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[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride

[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Structure
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride structure
CAS No.
191654-69-0
Chemical Name:
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride
Synonyms
[PdCl2{(R)-4-tolylbinap}];[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride
CBNumber:
CB42637848
Molecular Formula:
C48H42Cl2P2Pd
Molecular Weight:
858.13
MDL Number:
MFCD11656205
MOL File:
191654-69-0.mol
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[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Properties

Melting point >300°C

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332-H315-H319-H335
Precautionary statements  P261-P280-P305+P351+P338
Hazard Codes  Xn
Risk Statements  20/21/22-36/37/38
Safety Statements  26
WGK Germany  3

[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 708461 [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride 191654-69-0 100mg $50.9 2023-06-20 Buy
Sigma-Aldrich 708461 [(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladium(II) chloride 191654-69-0 500mg $137 2022-05-15 Buy
American Custom Chemicals Corporation ING0013493 [(R)-(+)-2,2'-BIS-(DI-PARA-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE 95.00% 191654-69-0 5MG $496.53 2021-12-16 Buy
Product number Packaging Price Buy
708461 100mg $50.9 Buy
708461 500mg $137 Buy
ING0013493 5MG $496.53 Buy

[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Chemical Properties,Uses,Production

Uses

Catalyst for:

  • Enantioselective preparation of hydroxydicarbonyls via aldol addition of pyruvates and diketones with ketene thioacetal
  • Stereoselective aldol condensation using trimethyl[[(phenyl)ethenyl]oxy]silane and benzaldehyde as reactants
  • Stereoselective preparation of naphthalenols via alkylative ring opening of oxabenzonorbornadienes with dialkylzinc

Reactant for:
  • Preparation of palladium bis(diphenylphosphino)binaphthyl aqua mononuclear and hydroxo-bridged dinuclear complexes

[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Preparation Products And Raw materials

Raw materials

Preparation Products

[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride Suppliers

Global( 4)Suppliers
Supplier Tel Email Country ProdList Advantage
Aladdin Scientific 		+1-+1(833)-552-7181 sales@aladdinsci.com United States 52924 58
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51456 80
Baoji Didu Pharmaceutical and Chemical Co., Ltd 02961856358 15829046862 1035@dideu.com China 10011 58
Supplier Advantage
Aladdin Scientific 		58
Sigma-Aldrich 80
Baoji Didu Pharmaceutical and Chemical Co., Ltd 58
[(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl]palladiuM(II) chloride [PdCl2{(R)-4-tolylbinap}] 191654-69-0