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SILICON TETRAACETATE

CAS No.
562-90-3
Chemical Name:
SILICON TETRAACETATE
Synonyms
SiliconAcetate;TETRAACETOXYSILANE;SILICON (IV) ACETATE;SILICON TETRAACETATE;Silicon(IV)tetraacetate;Silicon tetraacetate 98%;triacetyloxysilyl acetate;Tetraacetyl orthosilicate;Silicon(IV)acetate,min.95%;Tetraacetic acid silicon salt
CBNumber:
CB3263967
Molecular Formula:
C8H12O8Si
Molecular Weight:
264.26
MDL Number:
MFCD00026184
MOL File:
562-90-3.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

SILICON TETRAACETATE Properties

Melting point 111-115 °C(lit.)
Boiling point 148 °C5 mm Hg(lit.)
Density 1,18 g/cm3
vapor density >1 (vs air)
Flash point >110°C
storage temp. -20°C
solubility Soluble in acetone and benzene.
form crystal
color white
Water Solubility soluble acetone, benzene [MER06]
Sensitive Moisture Sensitive
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
Merck 14,8498
BRN 994868
CAS DataBase Reference 562-90-3(CAS DataBase Reference)
FDA UNII VZ7LP47EPP
EPA Substance Registry System Silicon tetraacetate (562-90-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
10
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29159000
NFPA 704
1
3 0

SILICON TETRAACETATE price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 345156 Silicon tetraacetate 98% 562-90-3 10g $55.6 2024-03-01 Buy
Sigma-Aldrich 345156 Silicon tetraacetate 98% 562-90-3 100g $225 2024-03-01 Buy
Alfa Aesar 014703 Silicon(IV) acetate 562-90-3 50g $143 2024-03-01 Buy
Alfa Aesar 014703 Silicon(IV) acetate 562-90-3 250g $532 2023-06-20 Buy
Strem Chemicals 93-1443 Silicon(IV) acetate, min. 95% 562-90-3 25g $69 2024-03-01 Buy
Product number Packaging Price Buy
345156 10g $55.6 Buy
345156 100g $225 Buy
014703 50g $143 Buy
014703 250g $532 Buy
93-1443 25g $69 Buy

SILICON TETRAACETATE Chemical Properties,Uses,Production

Introduction

Tetraacetoxysilane is a clear to yellowish liquid with acrid odor of acetic acid (vinegar). It hydrolyzes in the presence of moisture (acetic acid is released) to form silanols, which can react with themselves to pro-duce siloxanes or bind to inorganic substrates.

Chemical Properties

Off-white crystalline solid

Uses

Silicon tetraacetate is used in the preparation of silicon dioxide thin films by a direct photochemical vapor deposition method. It serves as a precursor to prepare silicon complexes with monofunctional bidentate Schiff bases. It is also used as an alternative to silicon hydride and alkoxide for low-temperature silicon dioxide production. Further, it reacts with ethanol in the absence of water to get silica gel and ethyl acetate. In addition, it is employed as a sol-gel precursor.

General Description

Silicon tetraacetate is an alternative to silicon hydride and alkoxide for low-temperature SiO2 production. Silicon tetraacetate reacts with ethanol in absence of water to form silica gel and ethyl acetate. Silicon tetraacetate is reported as a sol-gel precursor.

Purification Methods

It can be crystallised from mixtures of CCl4 and pet ether or Et2O, or from acetic anhydride and then dried in a vacuum desiccator over KOH. Ac2O adheres to the crystals and is removed first by drying at room temperature, then at 100o for several hours. It is soluble in Me2CO, is very hygroscopic and effervesces with H2O. It decomposes at 160-170o. [Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 701 1963, Beilstein 2 H 171.]

SILICON TETRAACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 148)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18779 58
Henan Tianfu Chemical Co.,Ltd.
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career henan chemical co
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City Chemical LLC
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+86-29-87569266 15319487004 1015@dideu.com China 4084 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9636 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34553 58

View Lastest Price from SILICON TETRAACETATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
TETRAACETOXYSILANE pictures 2024-11-05 TETRAACETOXYSILANE
562-90-3
US $0.00 / KG 1KG 98.00% 209-239-7 Shanghai Daken Advanced Materials Co.,Ltd
SILICON TETRAACETATE pictures 2019-07-06 SILICON TETRAACETATE
562-90-3
US $1.00 / KG 1G 98% 1000KG Career Henan Chemical Co
Silicon(IV) Acetate, Anhydrous Tetraacetyl orthosilicate Silicon(iv)acetate, 93%, tech. Silicon(IV) acetate, min. 95% Silicic tetraacetic acid tetraanhydride Tetraacetic acid silicon salt Silicon(IV) Acetate, Anhydrous 99% Silicon tetraacetate 98% TETRAACETOXYSILANE SILICON TETRAACETATE SILICON (IV) ACETATE Silicon(IV) acetate, tech., 93% SiliconTetraacetate(techgrade)(Highpurityalsoavailable) SiliconAcetate Silicon(IV)acetate,min.95% Aceticacid,tetraanhydridewithsilicicacid aceticacid,tetraanhydridewithsilicicacid(h4sio4) Silicon(IV)tetraacetate Acetic acid,1,1',1'',1'''-tetraanhydride with silicic acid (H4SiO4) Silicon tetraacetate, anhydrous 99% triacetyloxysilyl acetate 562-90-3 526-90-3 C8H12O8Si SiOCOCH34 SiOOCCH34 C8 to C9 Carbonyl Compounds Building Blocks Organic Building Blocks Organosilicon Others Organometallic Reagents Esters metal acetate salt Building Blocks C8 to C9 Carbonyl Compounds Chemical Synthesis Organic Building Blocks Acetoxy Silanes Crosslinkers Crosslinking Agents C8 to C9 Carbonyl Compounds Esters