ChemicalBook >> CAS DataBase List >>1H,1H,2H,2H-Perfluorooctanesulfonic acid

1H,1H,2H,2H-Perfluorooctanesulfonic acid

CAS No.
27619-97-2
Chemical Name:
1H,1H,2H,2H-Perfluorooctanesulfonic acid
Synonyms
Perfluorohexyl ethyl sulfonic acid;Perfluorohexyl Ethyl sulphonic acid;3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctanesulphonic acid;1H.1H.2H.2H-perfluorooctane;perfluorohexyl ethyl sulfonate;Thirteen fluorooctanesulfonic acid;1H.1H.2H.2H-perfluorooctane sulfonate;(1H,1H,2H,2H)-Perfluorooctanesulfonic];2-(Perfluorohexyl)ethane-1-sulfonic acid;1H,1H,2H,2H-PERFLUOROOCTANESULFONIC ACID
CBNumber:
CB3467468
Molecular Formula:
C8H5F13O3S
Molecular Weight:
428.17
MDL Number:
MFCD00042455
MOL File:
27619-97-2.mol
Last updated:2024-04-26 11:45:26

1H,1H,2H,2H-Perfluorooctanesulfonic acid Properties

Density 1,25 g/cm3
vapor pressure 1.96Pa at 20℃
solubility Acetone: Slightly soluble,Chloroform: Slightly soluble,DMSO: Slightly soluble,Methanol: Slightly soluble
form A low-melting solid
pka 1.31±0.50(Predicted)
Water Solubility 658g/L at 20℃
InChI InChI=1S/C8H5F13O3S/c9-3(10,1-2-25(22,23)24)4(11,12)5(13,14)6(15,16)7(17,18)8(19,20)21/h1-2H2,(H,22,23,24)
InChIKey VIONGDJUYAYOPU-UHFFFAOYSA-N
SMILES C(S(O)(=O)=O)CC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
FDA UNII 9E5JL7S7WY
EPA Substance Registry System 1-Octanesulfonic acid, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro- (27619-97-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P271-P280
Hazard Codes  C,Xi
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  3265
Hazard Note  Corrosive
HazardClass  IRRITANT, CORROSIVE
HS Code  2904990090
NFPA 704
0
3 0

1H,1H,2H,2H-Perfluorooctanesulfonic acid price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC T007805 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctane-1-sulphonicAcid 27619-97-2 25mg $110 2021-12-16 Buy
Apolloscientific PC6143 1H,1H,2H,2H-Tridecafluorooctane-1-sulphonicacid 98% 27619-97-2 100mg $116 2021-12-16 Buy
SynQuest Laboratories 6164-3-06 1H,1H,2H,2H-Perfluorooctanesulfonic acid 98% 27619-97-2 1g $185 2021-12-16 Buy
SynQuest Laboratories 6164-3-49 1H,1H,2H,2H-Perfluorooctanesulfonic acid, 32% aqueous solution 27619-97-2 1g $195 2021-12-16 Buy
SynQuest Laboratories 6164-3-46 1H,1H,2H,2H-Perfluorooctanesulfonic acid, 25% aqueous solution 27619-97-2 1g $195 2021-12-16 Buy
Product number Packaging Price Buy
T007805 25mg $110 Buy
PC6143 100mg $116 Buy
6164-3-06 1g $185 Buy
6164-3-49 1g $195 Buy
6164-3-46 1g $195 Buy

1H,1H,2H,2H-Perfluorooctanesulfonic acid Chemical Properties,Uses,Production

Description

1H,1H,2H,2H-Perfluorooctanesulfonic acid (1H,1H,2H,2H-Perfluorooctanesulphonic acid) is an efficient fluorine-containing surfactant without perfluorooctane sulfonic acid, which has the characteristics of high temperature resistance, oxidant resistance, electrolytic stability, etc. It can reduce the concentration of chromic acid in plating workshop and inhibit the precipitation of chromic acid and chromium mist.

Chemical Properties

White to Brown Solid.

Uses

1H,1H,2H,2H-Perfluorooctanesulfonic acid is an aliphatic compound for fluorinated surfactant synthesis.

Application

1H,1H,2H,2H-Perfluorooctanesulfonic acid (1H,1H,2H,2H-Perfluorooctanesulphonic acid) can functionalize gallium nitride (GaN) to tune the optical properties, which can potentially be used in chemical sensor based applications. It can modify the surface characteristics of copper substrates that find usage in printed circuit boards as copper foils. It can also be coated on the indium tin oxide substrate, which may be utilized in organic light emitting diodes (OLEDs) and organic photovoltaics (OPVs).

General Description

1H,1H,2H,2H-Perfluorooctanesulfonic acid is a fluoroalkyl phosphonic acid that contains 8 fluorinated carbon atoms. It forms a self-assembled layer on the substrate due to the adhesion of the phosphonates. The surface adhesion is a component of the acid base linkage that is enhanced by the hydroxyl groups.

Flammability and Explosibility

Not classified

Toxicology

Toxicological studies of 1H,1H,2H,2H-Perfluorooctanesulfonic acid (6:2 FTS) induced cardiovascular abnormalities in zebrafish embryos and larvae showed that the acute toxicity of 6:2 FTS was lower than that of PFOS. 6:2 FTS could affect the development of zebrafish, including increasing the utilization of yolk sac and the length of the pharyngeal pouch, leading to pericardial edema and inhibiting beating of the heart. Then transgenic zebrafish CZ63 and CZ40 were used to further explore its cardiovascular toxicity. 6:2 FTS could induce vascular hyperplasia, inhibit atrial development, and reduce blood flow velocity in larvae at 72 hours postfertilization. In addition, 6:2 FTS enhanced CAT and GSH-Px activities, involved in calcium signalling and myocardial contraction, and affected MAPK, FoxO and p53 signalling pathways[3].

storage

2-8°C

Environmental considerations

Regulatory efforts are underway to limit the use of some Fluorinated additive material, mainly perfluorinated compounds (PFCs), due to concerns over their environmental persistency, bioaccumulation ability, and toxicity. Among the PFCs, perfluorosulfonates (PFSAs) and perfluorocarboxylates (PFCAs) are most widely detected in human and other biological samples, including those in pristine areas such as the Arctic. The longer-chained PFCs are known to be bioaccumulative and have toxic effects on biota. For example, neuroendocrine effects and peroxisome proliferation have been shown to occur. The perfluorinated sulfonamides are neutral compounds and are consequently not as water-soluble as the acids and are more volatile. It has been suggested that they are transformed into perfluorinated sulfonates (PFSAs) and PFCAs in the atmosphere. Since the perfluorinated acids have high water solubilities and low pKa values, they are dissociated at environmentally relevant pH values. They are primarily found in water or bound to particles, sediments, and soils[1-2].

References

[1] L. Ahrens. "Determination of polyfluoroalkyl compounds in water and suspended particulate matter in the river Elbe and North Sea, Germany." Frontiers of Environmental Science & Engineering in China 3.1(2009): 152–170.
[2] RuanTing. "Trace determination of airborne polyfluorinated iodine alkanes using multisorbent thermal desorption/gas chromatography/high resolution mass spectrometry." Journal of Chromatography A 1217 26 (2010): 4439–47.
[3] LING WANG, YAWEI WANG; Early Stage Exposure of 1H,1H,2H,2H-Perfluorooctanesulfonate-Induced Cardiovascular Abnormality in Zebrafish Embryos and Larvae[J]. ACS ES&T water, 2022. DOI:10.1021/acsestwater.2c00435.

34451-26-8
27619-97-2
Synthesis of 1H,1H,2H,2H-Perfluorooctanesulfonic acid from 1H,1H,2H,2H-PERFLUOROOCTANETHIOL

1H,1H,2H,2H-Perfluorooctanesulfonic acid Preparation Products And Raw materials

Global( 137)Suppliers
Supplier Tel Email Country ProdList Advantage
Tianjin Huiren Chemtech Co., Ltd
+86-86-22-23707858 +86-86-13672008665 huirentech@foxmail.com China 171 58
Wuhan Bright Chemical Co., Ltd
+86-02785804899 +86-15071395570 alice@brightchemical.com.cn China 93 58
Tangshan Moneide Trading Co., Ltd.
+86-315-8309571 +8615633399667 sales@moneidechem.com China 574 58
SHANDONG OUCHEM CO.,LTD.
+86-18506360988 +86-18506360988 wtaili@ouchem.cn China 51 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18777 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
Hangzhou FandaChem Co.,Ltd.
+8615858145714 FandaChem@Gmail.com China 9214 55
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29882 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9636 58

View Lastest Price from 1H,1H,2H,2H-Perfluorooctanesulfonic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1H,1H,2H,2H-Perfluorooctanesulfonic acid pictures 2024-11-05 1H,1H,2H,2H-Perfluorooctanesulfonic acid
27619-97-2
US $0.00-0.00 / kg 0.1kg 98%Min. 3000kg SHANDONG OUCHEM CO.,LTD.
1H,1H,2H,2H-PERFLUOROOCTANESULFONIC ACID pictures 2024-10-17 1H,1H,2H,2H-PERFLUOROOCTANESULFONIC ACID
27619-97-2
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Weibang Biotechnology Co., Ltd
Perfluorooctanesulphonic acid pictures 2023-04-20 Perfluorooctanesulphonic acid
27619-97-2
US $0.00 / KG 1KG 30% 1000KG Wuhan Silworld Chemical Co.,Ltd
(1H,1H,2H,2H)-Perfluorooctanesulfonic] 1-Octanesulfonic acid, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro- 1H,1H,2H,2H-Perfluorooctanesulphonic acid 98% 1H,1H,2H,2H-Perfluorooctanesulphonicacid98% 2-(Perfluorohexyl)ethane-1-sulfonic acid 2-(Tridecafluorohexyl)ethanesulfonic acid 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctane-1-sulfonic acid 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctane-1-sulphonic acid 1H,1H,2H,2H-Tridecafluorooctane-1-sulphonic acid 98% 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctane-1-sulphonic acid, 1H,1H,2H,2H-Perfluorooctanesulphonic acid, 2-(Perfluorohex-1-yl)ethane-1-suphonic acid 1H,1H,2H,2H-Tridecafluorooctane-1-sulphonicacid98% 1H,1H,2H,2H-Perfluorooctanesulfonic acid (25% aqueous solution) 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-octanesulfonicaci 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro-1-Octanesulfonicacid 1H,1H,2H,2H-PERFLUOROOCTANESULFONIC ACID 1H,1H,2H,2H-PERFLUOROOCTANESULPHONIC ACID 1H,1H,2H,2H-Perfluorooctanesulfonic acid, 32% aqueous solution 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctanesulfonicacid 2-(Perfluorohexyl)ethane-0-sulfonic acid perfluorohexyl ethyl sulfonate 27619-97-2 C8H5F13O3S 1H,1H,2H,2H-PERFLUOROOCTANESULFONIC ACID 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctanesulphonic acid Perfluorohexyl ethyl sulfonic acid Perfluorohexyl Ethyl sulphonic acid 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctane-1-sulfonicaci 1-Octanesulfonic acid,3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro- CAS NO.27619-97-2 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctanesulphonic acid (30% solution) 1H,1H,2H,2H-Perfluorooctane sulfonic acid 100 μg/mL in Methanol 1H,1H,2H,2H-Perfluorooctanesulfonic acid in methanol 1H.1H.2H.2H-perfluorooctane 1H.1H.2H.2H-perfluorooctane sulfonate Thirteen fluorooctanesulfonic acid 27619-97-2 C8H5F13O3S