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Borane-2-picoline complex

CAS No.
3999-38-0
Chemical Name:
Borane-2-picoline complex
Synonyms
Pic-BH3;2-picoline borane;2-methylpyridine borane;2-Methylpyridine borane complex;(2-Methylpyridin-1-iuM-1-yl)trihydroborate;Borane-2-picoL;orane-2-picoline coMplex;BORANE - 2-PICOLINE COMPLEX;2- methylpyridine -N- borane;2-Methylpyridine - borane (1:1)
CBNumber:
CB3500718
Molecular Formula:
C6H10BN
Molecular Weight:
106.96
MDL Number:
MFCD07784361
MOL File:
3999-38-0.mol
MSDS File:
SDS
Last updated:2025-02-16 18:17:59

Borane-2-picoline complex Properties

Melting point 48 °C
Density 1.297 g/mL at 25 °C
Flash point 100°(212°F)
storage temp. 2-8°C
solubility Dichloromethane (Sparingly), Ethyl Acetate (Slightly)
form Solid
color White
Water Solubility Slightly sol. in water, cyclohexane, very sol. in methanol, THF, diglyme, and benzene
Sensitive Moisture Sensitive
InChI InChI=1S/C6H10BN/c1-6-4-2-3-5-8(6)7/h2-5H,1,7H3
InChIKey ZMASBEFBIXMNCP-UHFFFAOYSA-N
SMILES [B+3](N1=CC=CC=C1C)([H-])([H-])[H-]
UNSPSC Code 12352005
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Danger
Hazard statements  H261-H315-H319-H335
Precautionary statements  P231+P232-P302+P352-P305+P351+P338
Hazard Codes  F,Xn,Xi
Risk Statements  14/15-40-36/37/38-26
Safety Statements  36/37-43-26-36/37/38-14/15
RIDADR  UN 3130 6.1(4.3) / PGII
WGK Germany  3
HazardClass  4.3
PackingGroup  II
HS Code  29333990
NFPA 704
2
2 2
W

Borane-2-picoline complex price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 654213 2-Methylpyridine borane complex solution 95% 3999-38-0 5g $74.9 2024-03-01 Buy
Sigma-Aldrich 771759 2-Methylpyridine borane complex solution 0.5 M in dichloromethane 3999-38-0 10ml $45.2 2023-06-20 Buy
TCI Chemical B3018 Borane - 2-Methylpyridine Complex >85.0%(T) 3999-38-0 5g $69 2024-03-01 Buy
TCI Chemical B3018 Borane - 2-Methylpyridine Complex >85.0%(T) 3999-38-0 25g $207 2024-03-01 Buy
Alfa Aesar H66642 Borane-2-methylpyridine complex, 95% 3999-38-0 5g $70.5 2024-03-01 Buy
Product number Packaging Price Buy
654213 5g $74.9 Buy
771759 10ml $45.2 Buy
B3018 5g $69 Buy
B3018 25g $207 Buy
H66642 5g $70.5 Buy

Borane-2-picoline complex Chemical Properties,Uses,Production

Uses

Used as reactant for N-Benzyl-protection of amino acid derivatives by reductive alkylation, reductive alkoxyamination, as reducing agent for the labeling of oligosaccharides by reductive amination, synthesis of alkoxyamine derivatives, via reduction of oxime ethers, reductive amination reactions of C1-C10 aldehyde 2,4-dinitrophenylhydrazones, synthesis of various trifluoromethylated amino compounds and an alternative reagent for reductive aminations.

Uses

Environmentally benign reducing agent. Reactant for: Reductive amination. N-Benzyl-protection of amino acid derivatives by reductive alkylation. Reductive alkoxyamination.

General Description

2-Methylpyridine borane complex is a nontoxic alternate to the reducing agent sodium cyanoborohydride.

reaction suitability

reagent type: reductant

109-06-8
3999-38-0
Synthesis of Borane-2-picoline complex from 2-Picoline

Borane-2-picoline complex Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 231)Suppliers
Supplier Tel Email Country ProdList Advantage
Allfluoro pharmaceutical co. ltd.
+86-400-0216110 +86-15958047586 sales@allfluoro.com China 11385 58
Hebei Yanxi Chemical Co., Ltd.
+8617531153977 allison@yan-xi.com China 5855 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-13131129325 sales1@chuanghaibio.com China 5887 58
Hebei Weibang Biotechnology Co., Ltd
+8617732866630 bess@weibangbio.com China 18147 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29792 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21632 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1803 55
Zjartschem
+86-571 87238903 jocelynpan@zjarts.com CHINA 988 58
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29871 58
SHANDONG ZHI SHANG CHEMICAL CO.LTD
+86 18953170293 sales@sdzschem.com China 2930 58

View Lastest Price from Borane-2-picoline complex manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Borane - 2-Methylpyridine Complex pictures 2024-10-25 Borane - 2-Methylpyridine Complex
3999-38-0
US $40.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.
Borane-2-picoline complex pictures 2024-10-25 Borane-2-picoline complex
3999-38-0
US $0.00-0.00 / KG 50KG 99% 500000kg Hebei Weibang Biotechnology Co., Ltd
Borane-2-picoline complex pictures 2024-10-11 Borane-2-picoline complex
3999-38-0
US $1.90 / KG 1KG 99% 10 ton Hebei Chuanghai Biotechnology Co,.LTD

Borane-2-picoline complex Spectrum

Borane - 2-Picoline Complex 2-Picoline Borane 2-Methylpyridine Borane orane-2-picoline coMplex BORANE - 2-PICOLINE COMPLEX borane - 2-methylpyridine complex Trihydro(2-methylpyridine)-boron Boron,trihydro(2-Methylpyridine)-, (T-4)- 2-Methylpyridine borane coMplex solution 95% 2-Methylpyridine borane complex solution 2-Methylpyridine - borane (1:1) Borane-2-picoL Borane - 2-Methylpyridine Complex > Borane-2-picoline complex ISO 9001:2015 REACH Factories direct supplier Borane-2-picoline complex CAS 3999-38-0 Borane-2-methylpyridine complex, 95%, 2-methylpyridine borane 2-picoline borane (2-Methylpyridin-1-iuM-1-yl)trihydroborate 2-Methylpyridine borane complex Pic-BH3 2- methylpyridine -N- borane Borane - 2-Methylpyridine Complex, ≥ 85.0% 3999-38-0 3999-38-2 C6H10BN B (Classes of Boron Compounds) Boranes Reduction Synthetic Organic Chemistry 3999-38-0