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1,3-Bis(diphenylphosphino)propane

1,3-Bis(diphenylphosphino)propane Structure
1,3-Bis(diphenylphosphino)propane structure
CAS No.
6737-42-4
Chemical Name:
1,3-Bis(diphenylphosphino)propane
Synonyms
DPPP;1,3-bis(diphenyphosphino)propane;1,3-BIS(DIPHENYLPHOSPHINE)PROPANE;Bis(1,3-diphenylphosphino)propane;98% DPPP;1,3-Bis(diphenyL;phosphino)propane;PH2PCH2 CH2CH2PPH2;1,3-BIS(DIPHENYPHOSPHINO);1,3-bis-(diphosphino)propane
CBNumber:
CB4132404
Molecular Formula:
C27H26P2
Molecular Weight:
412.45
MDL Number:
MFCD00003050
MOL File:
6737-42-4.mol
MSDS File:
SDS
Last updated:2025-01-27 09:38:02
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1,3-Bis(diphenylphosphino)propane Properties

Melting point 63-65 °C (lit.)
Boiling point 529.7±33.0 °C(Predicted)
Flash point 235°C
storage temp. Inert atmosphere,Room Temperature
form Granules or Powder
color White to light yellow-beige
Water Solubility insoluble
Sensitive Air Sensitive
BRN 2821785
InChI InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
InChIKey LVEYOSJUKRVCCF-UHFFFAOYSA-N
SMILES P(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1
CAS DataBase Reference 6737-42-4(CAS DataBase Reference)
FDA UNII 44R56E2C68
NIST Chemistry Reference 1,3-Bis(diphenylphosphino)propane(6737-42-4)
EPA Substance Registry System Phosphine, 1,3-propanediylbis[diphenyl- (6737-42-4)
UNSPSC Code 12352002
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39-36
WGK Germany  3
F  10-23
TSCA  Yes
HS Code  29310095
NFPA 704
1
2 0

1,3-Bis(diphenylphosphino)propane price More Price(41)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 262048 1,3-Bis(diphenylphosphino)propane 97% 6737-42-4 1g $35.4 2024-03-01 Buy
Sigma-Aldrich 262048 1,3-Bis(diphenylphosphino)propane 97% 6737-42-4 5g $65.3 2024-03-01 Buy
TCI Chemical B1138 1,3-Bis(diphenylphosphino)propane >98.0%(GC) 6737-42-4 5g $34 2024-03-01 Buy
TCI Chemical B1138 1,3-Bis(diphenylphosphino)propane >98.0%(GC) 6737-42-4 25g $79 2024-03-01 Buy
Alfa Aesar A12931 1,3-Bis(diphenylphosphino)propane, 97% 6737-42-4 5g $76.9 2024-03-01 Buy
Product number Packaging Price Buy
262048 1g $35.4 Buy
262048 5g $65.3 Buy
B1138 5g $34 Buy
B1138 25g $79 Buy
A12931 5g $76.9 Buy

1,3-Bis(diphenylphosphino)propane Chemical Properties,Uses,Production

Description

1,3-Bis(diphenylphosphino)propane is a ligand for metal-catalyzed substitution reactions of aryl and vinyl triflates, halides, and carbonates; carbonylation reactions; Grignard coupling; diene alkylation; macrocycle synthesis.

Chemical Properties

white to light yellow crystal powde

Uses

1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

reaction suitability

reagent type: ligand
reaction type: C-C Bond Formation
reagent type: ligand
reaction type: Carbonylations
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

1,3-Bis(diphenylphosphino)propane synthesis

16524-41-7
6737-42-4
Synthesis of 1,3-Bis(diphenylphosphino)propane from 3-(diphenylphosphoryl)propyl(diphenyl)phosphine oxide

1,3-Bis(diphenylphosphino)propane Preparation Products And Raw materials

Raw materials

Diphenylphosphine Ethanol 1,3-Dichloropropane Acetone Sodium
1,3-Dibromopropane Tetrahydrofuran Ethyl acetate Hydrochloric acid Dichloromethane
Sodium hydroxide Triphenylphosphine Magnesium sulfate Lithium n-Butyllithium
3-(diphenylphosphoryl)propyl(diphenyl)phosphine oxide Diphenylphosphine oxide 1-Bromo-3-chloropropane

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Preparation Products

3-DODECYLTHIOPHENE [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride

1,3-Bis(diphenylphosphino)propane Suppliers

Global( 510)Suppliers
Supplier Tel Email Country ProdList Advantage
Shaoxin Catsyn Co., Ltd.
+undefined-0575-82040869 +86-0575-82040869; sales@catsyn.com China 6114 58
Hebei Mujin Biotechnology Co.,Ltd 		+86 13288715578 +8613288715578 sales@hbmojin.com China 12809 58
Hebei Yanxi Chemical Co., Ltd. 		+8617531153977 allison@yan-xi.com China 5854 58
Shanghai UCHEM Inc. 		+862156762820 +86-13564624040 sales@myuchem.com China 7906 58
Hebei Chuanghai Biotechnology Co., Ltd 		+8615531151365 mina@chuanghaibio.com China 18137 58
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-+86-371-66670886 info@dakenam.com China 19805 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21628 55
Nanjing ChemLin Chemical Industry Co., Ltd. 		025-83697070 product@chemlin.com.cn CHINA 3009 60
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 33024 60
AB PharmaTech,LLC 		323-480-4688 sales@acrospharmatech.com United States 989 55
Supplier Advantage
Shaoxin Catsyn Co., Ltd.
58
Hebei Mujin Biotechnology Co.,Ltd 		58
Hebei Yanxi Chemical Co., Ltd. 		58
Shanghai UCHEM Inc. 		58
Hebei Chuanghai Biotechnology Co., Ltd 		58
Shanghai Daken Advanced Materials Co.,Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
Nanjing ChemLin Chemical Industry Co., Ltd. 		60
ATK CHEMICAL COMPANY LIMITED 		60
AB PharmaTech,LLC 		55

Related articles

View Lastest Price from 1,3-Bis(diphenylphosphino)propane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,3-Bis(diphenylphosphino)propane pictures 2025-04-25 1,3-Bis(diphenylphosphino)propane
6737-42-4
 US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
1,3-Bis(diphenylphosphino)propane pictures 2025-04-15 1,3-Bis(diphenylphosphino)propane
6737-42-4
 US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Chuanghai Biotechnology Co., Ltd
1,3-Bis(diphenylphosphino)propane pictures 2025-04-04 1,3-Bis(diphenylphosphino)propane
6737-42-4
 US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.

1,3-Bis(diphenylphosphino)propane Spectrum

1,3-Bis(diphenylphosphino)propane(6737-42-4)MS1,3-Bis(diphenylphosphino)propane(6737-42-4)1HNMR1,3-Bis(diphenylphosphino)propane(6737-42-4)31PNMR1,3-Bis(diphenylphosphino)propane(6737-42-4)IR11,3-Bis(diphenylphosphino)propane(6737-42-4)IR2

6737-42-4(1,3-Bis(diphenylphosphino)propane)Related Search:

BIS-Tris Propane Di(trimethylol propane) Diphenylmethane tert-Butylchlorodiphenylsilane N-(Carboxymethyl)-N-(phosphonomethyl)-glycine
Diphenylsilane Chlorodiphenylphosphine Diphenylphosphine 1,1'-Bis(diphenylphosphino)ferrocene 1,2-Bis(diphenylphosphino)ethane
1,4-Bis(diphenylphosphino)butane Propane DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II) (2R,4R)-(+)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE (2S,4S)-(-)-2,4-BIS(DIPHENYLPHOSPHINO)PENTANE
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride 1,1,1-TRIS(DIPHENYLPHOSPHINOMETHYL)ETHANE TRIMETHYLENEBIS(TRIPHENYLPHOSPHONIUM BROMIDE)

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1,3-BIS(DIPHENYLPHOSPHINO)PROPANE TRIMETHYLENEBIS(DIPHENYLPHOSPHINE) [3-(Diphenylphosphino)propyl](diphenyl)phosphine 1,3-Propanediylbis(diphenylphosphine) Phosphine, 1,3-propanediylbis[diphenyl- Phosphine, trimethylenebis(diphenyl- Propane-1,3-diylbis(diphenylphosphine) PROPYLENEBIS(DIPHENYLPHOSPHINE) 1,3-bis(diphenyphosphino)propane(dppp) 1,3-Bis(Diphenlphosphino)Propane 1,3-Bis(diphenylphosphino)propane,98%DPPP DPPP/ 1,3-BIS(DIPHENYLPHOSPHINE)PROPANE DPPP/1,3-BIS- (DIPHENYLPHOSPHINO)PROPANE PH2PCH2 CH2CH2PPH2 1,3-propanediylbis[diphenyl-phosphin 1, 3 - a double (diphenyl phosphine) propane 1,3-Bis(diphenylphosphino)propane Propane-1,3-diylbis(diphenylphosphine) 1-(phenyl(3-(diphenylphosphino)propyl)phosphino)benzene 1,3-BIS(DIPHENYPHOSPHINO) 1,3-Bis(diphenylphosphino)propane, C 77.5%, H 6.5% 1,3-Bis(diphenylphosphino)propane,97% 3-Di(phenyl)phosphanylpropyl-di(phenyl)phosphane 1,3-Bis(diphenylphosphino)propane ,98% 1,3-Bis(diphenylphosphino)propane, 97% 5GR 98% DPPP 1,3-Bis(diphenylphosphiNA)propane 1,3-Bis(diphenylphosphino)prop Bis diphenylphosphino propane Propane-1,3-diylbis(diphenylphosphane) 98% Propane-1,3-diylbis(diphenylphosphine), 1,3-Bis(diphenylphosphino)propane 1,3- double(twophenylphosphine groups)propane(DPPP) 1,3-Bis(diphenylphosphino)propane, 95+% DPPP (1,3-Bis(Diphenylphosphino)Propane) extrapure, 98% 1,3- bis(diphenylphosphaneyI)propane (DPPP) Phosphine, 1,1'-(1,3-propanediyl)bis[1,1-diphenyl- 1,3-Bis(diphenylphosphino)propane, 97%, for synthesis 1,3-Bis(diphenylphosphino)propane > phosphino)propane 1,3-Bis(diphenyL 1,3-bis-(diphosphino)propane ,3-Bis(diphenylphosphino)propane 1,3-BIS(DIPHENYLPHOSPHINE)PROPANE DPPP Bis(1,3-diphenylphosphino)propane 1,3-bis(diphenyphosphino)propane 1,3-Bis(diphenylphosphanyl)propane 6737-42-4 C6H52PCH2CH2CH2PC6H52 C6H52PCH23PC6H52 C27H26P2 Phosphine Ligands Phosphorus Compounds Polydentate Phosphine Ligands Catalysis and Inorganic Chemistry Phosphine Ligands Synthetic Organic Chemistry Ligand API intermediates