Borane-methyl sulfide complex
- CAS No.
- 13292-87-0
- Chemical Name:
- Borane-methyl sulfide complex
- Synonyms
- BMS;Dimethylsulfide borane complex;(Dimethyl sulfide)trihydroboron;DMSB;borane-methyl sulfide;DIMETHYL SULFIDE BORANE;BORANE-DIMETHYLSULFIDE;BORANE-DIMETHYLSULFIDE COMPLEX;borane dimethyl sulfide complex solution;Borane dimethyL
- CBNumber:
- CB3700534
- Molecular Formula:
- C2H10BS
- Molecular Weight:
- 76.97
- MDL Number:
- MFCD00013189
- MOL File:
- 13292-87-0.mol
Melting point | -40--37°C |
---|---|
Boiling point | ~34 °C |
Density | 1.287 g/mL at 25 °C |
refractive index | 1.4570 |
Flash point | 65 °F |
storage temp. | 2-8°C |
solubility | Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents. |
form | Solution |
color | Colorless to pale yellow |
Specific Gravity | 0.801 |
Water Solubility | reacts |
Sensitive | Air & Moisture Sensitive |
BRN | 3663489 |
InChIKey | RMHDLBZYPISZOI-UHFFFAOYSA-N |
CAS DataBase Reference | 13292-87-0(CAS DataBase Reference) |
EWG's Food Scores | 1 |
FDA UNII | 6AVE9SRR08 |
NIST Chemistry Reference | Borane-methyl sulfide complex(13292-87-0) |
EPA Substance Registry System | Boron, trihydro[thiobis[methane]]-, (T-4)- (13292-87-0) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() ![]() ![]() GHS02,GHS05,GHS06,GHS08 |
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Signal word | Danger | |||||||||
Hazard statements | H225-H260-H301+H311-H318-H360FD-H412 | |||||||||
Precautionary statements | P210-P231+P232-P273-P280-P301+P310-P305+P351+P338 | |||||||||
Hazard Codes | F+,Xn,F,Xi | |||||||||
Risk Statements | 12-14/15-19-20/22-37/38-41-67-65-63-48/20-38-11-22-14-40-36-21-36/37/38-37 | |||||||||
Safety Statements | 36/37-62-36/39-33-26-23-16-36-24/25-7/8-43-39-36/37/39 | |||||||||
RIDADR | UN 3399 4.3/PG 1 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | PV5080000 | |||||||||
F | 10-13-23 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 4.3 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29309090 | |||||||||
NFPA 704 |
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Borane-methyl sulfide complex price More Price(35)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 192120 | Borane dimethyl sulfide complex solution 2.0?M in THF | 13292-87-0 | 4X25ML | $80.3 | 2024-03-01 | Buy |
Sigma-Aldrich | 179825 | Borane dimethyl sulfide complex | 13292-87-0 | 25ml | $80.6 | 2024-03-01 | Buy |
Sigma-Aldrich | 179825 | Borane dimethyl sulfide complex | 13292-87-0 | 4x25ml | $153 | 2024-03-01 | Buy |
TCI Chemical | D1843 | Dimethyl Sulfide Borane >90.0%(T) | 13292-87-0 | 25mL | $40 | 2024-03-01 | Buy |
TCI Chemical | D1843 | Dimethyl Sulfide Borane >90.0%(T) | 13292-87-0 | 100mL | $116 | 2024-03-01 | Buy |
Borane-methyl sulfide complex Chemical Properties,Uses,Production
Chemical Properties
clear colorless to light yellow solution
Uses
Borane-dimethyl sulfide (BH3 Me2S) can be used as a reagent:
- For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate.
- For the conversion of ozonides to alcohols.
- In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols.
- For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C3-symmetric tripodal hydroxyamide as a ligand.
- For the hydroboration reduction and other applications.
- With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.
Uses
Borane-dimethyl sulfide complex is used for hydroborations and reductions. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides.
General Description
Borane dimethyl sulfide complex (BMS) acts as a highly efficient and selective reducing agent in the presence of catalytic sodium tetrahydroborate for α-hydroxy esters. Asymmetric borane reduction of a variety of prochiral ketones with BMS using spiroborate esters as catalyst has been reported.
Borane-methyl sulfide complex Preparation Products And Raw materials
Raw materials
Preparation Products
1of4
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5823 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21668 | 55 |
Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3012 | 60 |
Zjartschem | +86-571 87238903 | jocelynpan@zjarts.com | CHINA | 993 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29894 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
Shandong chuangyingchemical Co., Ltd. | 18853181302 | sale@chuangyingchem.com | CHINA | 5909 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49391 | 58 |
View Lastest Price from Borane-methyl sulfide complex manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2024-08-20 | Borane-Methyl Sulfide Complex
13292-87-0
|
US $5.00-2.00 / KG | 1KG | 99% | 10000kg | Hebei Chuanghai Biotechnology Co,.LTD | |
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2024-04-25 | Borane-Methyl Sulfide Complex
13292-87-0
|
US $10.00 / kg | 1kg | 99.6% | 100000 | Ouhuang Engineering Materials (Hubei) Co., Ltd | |
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2022-09-27 | Borane-methyl sulfide complex
13292-87-0
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. |
-
- Borane-Methyl Sulfide Complex
13292-87-0
- US $5.00-2.00 / KG
- 99%
- Hebei Chuanghai Biotechnology Co,.LTD
-
- Borane-Methyl Sulfide Complex
13292-87-0
- US $10.00 / kg
- 99.6%
- Ouhuang Engineering Materials (Hubei) Co., Ltd
-
- Borane-methyl sulfide complex
13292-87-0
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.