ChemicalBook >> CAS DataBase List >>2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
- CAS No.
- 898838-07-8
- Chemical Name:
- 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex
- Synonyms
- piperidinyL;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride;Magnesate(1-), dichloro(2,2,6,6-tetramethylpiperidinato)-, lithium (1:1);2,2,6,6-tetramethylpiperidin-1-ide;lithium,magnesium,2,2,6,6-tetramethylpiperidin-1-ide,dichloride;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution;2,2,6,6-tetramethylpiperidinato)magnesate lithium;2,2,6,6-Tetramethylpiperidinylmagnesium chloride l;2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chl;Dichloro(2,2,6,6-tetramethylpiperidinato)magnesate(1-) lithium
- CBNumber:
- CB32489918
- Molecular Formula:
- C9H18Cl2LiMgN
- Molecular Weight:
- 242.4
- MDL Number:
- MFCD12546030
- MOL File:
- 898838-07-8.mol
- MSDS File:
- SDS
Last updated:2025-01-27 09:38:02
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS02,GHS05,GHS07,GHS08 |
|---|---|
| Signal word | Danger |
| Hazard statements | H225-H302-H314-H335-H351-H361d |
| Precautionary statements | P210-P260-P280-P305+P351+P338-P370+P378-P403+P235 |
| Hazard Codes | F,C |
| Risk Statements | 63-11-14-19-34-37-40 |
| Safety Statements | 16-26-36/37/39-45 |
| RIDADR | UN 3399 4.3/PG 1 |
| WGK Germany | 3 |
| HS Code | 29333990 |
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex price More Price(3)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 703540 | 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution 1.0 M in THF/toluene | 898838-07-8 | 4x25ml | $184 | 2024-03-01 | Buy |
| Sigma-Aldrich | 703540 | 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution 1.0 M in THF/toluene | 898838-07-8 | 100ml | $216 | 2024-03-01 | Buy |
| Sigma-Aldrich | 703540 | 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution 1.0 M in THF/toluene | 898838-07-8 | 500ml | $668 | 2024-03-01 | Buy |
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Chemical Properties,Uses,Production
Uses
2,2,6,6-Tetramethylpiperidinylmagnesium Chloride Lithium Chloride Complex is used in preparation of Pyridazinones as herbicides. Also, used in preparation of MCL-1 inhibitors useful for treatment of cancer.
Uses
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.
Uses
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex deprotonations using Knochel-Hauser-Base
reaction suitability
reaction type: Grignard Reaction
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 89)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
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| Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 8497 | 58 |
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| LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43340 | 58 |
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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chl
2,2,6,6-Tetramethylpiperidinylmagnesium chloride l
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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex 1.0 M solution in THF
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution
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lithium,magnesium,2,2,6,6-tetramethylpiperidin-1-ide,dichloride
piperidinyL
2,2,6,6-tetramethylpiperidin-1-ide
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride
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2,2,6,6-TETRAMETHYLPIEPERIDINYL MAGNESIUM CHLORIDE, LITHIUM CHLORIDE COMPLEX 1.0 M in THF
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2,2,6,6-tetramethylpiperidinato)magnesate lithium
Magnesium dichloride (2,2,6,6-tetramethylpiperidine) lithium salt
898838-07-8
899938-07-8
C9H18Cl2LiMgN
C9H18Cl2MgNLi
Chemical Synthesis
Grignard Reagents
Heteroaryl
Organometallic Reagents