t-Butyl (Methyldiphenylsilyl)acetate

CAS No.
77772-21-5
Chemical Name:
t-Butyl (Methyldiphenylsilyl)acetate
Synonyms
t-Butyl (Methyldiphenylsilyl)acetate;Acetic acid, 2-(methyldiphenylsilyl)-, 1,1-dimethylethyl ester
CBNumber:
CB33072692
Molecular Formula:
C19H24O2Si
Molecular Weight:
312.48
MDL Number:
MOL File:
77772-21-5.mol
MSDS File:
SDS

t-Butyl (Methyldiphenylsilyl)acetate Properties

Boiling point 373.9±34.0 °C(Predicted)
Density 1.02±0.1 g/cm3(Predicted)

t-Butyl (Methyldiphenylsilyl)acetate Chemical Properties,Uses,Production

Physical properties

clear to light yellow liquids.

Uses

vinyl 1,1-dication synthetic equivalent in reactions with Grignard reagents; reagent for Peterson synthesis of α,β-un saturated esters.

Preparation

whereas the direct silylation of the lithium enolate of an ester normally results in the formation of a mixture of the α-silyl ester and the corresponding silyl ketene acetal, the same reaction with methyldiphenylchlorosilane gives exclusively the α-methyldiphenylsilyl ester. This direct C-silylation is the best general route to α-silyl esters.

t-Butyl (Methyldiphenylsilyl)acetate Preparation Products And Raw materials

Raw materials

Preparation Products

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t-Butyl (Methyldiphenylsilyl)acetate Acetic acid, 2-(methyldiphenylsilyl)-, 1,1-dimethylethyl ester 77772-21-5