Diacetone-D-glucose
- CAS No.
- 582-52-5
- Chemical Name:
- Diacetone-D-glucose
- Synonyms
- GLUCOFURANOSE;(3aR,5S,6S,6aR)-5-((R)-2,2-DiMethyl-1,3-dioxolan-4-yl)-2,2-diMethyltetrahydrofuro[2,3-d][1,3]dioxol-6-ol;DIACETONEGLUCOSE;1,2:5,6-DI-O-ISOPROPYLIDENE-A-D-GLUCOFURANOSE;1,2:5,6-DIISOPROPYLENE-ALPHA-D-GLUCOFURANOSE;1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose;1,2:5,6-DI-O-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSE;1,2:5,6-O-DI-ISOPROPYLIDENE-ALPHA-D-GLUCOFURANOSIDE;ucose;NSC 1223
- CBNumber:
- CB3673320
- Molecular Formula:
- C12H20O6
- Molecular Weight:
- 260.29
- MDL Number:
- MFCD00005544
- MOL File:
- 582-52-5.mol
- MSDS File:
- SDS
Melting point | 110-111 °C(lit.) |
---|---|
alpha | -11 º (c=5, EtOH) |
Boiling point | 323.54°C (rough estimate) |
Density | 1.1432 (rough estimate) |
refractive index | -18.5 ° (C=5, H2O) |
storage temp. | Inert atmosphere,Store in freezer, under -20°C |
solubility | Chloroform (Slightly), Methanol (Slightly), Water (Slightly, Sonicated) |
pka | 13.15±0.60(Predicted) |
form | Powder |
color | White to yellow |
optical activity | [α]20/D 18°, c = 1% in H2O |
Water Solubility | slightly soluble |
Merck | 14,2965 |
BRN | 84386 |
InChIKey | KEJGAYKWRDILTF-YENDLIOYSA-N |
FDA UNII | R3P8TN410C |
EPA Substance Registry System | Diacetone glucose (582-52-5) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H302 | |||||||||
Precautionary statements | P280-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 24/25-36/37-26 | |||||||||
WGK Germany | 2 | |||||||||
RTECS | LZ4958000 | |||||||||
F | 3-10 | |||||||||
TSCA | Yes | |||||||||
HS Code | 29329970 | |||||||||
Toxicity | LD50 oral in mouse: 4gm/kg | |||||||||
NFPA 704 |
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Diacetone-D-glucose price More Price(42)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 31460 | 1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose purum,≥98.0%(TLC) | 582-52-5 | 25g | $62.6 | 2024-03-01 | Buy |
Sigma-Aldrich | 31460 | 1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose purum,≥98.0%(TLC) | 582-52-5 | 100g | $138 | 2024-03-01 | Buy |
Sigma-Aldrich | S83055 | 5-(2,2-DIMETHYL-(1,3)DIOXOLAN-4-YL)-2,2-DIMETHYL-4H-FURO(2,3-D)(1,3)DIOXOL-6-OL AldrichCPR | 582-52-5 | 250MG | $28.6 | 2023-06-20 | Buy |
TCI Chemical | D1949 | 1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose >97.0%(GC) | 582-52-5 | 10g | $16 | 2024-03-01 | Buy |
TCI Chemical | D1949 | 1,2:5,6-Di-O-isopropylidene-alpha-D-glucofuranose >97.0%(GC) | 582-52-5 | 25g | $40 | 2024-03-01 | Buy |
Diacetone-D-glucose Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powde
Uses
1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose is a compound useful in organic synthesis.
Uses
It is mainly used in biochemical reaction and used as medicine intermediate. It is used in synthesize for below products: L-gulose;1,2:5,6-Di-O-isopropylidene-a-D-gulofuranose; Alllose; ;1,2:5,6-Double-O-Isopropylidene-3-C-(1-Methoxycarbonyl)Ethide-alfa-D-Furanose) ;1,2:5,6-Di-O-isopropylidene-a-D-ribo-hexofuranose-3-ulose;6-deoxy idose.
Purification Methods
Diacetone-D-glucose crystallises from Et2O, (needles), pet ether or *C6H6 and sublimes in vacuo. It is soluble in 7 volumes of H2O and 200 volumes of pet ether at their boiling points. The solubility in H2O at 17.5o is 4.3%. It precipitates from aqueous solutions on basification with NaOH. [Schmid & Karrer Helv Chim Acta 32 1371 1949, Fischer & Rund Chem Ber 49 90, 93 1916, IR: Kuhn Anal Chem 22 276 1950, Beilstein 19/12 V 318.]
Diacetone-D-glucose Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Zhejiang Synose Tech Co., Ltd | 579-82270620 | expo@synose.com | CHINA | 218 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12839 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5857 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5892 | 58 |
Frapp's ChemicalNFTZ Co., Ltd. | +86 (576) 8169-6106 | sales@frappschem.com | China | 880 | 50 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18775 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
Hangzhou FandaChem Co.,Ltd. | +8615858145714 | FandaChem@Gmail.com | China | 9206 | 55 |
Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32957 | 60 |
View Lastest Price from Diacetone-D-glucose manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-11-28 | Diacetone-D-glucose
582-52-5
|
US $0.00-0.00 / Kg | 1Kg | 98% | 20Ton | Xinxiang Aurora Biotechnology Co.,Ltd. | ||
2024-11-27 | Diacetone-D-glucose
582-52-5
|
US $0.00 / kg | 1kg | 98%min | 10000kg | WUHAN FORTUNA CHEMICAL CO., LTD | ||
2024-11-14 | Diacetone-D-glucose
582-52-5
|
US $95.00 / Kg/Bag | 1KG | 99% | 100kg | Baoji Guokang Bio-Technology Co., Ltd. |
- Diacetone-D-glucose
582-52-5
- US $0.00-0.00 / Kg
- 98%
- Xinxiang Aurora Biotechnology Co.,Ltd.
- Diacetone-D-glucose
582-52-5
- US $0.00 / kg
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
- Diacetone-D-glucose
582-52-5
- US $95.00 / Kg/Bag
- 99%
- Baoji Guokang Bio-Technology Co., Ltd.