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MANGANESE(II) ACETYLACETONATE

CAS No.
14024-58-9
Chemical Name:
MANGANESE(II) ACETYLACETONATE
Synonyms
NSC 4656;Mn(acac)2;NSC 52334;NSC 177707;Manganesepentanedionate;MANGANOUS ACETYLACETONATE;MANGANESE ACETYLACETONATE;acetylacetonemanganese(ii);bis(acetylacetone)manganese;manganese(2+)acetylacetonate
CBNumber:
CB3422931
Molecular Formula:
C10H14MnO4
Molecular Weight:
253.15
MDL Number:
MFCD00000022
MOL File:
14024-58-9.mol
Last updated:2024-03-27 14:23:05

MANGANESE(II) ACETYLACETONATE Properties

Melting point 248-250 °C (dec.)(lit.)
Boiling point 130.3°C
Density 1,6 g/cm3
storage temp. Store below +30°C.
solubility 11.5g/l
form Powder
color tan
Specific Gravity 1.60
Water Solubility Soluble in water
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
Sensitive Hygroscopic
BRN 4157965
Exposure limits OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
Stability hygroscopic
EWG's Food Scores 1
EPA Substance Registry System Manganese, bis(2,4-pentanedionato-.kappa.O,.kappa.O')- (14024-58-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS07,GHS08
Signal word  Warning
Hazard statements  H302+H312+H332-H315-H319-H335-H351
Precautionary statements  P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338-P308+P313
Hazard Codes  Xn
Risk Statements  20/21/22-36/37/38-40
Safety Statements  26-36
WGK Germany  3
RTECS  OO9350000
TSCA  Yes
HS Code  2914 19 90
NFPA 704
1
2 0

MANGANESE(II) ACETYLACETONATE price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 245763 Manganese(II) acetylacetonate 14024-58-9 5g $57.6 2024-03-01 Buy
Sigma-Aldrich 245763 Manganese(II) acetylacetonate 14024-58-9 100g $143 2024-03-01 Buy
Sigma-Aldrich 8.05922 Manganese(II) acetylacetonate for synthesis 14024-58-9 100g $153 2022-05-15 Buy
TCI Chemical M0042 Bis(2,4-pentanedionato)manganese(II) Dihydrate >97.0%(T) 14024-58-9 25g $59 2021-12-16 Buy
TCI Chemical M0042 Bis(2,4-pentanedionato)manganese(II) Dihydrate >97.0%(T) 14024-58-9 500g $364 2021-12-16 Buy
Product number Packaging Price Buy
245763 5g $57.6 Buy
245763 100g $143 Buy
8.05922 100g $153 Buy
M0042 25g $59 Buy
M0042 500g $364 Buy

MANGANESE(II) ACETYLACETONATE Chemical Properties,Uses,Production

Chemical Properties

Beige solid

General Description

Manganese(II) acetylacetonate (Mn(acac)2) is a transition metal acetylacetonate that is trimeric in hydrocarbon solvents. It is monomeric and tetrahedral in its vapor state. It shows Mn-O bond energy of 65 kcal mol-1. It can be used with potassium permanganate in preparation of manganese triad (Mn(acac)3).

Safety Profile

Questionable carcinogen with experimental neoplastigenic and tumorigenic data. When heated to decomposition it emits acrid smoke and irritating fumes. See also iMANGANESE COMPOUNDS.

Purification Methods

Purify it by stirring 16g of reagent for a few minutes with 100mL absolute EtOH and filter by suction as rapidly as possible through coarse filter paper. Sufficient EtOH is added to the filtrate, to make up for the loss of EtOH and to redissolve any solid that separates. Water (15mL) is added to the filtrate, and the solution is evaporated with a stream of N2 until reduced to half its volume. Cool for a few minutes and filter off the yellow crystals, dry them under a stream of N2, then in a vacuum at room temperature for 6-8hours. These conditions are important for obtaining the dihydrate. A vacuum to several mm of Hg or much lower pressure for several days produces the anhydrous complex. The degree of hydration can be established by determining the loss in weight of 100g of sample after heating for 4hours at 100o and <20mmHg. The theoretical loss in weight for 2H2O is 12.5%. The material sublimes at 200o/2mm. It is soluble in heptane, MeOH, EtOH or *C6H6 at 30o. [Charles Inorg Synth VI 164 1960, Fernelius & Biswas Inorg Synth V 105 1957, Beilstein 3 II 3122.]

MANGANESE(II) ACETYLACETONATE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 148)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12840 58
hebei hongtan Biotechnology Co., Ltd
+86-86-1913198-3935 +8617331935328 sales03@chemcn.cn China 970 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58
Xiamen AmoyChem Co., Ltd
+86-86-5926051114 +8618959220845 sales@amoychem.com China 6383 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
career henan chemical co
+86-0371-86658258 +8613203830695 factory@coreychem.com China 29811 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 13504 58
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17365 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34553 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-89586680 +86-18192503167 1026@dideu.com China 7724 58

View Lastest Price from MANGANESE(II) ACETYLACETONATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
MANGANESE(II) ACETYLACETONATE pictures 2024-11-22 MANGANESE(II) ACETYLACETONATE
14024-58-9
US $50.00 / kg 1kg 99% 1000 hebei hongtan Biotechnology Co., Ltd
MANGANESE(II) ACETYLACETONATE pictures 2024-03-26 MANGANESE(II) ACETYLACETONATE
14024-58-9
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
MANGANESE(II) ACETYLACETONATE pictures 2021-07-02 MANGANESE(II) ACETYLACETONATE
14024-58-9
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2,4-PENTANEDIONE, MANGANESE(II) DERIVATIVE ACETYLACETONE, MANGANESE(II) DERIVATIVE ACETYLACETONE MANGANESE(II) SALT acetylacetonemanganese(ii) bis(2,4-pentanedionato)-manganes BIS(ACETYLACETONATO)MANGANESE(II) BIS(2,4-PENTANEDIONATO)MANGANESE(2) BIS(2,4-PENTANEDIONATO)MANGANESE(II) MANGANOUS ACETYLACETONATE MANGANESE(II) 2,4-PENTANEDIONATE MANGANESE II 2,4-PENTANEDIONATE TRIMERIC MANGANESE(II) ACETYLACETONATE MANGANESE ACETYLACETONATE Manganese(II)acetylacetonate,95% Manganese, bis(2,4-pentanedionato-.kappa.O,.kappa.O)- 2,4-Pentanedione manganese(II) derivative, Manganous acetylacetonate, Mn(acac)2 Bis(2,4-pentanedionato)manganese(II) Dihydrate Manganese(Ⅱ) 2,4-Pentanedionate Mn(acac)2 manganesebis(2,4-pentanedionate) manganesebis(acetylacetonate) Manganese(II)2,4-pentanedionate 95% Manganesepentanedionate bis(pentane-2,4-dionato-O,O')manganese Manganese(II) acetylacetonate hydrate Bis(2,4-pentanedionato)manganese bis(2,4-pentanedionato-o,o’)-manganes bis(acetylacetone)manganese Manganese bis(2,4-pentanedionate) Manganese bis(acetylacetonate) Manganese(2+) acetylacetonate manganese(2+)acetylacetonate Manganese(II) bis(acetylacetonate) manganese(ii)2,4-pentanedionate95% manganese(ii)bis(acetylacetonate) Manganese, bis(2,4-pentanedionato)- Manganese, bis(2,4-pentanedionato-O,O')- Acetylacetone Manganese(II) Salt Manganese(II) Acetylacetonate Bis(2,4-pentanedionato)Manganese(II)  MANGANESE(II) ACETYLACETONATE FOR SYNTHE NSC 177707 NSC 4656 NSC 52334 Manganese(II) Acetyllacetonate Manganese(Ⅱ) acetylacetonate MANGANESE (II) ACETYLACETONATEMANGANESE (II) ACETYLACETONATEMANGANESE (II) ACETYLACETONATE MANGANESE(II) 2,4-PENTANEDIONATE, tech-95 Bis(2,4-pentanedionato)manganese(II)Dihydrate> Manganese(II) Acetylacetonate,>98% MANGANESE(II) ACETYLACETONATE ISO 9001:2015 REACH Bis(2,4-pentanedionato)manganese Dihydrate 2,4-Pentanedione-manganese (2:1) 14024-58-9 CH3COCHCOCH32Mn C10H14MnO42H2O C10H14O4Mn MnCH3COCHCOCH32 C10H14MnO4