Methyl 1H-pyrrole-3-carboxylate
- CAS No.
- 2703-17-5
- Chemical Name:
- Methyl 1H-pyrrole-3-carboxylate
- Synonyms
- Methyl Pyrrole-3-carboxylate;EOS-61577;Methyl 3-pyrrolecarboxylate;Methyl1H-pyrrole-3-carboxylat;3-(Methoxycarbonyl)-1H-pyrrole;Methyl 1H-pyrrole-3-carboxylate;Methyl 1H-pyrrole-3-carboxylate, 95+%;Pyrrole-3-carboxylic acid methyl ester;1,1-dibromo-2-(chloromethyl)cyclopropane;1H-Pyrrole-3-carboxylic acid methyl ester
- CBNumber:
- CB41086094
- Molecular Formula:
- C6H7NO2
- Molecular Weight:
- 125.13
- MDL Number:
- MFCD00967074
- MOL File:
- 2703-17-5.mol
| Melting point | 85-89 °C |
|---|---|
| Boiling point | 284℃ |
| Density | 1.184 |
| Flash point | 126℃ |
| storage temp. | Inert atmosphere,Room Temperature |
| pka | 15.42±0.50(Predicted) |
| form | solid |
| color | Off-white to light yellow |
| Water Solubility | Slightly soluble in water. |
| InChI | InChI=1S/C6H7NO2/c1-9-6(8)5-2-3-7-4-5/h2-4,7H,1H3 |
| InChIKey | WLBNVSIQCFHAQB-UHFFFAOYSA-N |
| SMILES | N1C=CC(C(OC)=O)=C1 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-37-60 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 29339900 | |||||||||
| NFPA 704 |
|
Methyl 1H-pyrrole-3-carboxylate price More Price(29)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 685399 | Methyl 1H-pyrrole-3-carboxylate 97% | 2703-17-5 | 1g | $72.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 685399 | Methyl 1H-pyrrole-3-carboxylate 97% | 2703-17-5 | 250mg | $63.8 | 2023-06-20 | Buy |
| Alfa Aesar | H54340 | Methyl pyrrole-3-carboxylate, 97% | 2703-17-5 | 1g | $118.65 | 2024-03-01 | Buy |
| Alfa Aesar | H54340 | Methyl pyrrole-3-carboxylate, 97% | 2703-17-5 | 5g | $463.65 | 2024-03-01 | Buy |
| Alfa Aesar | H54340 | Methyl pyrrole-3-carboxylate, 97% | 2703-17-5 | 250mg | $37 | 2021-12-16 | Buy |
Methyl 1H-pyrrole-3-carboxylate Chemical Properties,Uses,Production
Uses
Methyl pyrrole-3-carboxylate is used as an organic chemical synthesis intermediate.
Application
A solution of methyl 1H-pyrrole-3-carboxylate (4.48 g, 35.8 mmol) in THF (70 mL) was cooled to -78 °C, N-bromosuccinimide (6.30 g, 35.4 mmol) was added, pyridine (five drops) was added, and the mixture was left standing in a freezer (-20 °C) for 3 days. The reaction mixture was concentrated under reduced pressure. Water was added to the residue, and the mixture was extracted using EtOAc. The extract was washed with brine, dried over Na2SO4, and concentrated under reduced pressure. The residue was purified by silica gel column chromatography (hexane-EtOAc = 9/1-1/1) to give Methyl 5-bromo-1H-pyrrole-3-carboxylate (3.59 g, 49percent) as a pale-yellow solid.
Research
Pyrrole and Methyl 1H-Pyrrole-3-Carboxylate could be used to prepare the Soft Actuators by Electrochemical Copolymerization. In specific, a counter electrode (Ti), a reference electrode (Ag/AgCl), and a working electrode (Ti) were immersed into methyl benzoate solutions of 0.25 M of pyrrole and methyl 1-H pyrrole-3-carboxylate with 100:0, 98:2, 95:5, 80:20 mol ratios and 0.2 M N, N-diethyl-N-methyl-N-(2-methoxyethyl)ammonium bis(trifluoromethanesulfonyl) imide. The thickness of the prepared films was measured to be approximately 100 μm using a micrometer. The PPy actuator was used as the working electrode in the 1 M LiTFSI aqueous electrolyte solutions. The Py copolymer film, fabricated from pyrrole solution containing 2 and 5 mol% of methyl 1-H pyrrole-3-carboxylate, showed a reduced actuating strain of approximately 2%, but the creep strain was reduced to less than 1%[1].
References
[1] Yamasaki, Jun et al. “Soft Actuators Prepared by Electrochemical Copolymerization of Pyrrole and Methyl 1H-Pyrrole-3-Carboxylate.” 2013. 0.
Methyl 1H-pyrrole-3-carboxylate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Jiangsu Vcan Advanced Material Co., Ltd. | +86-17306299870 +86-18652789875 | vcanam@vcanam.com | China | 38 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29793 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32956 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29880 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 18028 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39894 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63687 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49374 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9636 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
View Lastest Price from Methyl 1H-pyrrole-3-carboxylate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-07-06 | 1H-Pyrrole-3-carboxylic acid, methyl ester (9CI)
2703-17-5
|
US $8.00 / KG | 1KG | 99% | 10tons | Career Henan Chemical Co |
-
- 1H-Pyrrole-3-carboxylic acid, methyl ester (9CI)
2703-17-5
- US $8.00 / KG
- 99%
- Career Henan Chemical Co
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