ChemicalBook >> CAS DataBase List >>BRUCINE
BRUCINE
- CAS No.
- 5892-11-5
- Chemical Name:
- BRUCINE
- Synonyms
- BRUCINE ALKALOID;BURCINETETRAHYDRATE;BRUCINE TETRAHYDRATE;BRUCINE HYDRATE, TECH.;2,3-DIMETHOXYSTRYCHNIDIN-10-ONE;STRYCHNIDIN-10-ONE,2,3-DIMETHOXY;Paper Chemicals Wet Strength Agent 12.5%;Strychnidin-10-one, 2,3-dimethoxy-, tetrahydrate;Wet Strength Agent - Polyamide Epichlorohydrin Resin/Pae 12.5%
- CBNumber:
- CB4208446
- Molecular Formula:
- C23H26N2O4
- Molecular Weight:
- 394.46
- MDL Number:
- MFCD00005942
- MOL File:
- 5892-11-5.mol
Last updated:2023-04-23 13:52:06
| Melting point | 175-178 °C (dec.)(lit.) |
|---|---|
| optical activity | [α]20/D 67°, c = 1.3 in ethanol |
| Water Solubility | Soluble in methanol. Partially soluble Miscible with water. |
| CAS DataBase Reference | 5892-11-5(CAS DataBase Reference) |
| FDA UNII | UEJ23QX4RE |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H300+H330-H412 | |||||||||
| Precautionary statements | P273-P301+P310+P330-P304+P340+P310 | |||||||||
| Hazard Codes | T+ | |||||||||
| Risk Statements | 26/28-52/53-36/37/38-26/27/28 | |||||||||
| Safety Statements | 13-45-61-36/37-28 | |||||||||
| RIDADR | UN 1570 6.1/PG 1 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | EH8925000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | I | |||||||||
| NFPA 704 |
|
BRUCINE price More Price(11)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 367869 | Brucine hydrate technical grade | 5892-11-5 | 100g | $316.2 | 2024-03-01 | Buy |
| Alfa Aesar | A16251 | Brucine dihydrate, 98% | 5892-11-5 | 10g | $37.65 | 2024-03-01 | Buy |
| Alfa Aesar | A16251 | Brucine dihydrate, 98% | 5892-11-5 | 50g | $103.65 | 2024-03-01 | Buy |
| Biosynth Carbosynth | FB31436 | Brucine dihydrate | 5892-11-5 | 100g | $800 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FB31436 | Brucine dihydrate | 5892-11-5 | 250g | $1000 | 2021-12-16 | Buy |
BRUCINE Chemical Properties,Uses,Production
Uses
Resolving agentBrucine dihydrate is used as a resolving agent for chiral acids.
Purification Methods
Crystallise brucine once from water or aqueous Me2CO (as the tetrahydrate), then suspend it in CHCl3 and shake with anhydrous Na2SO4 (to dehydrate the brucine, which then dissolves). Precipitate it by pouring the solution into a large bulk of dry pet ether (b 40-60o), filter and heat to 120o in a high vacuum [Turner J Chem Soc 842 1951]. The tetrahydrate crystallises from a mixture of EtOH and H2O as colourless elongated needles [Eeles Acta Cryst 6 809 1953, Beilstein 27 III/IV 7875.] VERY POISONOUS
BRUCINE Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 43)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
| Mainchem Co., Ltd. | +86-0592-6210733 | sale@mainchem.com | China | 32343 | 55 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 021-61259108 18621169109 | market03@meryer.com | China | 40228 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30123 | 84 |
| Beijing Ouhe Technology Co., Ltd | 010-82967028 13552068683 | 2355560935@qq.com | China | 12390 | 60 |
| Hubei Shishun Biotechnology Co. Ltd | 027-59223025 15107168801 | 1718480011@qq.com | China | 9867 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | 029-61856358 15229202216 | 1020@dideu.com | China | 10007 | 58 |
| Carbosynth | -- | sales@carbosynth.com | United Kingdom | 6005 | 58 |
STRYCHNIDIN-10-ONE,2,3-DIMETHOXY
2,3-DIMETHOXYSTRYCHNIDIN-10-ONE
BRUCINE HYDRATE, TECH.
Strychnidin-10-one, 2,3-dimethoxy-, tetrahydrate
BURCINETETRAHYDRATE
BRUCINE TETRAHYDRATE
BRUCINE ALKALOID
Paper Chemicals Wet Strength Agent 12.5%
Wet Strength Agent - Polyamide Epichlorohydrin Resin/Pae 12.5%
5892-11-5
C23H26N2O44H2O
Alkaloids
for Resolution of Acids
Optical Resolution
Indole Alkaloids
Asymmetric Synthesis
Chiral Resolution Reagents
Chiral Resolving Reagents
Chiral Resolving ReagentsAsymmetric Synthesis
Asymmetric Synthesis
Chiral Building Blocks
Chiral Resolution Reagents
Complex Molecules