze2024@163.com China 226 58
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+86 13288715578 +8613288715578 sales@hbmojin.com China 12835 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5857 58
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+8617732866630 bess@weibangbio.com China 18151 58
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+86-(0)57185586718 +86-13336195806 sales@capot.com China 29791 60
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+86-371-66670886 info@dakenam.com China 18751 58
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+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1803 55

View Lastest Price from Biphenyl-4,4'-dicarboxylic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Biphenyl-4,4'-dicarboxylic acid pictures 2024-12-13 Biphenyl-4,4'-dicarboxylic acid
787-70-2
US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
Biphenyl-4,4'-dicarboxylic acid pictures 2024-10-25 Biphenyl-4,4'-dicarboxylic acid
787-70-2
US $20.00-1.00 / kg 1kg 0.99 30 tons Hebei Yanxi Chemical Co., Ltd.
Biphenyl-4,4'-dicarboxylic acid pictures 2024-10-24 Biphenyl-4,4'-dicarboxylic acid
787-70-2
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Weibang Biotechnology Co., Ltd
4,4'-BIPHENYLDICARBOXYLIC ACID 4,4'-BIBENZOIC ACID 4,4'-DICARBOXYDIPHENYL 4,4'-DIBENZOIC ACID 4,4'-BISBENZOIC ACID 4,4'-DIPHENIC ACID 4,4'-DIPHENYLDICARBOXYLIC ACID DIPHENYL-4,4'-DICARBOXYLIC ACID 4,4'-Dicarboxybiphenyl 4-(4-Carboxyphenyl)benzoic acid BIPHENYL-4,4-DICAROXYLIC ACID / 4,4-DIPHENIT ACID 4 4-DICARBOXYDIPHENYL 97% 4,4''-BIPHENYLDICARBOXYLIC ACID 99% 4 4-DIPHENYLDICARBOXYLIC ACID 97% 4,4'-Diphenit acid 4,4'-Biphenyldicarboxylic acid,98% Biphenyl-4,4'-dicarb 4,4'-Bibenzoic Acid 4,4'-Dibenzoic Acid 4,4'-Diphenyldicarboxylic Acid 4,4'-Biphenyl dicarboxylic acid (BPDA) Biphenyl-4,4'-dicarboxylic acid 97% Biphenyl-4,4'-dicarboxylic Acid, 97+% 4, 4 - biphenyl 2 forMic acid Biphenyl-4,4'-dicarboxylic acid SynonyMs 4,4'-Biphenyldicarboxylic acid 4-phenylcyclohexa-2,5-diene-1,1-dicarboxylic Biphenyl-4,4 4-phenylcyclohexa-2,5-diene-1,1-dicarboxylic acid Biphenyl-4,4'-dicarboxylic acid Vetec(TM) reagent grade, 97% LABOTEST-BB LT00452839 BIBENZOIC ACID BIPHENYL-4,4'-DICARBOXYLIC ACID P,P'-DIPHENIC ACID P,P'-BIPHENYLDICARBOXYLIC ACID RARECHEM AL BO 0295 (1,1’-Biphenyl)-4,4’-dicarboxylicacid [1,1’-biphenyl]-4,4’-dicarboxylicacid usafdo-69 4-BiphenyldicarboxylicAcid 4-phenylcyclohexa-2,4-diene-1,1-dicarboxylic acid [1,1'-Biphenyl]-4,4'-dicarboxylic acid, min. 98% 4,4'-Biphenyldicarboxylic Acid > Biphenyl-4,4-Dicarboxylic Acid,>98% -4,4’-dicarboxyL Big Discount Purity 99% Biphenyl-4, 4′ -Dicarboxylic Acid CAS?787-70-2?with Best Quality DK7488 1,1'-Biphenyl]-4,4'-dicarboxylic acid (9CI, ACI) biphenyl-4,4'-dicarboxylic acid 1,1'-Biphenyl]-4,4'-dicarboxylic acid 4,4'-Bibenzoic acid 1,1'-bipheny1]-4,4'-dicarboxylic acid 787-70-2 HO2CC6H4C6H4CO2H C13 to C42+ Carboxylic Acids Carbonyl Compounds Building Blocks Reagent for High-Performance Polymer Research Biphenyls (for High-Performance Polymer Research) Organic Building Blocks