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3,5-Di-tert-butylsalicylaldehyde

3,5-Di-tert-butylsalicylaldehyde Structure
3,5-Di-tert-butylsalicylaldehyde structure
CAS No.
37942-07-7
Chemical Name:
3,5-Di-tert-butylsalicylaldehyde
Synonyms
3,5-DI-TERT-BUTYL-2-HYDROXYBENZALDEHYDE;3,5-DI-T-BUTYL-2-HYDROXYBENZALDEHYDE;Dapagliflozin Impurity 108;3,5- di Ding JishuiYang Quan;3,5-DI-TBUTYLSALICYLALDEHYDE;3,5-Di-tert-butylsalicylaldehyd;3,5-DI-TERT-BUTYLSALICYLALDEHYDE;3,5-di-tert-Butyl Salicylaldehtde;Ditert-butyl-2-hydroxybenzaldehyde;3,5-Bis(tert-butyl)salicylaldehyde
CBNumber:
CB4262967
Molecular Formula:
C15H22O2
Molecular Weight:
234.33
MDL Number:
MFCD00191998
MOL File:
37942-07-7.mol
MSDS File:
SDS
Last updated:2024-11-05 11:59:05
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3,5-Di-tert-butylsalicylaldehyde Properties

Melting point 59-61 °C(lit.)
Boiling point 277.6±35.0 °C(Predicted)
Density 1.006±0.06 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Soluble in DMSO and methanol.
pka 9.78±0.23(Predicted)
form Solid
color Off-White to Light Yellow
Sensitive Air Sensitive
BRN 1877810
InChIKey RRIQVLZDOZPJTH-UHFFFAOYSA-N
CAS DataBase Reference 37942-07-7(CAS DataBase Reference)
FDA UNII KQA2N5HW8Z

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
Hazard Note  Irritant
HS Code  29124990
NFPA 704
1
2 0

3,5-Di-tert-butylsalicylaldehyde price More Price(35)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 140414 3,5-Di-tert-butyl-2-hydroxybenzaldehyde 99% 37942-07-7 5g $50.7 2024-03-01 Buy
Sigma-Aldrich 140414 3,5-Di-tert-butyl-2-hydroxybenzaldehyde 99% 37942-07-7 25g $61.4 2024-03-01 Buy
TCI Chemical D2646 3,5-Di-tert-butylsalicylaldehyde >98.0%(GC) 37942-07-7 5g $16 2024-03-01 Buy
TCI Chemical D2646 3,5-Di-tert-butylsalicylaldehyde >98.0%(GC) 37942-07-7 25g $38 2024-03-01 Buy
Alfa Aesar B23834 3,5-Di-tert-butyl-2-hydroxybenzaldehyde, 99% 37942-07-7 5g $54.65 2024-03-01 Buy
Product number Packaging Price Buy
140414 5g $50.7 Buy
140414 25g $61.4 Buy
D2646 5g $16 Buy
D2646 25g $38 Buy
B23834 5g $54.65 Buy

3,5-Di-tert-butylsalicylaldehyde Chemical Properties,Uses,Production

Chemical Properties

3,5-Di-tert-butylsalicylaldehyde is white to yellow powder or chunks or crystal or crystalline powder

Uses

3,5-Di-tert-butylsalicylaldehyde is a salicylaldehyde derivative with antibacterial activity used in the preparation nickel complexes. 3,5-Di-tert-butylsalicylaldehyde is structurally related to 3,5-di-t-butylcatechol (DTCAT) but is not as potent an activator of rat skeletal muscle ryanodine receptor Ca2+ channel (RyRC).

Uses

3,5-Di-tert-butyl-2-hydroxybenzaldehyde is used in the synthesis of Mn(III)-salen complex and its diamino precursor 5,6-diamino-5,6-dideoxy-1,2-O-isopropylidene-3-O-methyl-β-L-idofuranose, chiral Schiff base ligand for an enantioselective copper-catalyzed addition of phenyl acetylene to imines, chiral oxazolidine ligand for the enantioselective addition of diethyl zinc to aldehydes and tin Schiff base complexes with histidine analogues. It has antibacterial activity and is used in the preparation nickel complexes. It is structurally related to 3,5-di-t-butylcatechol (DTCAT) but is not as potent an activator of rat skeletal muscle ryanodine receptor Ca2+ channel (RyRC).

Uses

3,5-Di-tert-butyl-2-hydroxybenzaldehyde was used in the synthesis of

  • Mn(III)-salen complex and its diamino precursor 5,6-diamino-5,6-dideoxy-1,2-O-isopropylidene-3-O-methyl-β-L-idofuranose
  • chiral Schiff base ligand for an enantioselective copper-catalyzed addition of phenylacetylene to imines
  • chiral oxazolidine ligand for the enantioselective addition of diethylzinc to aldehydes
  • tin Schiff base complexes with histidine analogues

Definition

ChEBI: 3,5-di-tert-butyl-2-hydroxybenzaldehyde is a hydroxybenzaldehyde.

Synthesis Reference(s)

The Journal of Organic Chemistry, 59, p. 1939, 1994 DOI: 10.1021/jo00086a062
Tetrahedron, 46, p. 793, 1990 DOI: 10.1016/S0040-4020(01)81362-4
Tetrahedron Letters, 13, p. 4205, 1972 DOI: 10.1016/S0040-4039(01)94276-5

General Description

3,5-Di-tert-butyl-2-hydroxybenzaldehyde undergoes condensation reaction with

  • methyl-2-{N-(2′-aminoethane)}-amino-1-cyclopentenedithiocarboxylate to yield Schiff base ligand
  • N,N-diethyl-2-methyl-1,4-phenylenediamine during the synthesis of copper(II) and cobalt(II) complexes of salicylaldimine

3,5-Di-tert-butylsalicylaldehyde synthesis

50-00-0
96-76-4
37942-07-7
Synthesis of 3,5-Di-tert-butylsalicylaldehyde from Formaldehyde and 2,4-Di-tert-butylphenol

3,5-Di-tert-butylsalicylaldehyde Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(+)-2-Methyl-2-propanesulfinamide 1,4,7,10,13-PENTAOXA-16-AZACYCLOOCTADECANE (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE 2,4-di-tert-butyl-6-[(E)-(hydroxyimino)methyl]phenol Phenol, 2,2'-[(1R,2R)-1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4,6-bis(1,1-dimethylethyl)-

3,5-Di-tert-butylsalicylaldehyde Suppliers

Global( 440)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd 		+86 13288715578 +8613288715578 sales@hbmojin.com China 12840 58
Hebei Weibang Biotechnology Co., Ltd 		+8617732866630 bess@weibangbio.com China 18154 58
hebei hongtan Biotechnology Co., Ltd 		+86-86-1913198-3935 +8617331935328 sales03@chemcn.cn China 970 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29791 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 18779 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
Hangzhou FandaChem Co.,Ltd. 		+8615858145714 FandaChem@Gmail.com China 9214 55
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29884 58
Shenzhen Nexconn Pharmatechs Ltd 		+86-755-89396905 +86-15013857715 admin@nexconn.com China 10310 58
Jinan Finer Chemical Co., Ltd 		+86-531-88989536 +86-15508631887 sales@finerchem.com China 2964 58
Supplier Advantage
Hebei Mojin Biotechnology Co., Ltd 		58
Hebei Weibang Biotechnology Co., Ltd 		58
hebei hongtan Biotechnology Co., Ltd 		58
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
Hangzhou FandaChem Co.,Ltd. 		55
career henan chemical co 		58
Shenzhen Nexconn Pharmatechs Ltd 		58
Jinan Finer Chemical Co., Ltd 		58

View Lastest Price from 3,5-Di-tert-butylsalicylaldehyde manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3,5-Di-tert-butylsalicylaldehyde pictures 2024-11-22 3,5-Di-tert-butylsalicylaldehyde
37942-07-7
 US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
3,5-Bis(1,1-dimethylethyl)-2-hydroxy-benzaldehyde pictures 2024-11-22 3,5-Bis(1,1-dimethylethyl)-2-hydroxy-benzaldehyde
37942-07-7
 US $30.00 / kg 1kg 98% 2000kg hebei hongtan Biotechnology Co., Ltd
3,5-Bis(1,1-dimethylethyl)-2-hydroxy-benzaldehyde pictures 2024-11-21 3,5-Bis(1,1-dimethylethyl)-2-hydroxy-benzaldehyde
37942-07-7
 US $0.00 / KG 1KG ≥99% 200mt/year Jinan Finer Chemical Co., Ltd

3,5-Di-tert-butylsalicylaldehyde Spectrum

3,5-Di-tert-butylsalicylaldehyde(37942-07-7)FT-IR3,5-Di-tert-butylsalicylaldehyde(37942-07-7)IR

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3,5- di Ding JishuiYang Quan 3,5-Di-tert-butylsalicylaldehyde, 95+% 3, 5-2 tertiary butyl salicylaldehyde 3,5-Di-tert-butylsalicylaldehyde 3,5-Di-tert-butyl-2-hydroxybenzaldehyde 99% 3,5-DI-TBUTYLSALICYLALDEHYDE 3,5-DI-TERT-BUTYLSALICYLALDEHYDE 3,5-bis(1,1-dimethylethyl)-2-hydroxy-benzaldehyde BENZALDEHYDE, 3,5-BIS(1,1-DIMETHYLETHYL)-2-HYDROXY- 3,5-di-tert-Butyl Salicylaldehtde Ditert-butyl-2-hydroxybenzaldehyde 3,5-DI-TER-BUTYL-2-HYDROXYBENZYLALDEHYDE 3,5-DITERT-BUTYL-2-HYDROXYBENZALEDHYDE 3,5-Di-tert-butyl-2-hydroxybenzaldehyde,3,5-Di-tert-butylsalicylaldehyde 3,5-Bis(tert-butyl)-2-hydroxybenzaldehyde 3,5-Bis(tert-butyl)salicylaldehyde 3,5-Di-tert-butyl-2-hydroxybenzaldehyde ,99% 3,5-Bis(tert-butyl)-2-hydroxybenzaldehyde 99% 3,5-Bis(tert-butyl)salicylaldehyde, 2,4-Bis(tert-butyl)-6-formylphenol 2-Hydroxy-3,5-di-tert-butylbenzaldehyde 3,5-Di-tert-butyl-2-hydroxybenzaldehyde, 99%, for synthesis 3,5-Di-tert-butylsalicylaldehyde> Dapagliflozin Impurity 108 high quality 3,5-Bis(1,1-dimethylethyl)-2-hydroxy-benzaldehyde 3,5-DI-TERT-BUTYL-2-HYDROXYBENZALDEHYDE 3,5-DI-T-BUTYL-2-HYDROXYBENZALDEHYDE 3,5-Di-tert-butylsalicylaldehydene 3,5-Di-tert-butylsalicylaldehyd 37942-07-7 37492-07-7 39742-09-7 37942-04-7 HOC6H2CCH332CHO ALDEHYDE Carbonyl Compounds C10 to C21 Building Blocks Aldehydes Organic Building Blocks Building Blocks C13-C60 Carbonyl Compounds Chemical Synthesis Organic Building Blocks Aromatic Aldehydes & Derivatives (substituted) Aldehydes Phenyls & Phenyl-Het Phenyls & Phenyl-Het Achiral Oxygen 37942-07-7