(3β,16E,20β)-16,17,18,19-Tetradehydro-17-methoxycorynan-16-carboxylic acid methyl ester

CAS No.
57820-49-2
Chemical Name:
(3β,16E,20β)-16,17,18,19-Tetradehydro-17-methoxycorynan-16-carboxylic acid methyl ester
Synonyms
Epiallocorynantheine;epiallo-Corynantheine;(3β,16E,20β)-16,17,18,19-Tetradehydro-17-methoxycorynan-16-carboxylic acid methyl ester;Indolo[2,3-a]quinolizine-2-acetic acid, 3-ethenyl-1,2,3,4,6,7,12,12b-octahydro-α-(methoxymethylene)-, methyl ester, (αE,2S,3S,12bR)-
CBNumber:
CB42230070
Molecular Formula:
C22H26N2O3
Molecular Weight:
366.45
MDL Number:
MOL File:
57820-49-2.mol

(3β,16E,20β)-16,17,18,19-Tetradehydro-17-methoxycorynan-16-carboxylic acid methyl ester Properties

Boiling point 533.2±50.0 °C(Predicted)
Density 1.22±0.1 g/cm3(Predicted)
pka 18.03±0.60(Predicted)

(3β,16E,20β)-16,17,18,19-Tetradehydro-17-methoxycorynan-16-carboxylic acid methyl ester Chemical Properties,Uses,Production

Description

This stereoisomer of corynantheine has recently been isolated from Hunteria attenuata. It has the structure shown which is based upon chemical and spectroscopic data.

References

Phillipson, Hemingway, Phytochem., 14, 1855 (1975)

(3β,16E,20β)-16,17,18,19-Tetradehydro-17-methoxycorynan-16-carboxylic acid methyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

(3β,16E,20β)-16,17,18,19-Tetradehydro-17-methoxycorynan-16-carboxylic acid methyl ester Epiallocorynantheine epiallo-Corynantheine Indolo[2,3-a]quinolizine-2-acetic acid, 3-ethenyl-1,2,3,4,6,7,12,12b-octahydro-α-(methoxymethylene)-, methyl ester, (αE,2S,3S,12bR)- 57820-49-2