Borane-2-picoline complex
- CAS No.
- 3999-38-0
- Chemical Name:
- Borane-2-picoline complex
- Synonyms
- Pic-BH3;2-picoline borane;2-methylpyridine borane;2-Methylpyridine borane complex;(2-Methylpyridin-1-iuM-1-yl)trihydroborate;Borane-2-picoL;orane-2-picoline coMplex;BORANE - 2-PICOLINE COMPLEX;2- methylpyridine -N- borane;2-Methylpyridine - borane (1:1)
- CBNumber:
- CB3500718
- Molecular Formula:
- C6H10BN
- Molecular Weight:
- 106.96
- MDL Number:
- MFCD07784361
- MOL File:
- 3999-38-0.mol
- MSDS File:
- SDS
Melting point | 48 °C |
---|---|
Density | 1.297 g/mL at 25 °C |
Flash point | 100°(212°F) |
storage temp. | 2-8°C |
solubility | Dichloromethane (Sparingly), Ethyl Acetate (Slightly) |
form | Solid |
color | White |
Water Solubility | Slightly sol. in water, cyclohexane, very sol. in methanol, THF, diglyme, and benzene |
Sensitive | Moisture Sensitive |
InChI | InChI=1S/C6H10BN/c1-6-4-2-3-5-8(6)7/h2-5H,1,7H3 |
InChIKey | ZMASBEFBIXMNCP-UHFFFAOYSA-N |
SMILES | [B+3](N1=CC=CC=C1C)([H-])([H-])[H-] |
UNSPSC Code | 12352005 |
NACRES | NA.22 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS02,GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H261-H315-H319-H335 | |||||||||
Precautionary statements | P231+P232-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | F,Xn,Xi | |||||||||
Risk Statements | 14/15-40-36/37/38-26 | |||||||||
Safety Statements | 36/37-43-26-36/37/38-14/15 | |||||||||
RIDADR | UN 3130 6.1(4.3) / PGII | |||||||||
WGK Germany | 3 | |||||||||
HazardClass | 4.3 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29333990 | |||||||||
NFPA 704 |
|
Borane-2-picoline complex price More Price(22)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 654213 | 2-Methylpyridine borane complex solution 95% | 3999-38-0 | 5g | $74.9 | 2024-03-01 | Buy |
Sigma-Aldrich | 771759 | 2-Methylpyridine borane complex solution 0.5 M in dichloromethane | 3999-38-0 | 10ml | $45.2 | 2023-06-20 | Buy |
TCI Chemical | B3018 | Borane - 2-Methylpyridine Complex >85.0%(T) | 3999-38-0 | 5g | $69 | 2024-03-01 | Buy |
TCI Chemical | B3018 | Borane - 2-Methylpyridine Complex >85.0%(T) | 3999-38-0 | 25g | $207 | 2024-03-01 | Buy |
Alfa Aesar | H66642 | Borane-2-methylpyridine complex, 95% | 3999-38-0 | 5g | $70.5 | 2024-03-01 | Buy |
Borane-2-picoline complex Chemical Properties,Uses,Production
Uses
Used as reactant for N-Benzyl-protection of amino acid derivatives by reductive alkylation, reductive alkoxyamination, as reducing agent for the labeling of oligosaccharides by reductive amination, synthesis of alkoxyamine derivatives, via reduction of oxime ethers, reductive amination reactions of C1-C10 aldehyde 2,4-dinitrophenylhydrazones, synthesis of various trifluoromethylated amino compounds and an alternative reagent for reductive aminations.
Uses
Environmentally benign reducing agent. Reactant for: Reductive amination. N-Benzyl-protection of amino acid derivatives by reductive alkylation. Reductive alkoxyamination.
General Description
2-Methylpyridine borane complex is a nontoxic alternate to the reducing agent sodium cyanoborohydride.
reaction suitability
reagent type: reductant
Borane-2-picoline complex Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Allfluoro pharmaceutical co. ltd. | +86-400-0216110 +86-15958047586 | sales@allfluoro.com | China | 11385 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531153977 | allison@yan-xi.com | China | 5855 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5887 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8617732866630 | bess@weibangbio.com | China | 18147 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29792 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21632 | 55 |
Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1803 | 55 |
Zjartschem | +86-571 87238903 | jocelynpan@zjarts.com | CHINA | 988 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29871 | 58 |
SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2930 | 58 |
View Lastest Price from Borane-2-picoline complex manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
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2024-10-25 | Borane - 2-Methylpyridine Complex
3999-38-0
|
US $40.00 / kg | 1kg | 0.99 | 10 tons | Hebei Yanxi Chemical Co., Ltd. | |
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2024-10-25 | Borane-2-picoline complex
3999-38-0
|
US $0.00-0.00 / KG | 50KG | 99% | 500000kg | Hebei Weibang Biotechnology Co., Ltd | |
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2024-10-11 | Borane-2-picoline complex
3999-38-0
|
US $1.90 / KG | 1KG | 99% | 10 ton | Hebei Chuanghai Biotechnology Co,.LTD |
-
- Borane - 2-Methylpyridine Complex
3999-38-0
- US $40.00 / kg
- 0.99
- Hebei Yanxi Chemical Co., Ltd.
-
- Borane-2-picoline complex
3999-38-0
- US $0.00-0.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
-
- Borane-2-picoline complex
3999-38-0
- US $1.90 / KG
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD