Trifluoromethanesulfonyl chloride
- CAS No.
- 421-83-0
- Chemical Name:
- Trifluoromethanesulfonyl chloride
- Synonyms
- TRIFLYL CHLORIDE;PFC-MSC;Trifluoromethane chloride;TRIFLUOROMETHANESULFONYLCLORIDE;trifluoromethylsulfonyl chloride;Trifluoromethanesufonyl chloride;RIFLUOROMETHANESULFONYL CHLORIDE;Trifluoromathanesulfonyl chloride;TRIFLUOROMETHANESULFONYL CHLORIDE;Trifluoromethylsulphonyl chloride
- CBNumber:
- CB4253800
- Molecular Formula:
- CClF3O2S
- Molecular Weight:
- 168.52
- MDL Number:
- MFCD00007451
- MOL File:
- 421-83-0.mol
- MSDS File:
- SDS
Melting point | -26 °C |
---|---|
Boiling point | 29-32 °C (lit.) |
Density | 1.583 g/mL at 25 °C (lit.) |
vapor pressure | 10.36 psi ( 20 °C) |
refractive index |
n |
Flash point | 32°C |
storage temp. | 2-8°C |
solubility | Chloroform |
form | Liquid |
color | Clear colorless to faintly colored |
Specific Gravity | 1.583 |
Water Solubility | Hydrolyzes with water. |
Sensitive | Lachrymatory |
BRN | 1812016 |
InChIKey | GRGCWBWNLSTIEN-UHFFFAOYSA-N |
CAS DataBase Reference | 421-83-0(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H314 | |||||||||
Precautionary statements | P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405 | |||||||||
Hazard Codes | C | |||||||||
Risk Statements | 14-34 | |||||||||
Safety Statements | 26-36/37/39-45 | |||||||||
RIDADR | UN 3265 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
F | 10-21 | |||||||||
Hazard Note | Corrosive/Lachrymatory | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29049090 | |||||||||
NFPA 704 |
|
Trifluoromethanesulfonyl chloride price More Price(22)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 164798 | Trifluoromethanesulfonyl chloride ≥99% | 421-83-0 | 5g | $79.3 | 2024-03-01 | Buy |
Sigma-Aldrich | 164798 | Trifluoromethanesulfonyl chloride ≥99% | 421-83-0 | 25g | $263 | 2024-03-01 | Buy |
TCI Chemical | T1027 | Trifluoromethanesulfonyl Chloride >98.0%(GC) | 421-83-0 | 5g | $65 | 2024-03-01 | Buy |
TCI Chemical | T1027 | Trifluoromethanesulfonyl Chloride >98.0%(GC) | 421-83-0 | 25g | $204 | 2024-03-01 | Buy |
Alfa Aesar | B21774 | Trifluoromethanesulfonyl chloride 98% | 421-83-0 | 5g | $72.9 | 2024-03-01 | Buy |
Trifluoromethanesulfonyl chloride Chemical Properties,Uses,Production
Chemical Properties
Clear colorless to faintly colored liquid
Uses
Ru(II) complex-catalyzed trifluoromethylating agent for aromatics and alkenes.
Application
Trifluoromethanesulfonyl chloride can be used as:
A trifluoromethylating agent for the fluoroalkylation of heterocycles, arenes, and heteroarenes.
A sulfonating agent for alcohols.
A chlorinating agent for carbanions.
Synthesis
Add 150g (1mol) of trifluoromethanesulfonic acid to the reactor equipped with thermometer, distillation device and mechanical stirrer, slowly add 435mL (6mol) of thionyl chloride under ice bath, and then add the catalyst N,N-dimethyl Formamide 7.36 (0.1 mol), slowly raise the temperature to room temperature, stir for half an hour, continue to heat up to 40°C, continue to stir, react for 12 hours, and then drop to room temperature after the reaction is complete.Subsequently, vacuum distillation was carried out at 110° C. and -0.1 to -0.08 MPa, and at the same time, the temperature was slowly raised to 50° C. to obtain 147 g of trifluoromethanesulfonyl chloride, with a yield of 87.5%.
Trifluoromethanesulfonyl chloride Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Fluoropharm Co., Ltd. | +86-0571-85586753; +8613336034509 | sales@fluoropharm.com | China | 1376 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43340 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8812 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12840 | 58 |
Henan Bao Enluo International TradeCo.,LTD | +86-17331933971 +86-17331933971 | deasea125996@gmail.com | China | 2472 | 58 |
airuikechemical co., ltd. | +undefined86-15315557071 | sales02@sdzhonghuimaterial.com | China | 983 | 58 |
Shandong Deshang Chemical Co., Ltd. | +86-0531-8875-2665 +8613153039501 | info@deshangchem.com | China | 662 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18779 | 58 |
View Lastest Price from Trifluoromethanesulfonyl chloride manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-11-11 | Trifluoromethanesulfonyl chloride
421-83-0
|
US $10.00-7.00 / kg | 1kg | 99.99% | 10 tons | Shandong Deshang Chemical Co., Ltd. | ||
2024-11-06 | TRIFLUOROMETHANESULFONYL CHLORIDE
421-83-0
|
US $0.00-0.00 / KG | 1KG | 99% | 20 mt | Hebei Weibang Biotechnology Co., Ltd | ||
2024-10-15 | trifluoromethanesulfonyl chloride
421-83-0
|
US $0.00-0.00 / Kg | 1Kg | 99.9% | 200tons | airuikechemical co., ltd. |
- Trifluoromethanesulfonyl chloride
421-83-0
- US $10.00-7.00 / kg
- 99.99%
- Shandong Deshang Chemical Co., Ltd.
- TRIFLUOROMETHANESULFONYL CHLORIDE
421-83-0
- US $0.00-0.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
- trifluoromethanesulfonyl chloride
421-83-0
- US $0.00-0.00 / Kg
- 99.9%
- airuikechemical co., ltd.
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