2,2-Bis[4-(4-aminophenoxy)phenyl]propane
- CAS No.
- 13080-86-9
- Chemical Name:
- 2,2-Bis[4-(4-aminophenoxy)phenyl]propane
- Synonyms
- BAPP;2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]PROPANE;4-BAPOPP;4,4'-(4,4'-Isopropyl;2,2’-bis(4-aminophenoxyphenyl)propane;2,2'-Bis(4-aminophenoxyphenyl) propane;2,2-Bis[4-(4-aminophenoxy)phenyl]propan;2,2-Bis[p-(4-aMinophenoxy)phenyl]propane;2,2'-Bis[4-(4-aminophenoxy)pheny]propane;2,2-Bis[p-(p-aminophenoxy)phenyl]propane
- CBNumber:
- CB3780578
- Molecular Formula:
- C27H26N2O2
- Molecular Weight:
- 410.51
- MDL Number:
- MFCD00039152
- MOL File:
- 13080-86-9.mol
- MSDS File:
- SDS
Melting point | 127-130 °C(lit.) |
---|---|
Boiling point | 587.1±50.0 °C(Predicted) |
Density | 1.178±0.06 g/cm3(Predicted) |
vapor pressure | 0-0Pa at 20-25℃ |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
pka | 5.16±0.10(Predicted) |
form | Solid:particulate/powder |
Water Solubility | Very slightly soluble in water. Soluble in acetone, Dimethyl sulfoxide(DMSO). |
InChI | InChI=1S/C27H26N2O2/c1-27(2,19-3-11-23(12-4-19)30-25-15-7-21(28)8-16-25)20-5-13-24(14-6-20)31-26-17-9-22(29)10-18-26/h3-18H,28-29H2,1-2H3 |
InChIKey | KMKWGXGSGPYISJ-UHFFFAOYSA-N |
SMILES | C(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C)C |
LogP | 4.3-4.9 at 35℃ and pH7 |
CAS DataBase Reference | 13080-86-9(CAS DataBase Reference) |
EPA Substance Registry System | Benzenamine, 4,4'-[(1-methylethylidene)bis(4,1-phenyleneoxy)]bis- (13080-86-9) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H302-H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P270-P301+P312-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xn,Xi | |||||||||
Risk Statements | 22-36/37/38 | |||||||||
Safety Statements | 26-36 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | CY1062500 | |||||||||
TSCA | Yes | |||||||||
HS Code | 29222990 | |||||||||
NFPA 704 |
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2,2-Bis[4-(4-aminophenoxy)phenyl]propane price More Price(28)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 476331 | 4,4′-(4,4′-Isopropylidenediphenyl-1,1′-diyldioxy)dianiline 98% | 13080-86-9 | 50g | $82.8 | 2024-03-01 | Buy |
TCI Chemical | B1551 | 2,2-Bis[4-(4-aminophenoxy)phenyl]propane >98.0%(HPLC)(T) | 13080-86-9 | 25g | $37 | 2024-03-01 | Buy |
TCI Chemical | B1551 | 2,2-Bis[4-(4-aminophenoxy)phenyl]propane >98.0%(HPLC)(T) | 13080-86-9 | 250g | $228 | 2024-03-01 | Buy |
Alfa Aesar | H55057 | 2,2-Bis[4-(4-aminophenoxy)phenyl]propane, 98% | 13080-86-9 | 25g | $34.65 | 2024-03-01 | Buy |
Alfa Aesar | H55057 | 2,2-Bis[4-(4-aminophenoxy)phenyl]propane, 98% | 13080-86-9 | 100g | $112 | 2024-03-01 | Buy |
2,2-Bis[4-(4-aminophenoxy)phenyl]propane Chemical Properties,Uses,Production
Description
2,2-Bis[4-(4-aminophenoxy)phenyl]propane (BAPP), also known as 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline, is a diamino monomer with a diphenoxy-phenyl core. Since the molecule has two amine groups at both ends, it can be cross-linked with carboxylic acids or carboxylic dianhydrides to synthesize polyimides. It is commonly as a monomer for the preparation of polyimides in application of batteries, fuel cells, low dielectric materials and OLEDs.
Chemical Properties
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline (2,2-Bis[4-(4-aminophenoxy)phenyl]propane) is white solid
Uses
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline is used for preparation polyimide and epoxy resin material.
Uses
It is applied in pharmaceutical industry.
Application
2,2-Bis[4-(4-aminophenoxy)phenyl] propane (BAPP) can be used for:
(1) Preparation of polyimides. The glass transition temperature of this new polyimide is about 225-230°C. It has the typical yield of thermoplastic polymers. It has a typical thermoplastic polymer yield behaviour, which is very different from other polyimides. The elongation at break was 6% and 29% for polyamide and polyimide, respectively.
(2) Curing epoxy resin (ER) and poly(?-caprolactone) (PCL) for the preparation of crystalline thermoset blends.
(3) Constructing dental resin composites.
Synthesis
2,2‐Bis[4‐(4‐aminophenoxy)phenyl] propane (BAPP), as a monomer to prepare polyimide, was synthesized from Bisphenol A and p‐chloronitrobenzene via the nucleophilic substitution reaction[1].
References
[1] CUILI KONG. Synthesis, Structures and Properties of Polyimide Based on 2,2′‐Bis(4‐aminophenoxy phenyl) Propane[J]. Journal of Macromolecular Science, Part A, 2006. DOI:10.1080/10601320600941086.
![20653-11-6](/CAS/GIF/20653-11-6.gif)
![13080-86-9](/CAS/GIF/13080-86-9.gif)
2,2-Bis[4-(4-aminophenoxy)phenyl]propane Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shanghai Daeyeon Chemicals Co., Ltd | 021-64478606 +8615900664856 | daeyeon001@vip.163.com | China | 2062 | 58 |
CHINATECH(TIANJIN) CHEMICAL CO.,LTD. | +8618222493702 | sales8@chinatechem.com | China | 64 | 58 |
Heynova (Shanghai) New Material Technology CO., Ltd | +8617821320848 | zoe@heynovachem.com | China | 431 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86-13288715578 +8613288715578 | sales@hbmojin.com | China | 12464 | 58 |
Henan Bao Enluo International TradeCo.,LTD | +86-17331933971 +86-17331933971 | deasea125996@gmail.com | China | 2503 | 58 |
Hangzhou ICH Biofarm Co., Ltd | +86-0571-28186870; +undefined8613073685410 | sales@ichemie.com | China | 985 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20383 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21680 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9338 | 55 |
Related articles
- Synthesis and Application of 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline
- 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline can be used in new polyester materials.
- Sep 13,2022
View Lastest Price from 2,2-Bis[4-(4-aminophenoxy)phenyl]propane manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2024-06-28 | 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline
13080-86-9
|
US $142.00-135.00 / kg | 1kg | 99.99% | 100Tons | Hebei Dangtong Import and export Co LTD | |
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2024-01-23 | 2,2'-Bis(4-aminophenoxyphenyl)propane(BAPP)
13080-86-9
|
US $0.00 / KG | 1KG | 99.00% | 1500KG/month | Shanghai Daken Advanced Materials Co.,Ltd | |
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2024-01-08 | 4,4'-((Propane-2,2-diylbis(4,1-phenylene))bis(oxy))dianiline
13080-86-9
|
US $111.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd |
-
- 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline
13080-86-9
- US $142.00-135.00 / kg
- 99.99%
- Hebei Dangtong Import and export Co LTD
-
- 2,2'-Bis(4-aminophenoxyphenyl)propane(BAPP)
13080-86-9
- US $0.00 / KG
- 99.00%
- Shanghai Daken Advanced Materials Co.,Ltd
-
- 4,4'-((Propane-2,2-diylbis(4,1-phenylene))bis(oxy))dianiline
13080-86-9
- US $111.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd