Benzyltrimethylammonium hydroxide
- CAS No.
- 100-85-6
- Chemical Name:
- Benzyltrimethylammonium hydroxide
- Synonyms
- TRITON B;N,N,N-TriMethyl-1-phenylMethanaMiniuM hydroxide;benzyltrimethyl-ammoniuhydroxide;Benzyltrimethylammonium hydroxide solution;TRITON(R) B;sumquat2311;Triton(rg B;PhCH2NMe3(OH);Triton B (40% in water);Benzyltrimethylammoniumhydrox
- CBNumber:
- CB3318799
- Molecular Formula:
- C10H17NO
- Molecular Weight:
- 167.25
- MDL Number:
- MFCD00008281
- MOL File:
- 100-85-6.mol
- MSDS File:
- SDS
Melting point | 80 °C |
---|---|
Boiling point | 65°C |
Density | 1.059 g/mL at 25 °C |
vapor pressure | 0Pa at 25℃ |
refractive index |
n |
Flash point | 60 °F |
storage temp. | Store below +30°C. |
solubility | Miscible with alcohols, hydrocarbons, aromatic hydrocarbons and halogenated solvents. |
form | Solution |
color | Clear slightly yellow |
explosive limit | 5.50-36.50% |
Water Solubility | Miscible with water, hydrocarbons, aromatic hydrocarbons and halogenated solvents. |
Sensitive | Air Sensitive |
BRN | 3917256 |
Exposure limits |
ACGIH: TWA 200 ppm; STEL 250 ppm (Skin) OSHA: TWA 200 ppm(260 mg/m3) NIOSH: IDLH 6000 ppm; TWA 200 ppm(260 mg/m3); STEL 250 ppm(325 mg/m3) |
InChIKey | NDKBVBUGCNGSJJ-UHFFFAOYSA-M |
LogP | -3 at 20℃ |
CAS DataBase Reference | 100-85-6(CAS DataBase Reference) |
FDA UNII | 8P4488425W |
EPA Substance Registry System | Benzyltrimethylammonium hydroxide (100-85-6) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02,GHS05,GHS06,GHS08 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H225-H301+H311+H331-H314-H370 | |||||||||
Precautionary statements | P210-P233-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
Hazard Codes | C,T,F | |||||||||
Risk Statements | 34-39/23/24/25-23/24/25-11 | |||||||||
Safety Statements | 26-36/37/39-45-46-16-28A-7 | |||||||||
RIDADR | UN 3267 8/PG 2 | |||||||||
WGK Germany | 1 | |||||||||
RTECS | BO8575000 | |||||||||
F | 9-23 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29239000 | |||||||||
Toxicity | LDLo scu-mus: 35 mg/kg JPETAB 28,367,26 | |||||||||
NFPA 704 |
|
Benzyltrimethylammonium hydroxide price More Price(37)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 246034 | Benzyltrimethylammonium hydroxide solution 40 wt. % in H2O | 100-85-6 | 100g | $131 | 2024-03-01 | Buy |
Sigma-Aldrich | 246034 | Benzyltrimethylammonium hydroxide solution 40 wt. % in H2O | 100-85-6 | 500g | $377 | 2024-03-01 | Buy |
TCI Chemical | B0448 | Benzyltrimethylammonium Hydroxide (40% in Methanol) | 100-85-6 | 25mL | $22 | 2024-03-01 | Buy |
TCI Chemical | B0428 | Benzyltrimethylammonium Hydroxide (10% in Water) | 100-85-6 | 25mL | $38 | 2024-03-01 | Buy |
Alfa Aesar | 041717 | Benzyltrimethylammonium hydroxide, 20% w/w aq. soln. | 100-85-6 | 50ml | $24.8 | 2021-12-16 | Buy |
Benzyltrimethylammonium hydroxide Chemical Properties,Uses,Production
Chemical Properties
CLEAR SLIGHTLY YELLOW SOLUTION
Uses
Benzyltrimethylammonium hydroxide can be used:
- As a base in the synthesis of activated ynesulfonamides and tertiary enesulfonamides.
- In the synthesis of 3-indolyl-3-hydroxy oxindoles by treating isatin with indole.
- As a precursor for the preparation of quaternary ammonium acetate, benzyltrimethylammonium acetate (NBz111AcO). NBz111AcO solution in DMSO can be used to dissolve cellulose.
Uses
Benzyltrimethylammonium hydroxide is used as a phase-transfer catalyst. It is also used in aldol condensation reactions and base-catalyzed dehydration reactions. Further, it serves as a strong organic base and used in Horner-Wadsworth-Emmons olefination reactions. In addition, it is an active component in the formulation, which is used in silicon wafer cleaning applications.
Flammability and Explosibility
Not classified
Safety Profile
Poison by subcutaneous route. Astrong base. When heated to decomposition it emits toxicfumes of NH3 and NOx.
Purification Methods
A 38% solution (as supplied) is decolorized (charcoal), then evaporated under reduced pressure to a syrup, with final drying at 75o/1mm pressure. The anhydrous base is obtained by prolonged drying over P2O5 in a vacuum desiccator. [Beilstein 12 IV 2162.]
Benzyltrimethylammonium hydroxide Preparation Products And Raw materials
Raw materials
Preparation Products
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Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shaanxi Dideu Medichem Co. Ltd | +86-029-81138252 +86-18789408387 | 1057@dideu.com | China | 3958 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12840 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5893 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20287 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +8618949832763 | info@tnjchem.com | China | 2986 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29884 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8812 | 58 |
Xiamen AmoyChem Co., Ltd | +86-86-5926051114 +8618959220845 | sales@amoychem.com | China | 6383 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
View Lastest Price from Benzyltrimethylammonium hydroxide manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-11-22 | Benzyltrimethylammonium hydroxide
100-85-6
|
US $0.00 / KG | 1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | ||
2024-10-11 | Benzyltrimethylammonium hydroxide
100-85-6
|
US $5.00-2.00 / kg | 1kg | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD | ||
2024-05-26 | Benzyltrimethylammonium hydroxide
100-85-6
|
US $1.00 / KG | 1KG | 98% | 20T | Shaanxi Dideu Medichem Co. Ltd |
- Benzyltrimethylammonium hydroxide
100-85-6
- US $0.00 / KG
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
- Benzyltrimethylammonium hydroxide
100-85-6
- US $5.00-2.00 / kg
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD
- Benzyltrimethylammonium hydroxide
100-85-6
- US $1.00 / KG
- 98%
- Shaanxi Dideu Medichem Co. Ltd
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