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Trifluoromethanesulfonyl chloride

CAS No.
421-83-0
Chemical Name:
Trifluoromethanesulfonyl chloride
Synonyms
TRIFLYL CHLORIDE;PFC-MSC;Trifluoromethane chloride;TRIFLUOROMETHANESULFONYLCLORIDE;trifluoromethylsulfonyl chloride;Trifluoromethanesufonyl chloride;RIFLUOROMETHANESULFONYL CHLORIDE;Trifluoromathanesulfonyl chloride;TRIFLUOROMETHANESULFONYL CHLORIDE;Trifluoromethylsulphonyl chloride
CBNumber:
CB4253800
Molecular Formula:
CClF3O2S
Molecular Weight:
168.52
MDL Number:
MFCD00007451
MOL File:
421-83-0.mol
MSDS File:
SDS
Last updated:2024-11-06 15:28:16

Trifluoromethanesulfonyl chloride Properties

Melting point -26 °C
Boiling point 29-32 °C (lit.)
Density 1.583 g/mL at 25 °C (lit.)
vapor pressure 10.36 psi ( 20 °C)
refractive index n20/D 1.334(lit.)
Flash point 32°C
storage temp. 2-8°C
solubility Chloroform
form Liquid
color Clear colorless to faintly colored
Specific Gravity 1.583
Water Solubility Hydrolyzes with water.
Sensitive Lachrymatory
BRN 1812016
InChIKey GRGCWBWNLSTIEN-UHFFFAOYSA-N
CAS DataBase Reference 421-83-0(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405
Hazard Codes  C
Risk Statements  14-34
Safety Statements  26-36/37/39-45
RIDADR  UN 3265 8/PG 2
WGK Germany  3
10-21
Hazard Note  Corrosive/Lachrymatory
HazardClass  8
PackingGroup  II
HS Code  29049090
NFPA 704
1
3 2
W

Trifluoromethanesulfonyl chloride price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 164798 Trifluoromethanesulfonyl chloride ≥99% 421-83-0 5g $79.3 2024-03-01 Buy
Sigma-Aldrich 164798 Trifluoromethanesulfonyl chloride ≥99% 421-83-0 25g $263 2024-03-01 Buy
TCI Chemical T1027 Trifluoromethanesulfonyl Chloride >98.0%(GC) 421-83-0 5g $65 2024-03-01 Buy
TCI Chemical T1027 Trifluoromethanesulfonyl Chloride >98.0%(GC) 421-83-0 25g $204 2024-03-01 Buy
Alfa Aesar B21774 Trifluoromethanesulfonyl chloride 98% 421-83-0 5g $72.9 2024-03-01 Buy
Product number Packaging Price Buy
164798 5g $79.3 Buy
164798 25g $263 Buy
T1027 5g $65 Buy
T1027 25g $204 Buy
B21774 5g $72.9 Buy

Trifluoromethanesulfonyl chloride Chemical Properties,Uses,Production

Chemical Properties

Clear colorless to faintly colored liquid

Uses

Ru(II) complex-catalyzed trifluoromethylating agent for aromatics and alkenes.

Application

Trifluoromethanesulfonyl chloride can be used as:
A trifluoromethylating agent for the fluoroalkylation of heterocycles, arenes, and heteroarenes.
A sulfonating agent for alcohols.
A chlorinating agent for carbanions.

Synthesis

Add 150g (1mol) of trifluoromethanesulfonic acid to the reactor equipped with thermometer, distillation device and mechanical stirrer, slowly add 435mL (6mol) of thionyl chloride under ice bath, and then add the catalyst N,N-dimethyl Formamide 7.36 (0.1 mol), slowly raise the temperature to room temperature, stir for half an hour, continue to heat up to 40°C, continue to stir, react for 12 hours, and then drop to room temperature after the reaction is complete.Subsequently, vacuum distillation was carried out at 110° C. and -0.1 to -0.08 MPa, and at the same time, the temperature was slowly raised to 50° C. to obtain 147 g of trifluoromethanesulfonyl chloride, with a yield of 87.5%. TRIFLUOROMETHANESULFONYL CHLORIDE

1493-13-6
421-83-0
Synthesis of Trifluoromethanesulfonyl chloride from Trifluoromethanesulfonic acid
Global( 283)Suppliers
Supplier Tel Email Country ProdList Advantage
Fluoropharm Co., Ltd.
+86-0571-85586753; +8613336034509 sales@fluoropharm.com China 1376 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
LEAPCHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 43340 58
Hebei Weibang Biotechnology Co., Ltd
+8615531157085 abby@weibangbio.com China 8812 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12840 58
Henan Bao Enluo International TradeCo.,LTD
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airuikechemical co., ltd.
+undefined86-15315557071 sales02@sdzhonghuimaterial.com China 983 58
Shandong Deshang Chemical Co., Ltd.
+86-0531-8875-2665 +8613153039501 info@deshangchem.com China 662 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29791 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18779 58

View Lastest Price from Trifluoromethanesulfonyl chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Trifluoromethanesulfonyl chloride pictures 2024-11-11 Trifluoromethanesulfonyl chloride
421-83-0
US $10.00-7.00 / kg 1kg 99.99% 10 tons Shandong Deshang Chemical Co., Ltd.
TRIFLUOROMETHANESULFONYL CHLORIDE pictures 2024-11-06 TRIFLUOROMETHANESULFONYL CHLORIDE
421-83-0
US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Weibang Biotechnology Co., Ltd
trifluoromethanesulfonyl chloride pictures 2024-10-15 trifluoromethanesulfonyl chloride
421-83-0
US $0.00-0.00 / Kg 1Kg 99.9% 200tons airuikechemical co., ltd.
TRIFLUOROMETHANESULFONYL CHLORIDE TRIFLUOROMETHANESULPHONYL CHLORIDE Methanesulfonyl chloride, trifluoro- PFC-MSC Trifluoromathanesulfonyl chloride Trifluoromethanesulphonylchloride,99% trifluoromethylsulfonyl chloride Trifluoromethanesulphonyl chloride 99% TRIFLUOROMETHANESULFONYLCLORIDE TRIFLUOROMETHANESULFONYL CHLORIDE, 99+% Trifluoromethanesulfonylchloride,98% Trifluoromethylsulphonyl chloride Trifluoromethanesulfonic acid chloride Trifluoromethanesufonyl chloride Trifluoromethylsulphonyl chloride 99% TriMethylsilyltrilfluoroMethanesulfonate TrifluoroMethanesulfonyl chloride, 99% 25GR TRIFLUOROMETHANESULFONYL CHLORIDE FOR SY Three fluorineMethane sulfonyl chloride Trifluoromethanesulfonyl chloride, 99.5% trifluoromethanesulfonyl chloride CClF3O2S Trifluoromethane chloride Trifluoromethanesulfonyl chloride, 98%, for synthesis TRIFLYL CHLORIDE RIFLUOROMETHANESULFONYL CHLORIDE Trifluoromethanesulfonyl Chloride, ≥ 98.0% 421-83-0 421-86-0 CClF3O2S CF3SO2Cl C3F4l2 CF3ClO2S CClF3SO2 Protection and Derivatization Protecting and Derivatizing Reagents Others Synthetic Reagents Piperazine derivates organofluorine compounds Others Protecting and Derivatizing Reagents Protection and Derivatization