Methyl 2-furoate
- CAS No.
- 611-13-2
- Chemical Name:
- Methyl 2-furoate
- Synonyms
- METHYL FURAN-2-CARBOXYLATE;2-FURANCARBOXYLIC ACID METHYL ESTER;MEFAT;FEMA 2703;2-METHYLFUROATE;Methyle furoate;METHYL 2-FUROATE;METHYL PYROMUCATE;Methyl 2-furanoate;RARECHEM AL BF 0007
- CBNumber:
- CB3306772
- Molecular Formula:
- C6H6O3
- Molecular Weight:
- 126.11
- MDL Number:
- MFCD00003236
- MOL File:
- 611-13-2.mol
- MSDS File:
- SDS
Boiling point | 181 °C (lit.) |
---|---|
Density | 1.179 g/mL at 25 °C (lit.) |
FEMA | 2703 | METHYL 2-FUROATE |
refractive index |
n |
Flash point | 164 °F |
storage temp. | Inert atmosphere,Room Temperature |
solubility | Chloroform (Slightly), Methanol (Slightly) |
form | Liquid |
color | Clear pale yellow to brown |
Odor | fruity, mushroom-like odor |
Odor Type | fungal |
Water Solubility | slightly soluble |
Sensitive | Lachrymatory |
JECFA Number | 746 |
Merck | 14,4307 |
BRN | 111110 |
LogP | 0.99 |
CAS DataBase Reference | 611-13-2(CAS DataBase Reference) |
Substances Added to Food (formerly EAFUS) | METHYL 2-FUROATE |
FDA UNII | O9A8D29YDE |
NIST Chemistry Reference | Methyl 2-furoate(611-13-2) |
EPA Substance Registry System | 2-Furancarboxylic acid, methyl ester (611-13-2) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS06 |
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Signal word | Danger | |||||||||
Hazard statements | H301-H312-H315-H319-H335 | |||||||||
Precautionary statements | P280-P301+P310+P330-P302+P352+P312-P305+P351+P338 | |||||||||
Hazard Codes | Xn,Xi | |||||||||
Risk Statements | 36/37/38-21/22-22 | |||||||||
Safety Statements | 26-36-36/37/39 | |||||||||
RIDADR | UN 2810 6.1/PG 3 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | LV1950000 | |||||||||
Hazard Note | Irritant | |||||||||
TSCA | Yes | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29321900 | |||||||||
NFPA 704 |
|
Methyl 2-furoate price More Price(32)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | W270318 | Methyl 2-furoate ≥98%, FG | 611-13-2 | sample-k | $54.6 | 2024-03-01 | Buy |
Sigma-Aldrich | W270318 | Methyl 2-furoate ≥98%, FG | 611-13-2 | 100g | $75.3 | 2024-03-01 | Buy |
Sigma-Aldrich | W270318 | Methyl 2-furoate ≥98%, FG | 611-13-2 | 1kg | $212 | 2024-03-01 | Buy |
Sigma-Aldrich | W270318 | Methyl 2-furoate ≥98%, FG | 611-13-2 | 5kg | $480 | 2024-03-01 | Buy |
Sigma-Aldrich | 129852 | Methyl 2-furoate 98% | 611-13-2 | 25g | $35.4 | 2024-03-01 | Buy |
Methyl 2-furoate Chemical Properties,Uses,Production
Description
Methyl 2-furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy. May be prepared from 2-furoic acid in methanol solution in the presence of HCL as catalyst (oxidation or Carmizzaro reaction).
Chemical Properties
Methyl furoate has a pleasant, fruity odor similar to mushroom, fungus or tobacco with a sweet, tart, fruity taste that is quite heavy
Chemical Properties
Colorless to light yellow liqui
Occurrence
Reported found in cranberry, guava, baked potato, raisin, papaya, blackberry, baked potato, tomato, cognac, coffee, filbert, peanut, cocoa, passion fruit, almonds, tamarind, soursop, dried bonito, kiwifruit, mountain papaya, wild rice, okra, grape brandy and roasted hazelnut.
Uses
Methyl 2-furoate (Methyl furan-2-carboxylate, Methyl pyromucate) was used to synthesize cis-fused 5-oxofuro[2,3-b]furans. It was also used in the preparation of sesquiterpene lactone.
Uses
Solvent, organic synthesis.
Definition
ChEBI: Methyl 2-Furancarboxylate is a carboxylic ester. It is functionally related to a 2-furoic acid.
Preparation
From 2-furoic acid in methanol solution in the presence of HCl as catalyst (oxidation or Carmizzaro reaction)
Aroma threshold values
Aroma characteristics at 1.0%: musty, sweet caramel, fruity, cocoa, bready and slightly rubbery.
Taste threshold values
Taste characteristics at 20 ppm: brothy, yeasty, caramellic and burnt with a sweet bready, acetoin, buttery nuance
Synthesis Reference(s)
Chemical and Pharmaceutical Bulletin, 37, p. 3225, 1989 DOI: 10.1248/cpb.37.3225
General Description
Methyl 2-furoate has been identified as one of the volatile flavor compounds in tequila, okra, berrycactus and black currant juice.
Safety Profile
Poison by intraperitoneal route. A skin irritant and lachrymator. When heated to decomposition it emits acrid smoke and irritating fumes.
Methyl 2-furoate Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
1of2
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8806 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12833 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531153977 | allison@yan-xi.com | China | 5857 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8617732866630 | bess@weibangbio.com | China | 18151 | 58 |
Shaanxi Haibo Biotechnology Co., Ltd | +undefined18602966907 | qinhe02@xaltbio.com | China | 997 | 58 |
Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 | admin@zlchemi.com | China | 3002 | 58 |
JINING XINHE CHEMICAL CO., LTD | +8615318402391 | sales@xinhepharma.com | China | 809 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18750 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
Hangzhou FandaChem Co.,Ltd. | +8615858145714 | FandaChem@Gmail.com | China | 8978 | 55 |
View Lastest Price from Methyl 2-furoate manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2025-01-03 | Methyl 2-Furoate
611-13-2
|
US $75.00-20.00 / kg | 1kg | 99% | 20ton | Hebei Zhuanglai Chemical Trading Co.,Ltd | ||
2024-12-03 | Methyl 2-furoate
611-13-2
|
US $10.00 / KG | 1KG | 99% | 5tons | Hebei Weibang Biotechnology Co., Ltd | ||
2024-11-18 | Methyl 2-furoate
611-13-2
|
US $29.00 / mL | ≥95% | 10g | TargetMol Chemicals Inc. |
- Methyl 2-Furoate
611-13-2
- US $75.00-20.00 / kg
- 99%
- Hebei Zhuanglai Chemical Trading Co.,Ltd
- Methyl 2-furoate
611-13-2
- US $10.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
- Methyl 2-furoate
611-13-2
- US $29.00 / mL
- ≥95%
- TargetMol Chemicals Inc.