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MANGANESE(III) FLUORIDE

CAS No.
7783-53-1
Chemical Name:
MANGANESE(III) FLUORIDE
Synonyms
MnF3;Manganic fluoride;MANGANESE TRIFLUORIDE;Manganese(Ⅲ) Fluoride;MANGANESE(III) FLUORIDE;manganesefluoride(mnf3);Manganese fluoride (III);Manganese fluoride (MnF3);Manganese(III)fluoride99%;Manganese(III)fluoride,98%
CBNumber:
CB4356370
Molecular Formula:
F3Mn
Molecular Weight:
111.93
MDL Number:
MFCD00016223
MOL File:
7783-53-1.mol
MSDS File:
SDS
Last updated:2024-08-28 13:53:23

MANGANESE(III) FLUORIDE Properties

Melting point decomposes at >600℃ [KIR81]
Density 3.54 g/mL at 25 °C(lit.)
solubility reacts with H2O
form Powder
Specific Gravity 3.54
color red
Water Solubility Insoluble in organic solvents. Hydrolyzed by water.
Sensitive Hygroscopic
Merck 14,5741
crystal system Monoclinic
Space group C2/c
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.8920.5051.3489092.6900.606
Exposure limits ACGIH: TWA 2.5 mg/m3; TWA 0.02 mg/m3; TWA 0.1 mg/m3
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; IDLH 250 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
Stability Stable. Incompatible with strong oxidizing agents. Protect from moisture. Contact with combustible material may lead to fire.
CAS DataBase Reference 7783-53-1(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII VHG84D268X
EPA Substance Registry System Manganese fluoride (MnF3) (7783-53-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS03,GHS06
Signal word  Danger
Hazard statements  H272-H301-H312+H332-H315-H319-H335
Precautionary statements  P210-P280-P301+P310-P302+P352+P312-P304+P340+P312-P305+P351+P338
Hazard Codes  O,Xn
Risk Statements  8-20/21/22-36/37/38
Safety Statements  17-26-36/37/39
RIDADR  UN 3087 5.1/PG 2
WGK Germany  3
RTECS  OP0882600
Hazard Note  Harmful/Oxidising Agent/Hygroscopic
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  2826199090
NFPA 704
0
2 1
OX

MANGANESE(III) FLUORIDE price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 339296 Manganese(III) fluoride 99.9% trace metals basis 7783-53-1 10g $61.8 2024-03-01 Buy
Alfa Aesar 013069 Manganese(III) fluoride, 98% (metals basis) 7783-53-1 10g $44.65 2024-03-01 Buy
Alfa Aesar 013069 Manganese(III) fluoride, 98% (metals basis) 7783-53-1 50g $193 2023-06-20 Buy
Strem Chemicals 93-2542 Manganese(III) fluoride, 98% 7783-53-1 5g $30 2024-03-01 Buy
Strem Chemicals 93-2542 Manganese(III) fluoride, 98% 7783-53-1 25g $120 2024-03-01 Buy
Product number Packaging Price Buy
339296 10g $61.8 Buy
013069 10g $44.65 Buy
013069 50g $193 Buy
93-2542 5g $30 Buy
93-2542 25g $120 Buy

MANGANESE(III) FLUORIDE Chemical Properties,Uses,Production

Description

The manganese fluoride, MnF3, is preferably formed by fluorination of manganese(III) iodide. It is a solid, and although its decomposition pressure is lower than 10.1325kPa (0.1 atmosphere) at 600°C, fluorine is still released when heated. It is a strong fluorinating agent, which acts with sulfur, boron, silicon, carbon, phosphorus trichloride and carbon tetrachloride when heated. It is used to fluoride gaseous hydrocarbons.

Chemical Properties

purple powder or crystals

Uses

It is used as a fluorinating agent, useful for conversion of hydrocarbons into fluorocarbons. It is used in organic synthesis as Lewis acid to prepare a number of organic compounds.

Uses

Fluorinating agent in organic chemistry.

Preparation

Manganese(III) fluoride can also be formed via the reaction of elemental fluorine with a manganese(II) halide at around 250°C.

General Description

Manganese(III) fluoride (also known as manganese trifluoride), MnF3, is a red/purplish solid useful for converting hydrocarbons into fluorocarbons, that is, it is a fluorination agent. It forms a hydrate and numerous derivatives. MnF3 can be produced by reacting a solution of MnF2 in hydrogen fluoride with fluorine.

Hazard

Toxic material.

Synthesis

Dissolve Mn2O3 in hydrofluoric acid and concentrate the solution for crystallization, or reduce potassium permanganate in hydrofluoric acid with low manganese salt to obtain hydrated manganese fluoride MnF3·3H2O. This compound is soluble in cold water and does not decompose, and is stable in hot water in the presence of hydrofluoric acid. Anhydrous manganese trifluoride is slowly decomposed into manganese difluoride, hydrated manganese dioxide and hydrogen fluoride in water.

1313-13-9
7664-39-3
7783-53-1
Synthesis of MANGANESE(III) FLUORIDE from Manganese dioxide and Hydrogen fluoride

MANGANESE(III) FLUORIDE Preparation Products And Raw materials

Global( 76)Suppliers
Supplier Tel Email Country ProdList Advantage
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22963 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9636 58
Wuhan Monad Medicine Tech Co.,LTD
02768782018 18771942761 sales01@whmonad.com CHINA 979 58
Alfa Chemistry
Info@alfa-chemistry.com United States 24072 58
Shaanxi Didu New Materials Co. Ltd
+86-89586680 +86-13289823923 1026@dideu.com China 8670 58
Shanghai Acmec Biochemical Technology Co., Ltd.
+undefined18621343501 product@acmec-e.com China 33338 58
Aladdin Scientific
+1-+1(833)-552-7181 sales@aladdinsci.com United States 57505 58
SHANGHAI KEAN TECHNOLOGY CO., LTD.
+8613817748580 cooperation@kean-chem.com China 40066 58

View Lastest Price from MANGANESE(III) FLUORIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Manganese fluoride(MnF3) pictures 2021-08-31 Manganese fluoride(MnF3)
7783-53-1
US $10.00 / KG 1KG 99.99% 20 tons/month Wuhan Monad Medicine Tech Co.,LTD
MANGANESE(III) FLUORIDE MANGANESE TRIFLUORIDE Manganese fluoride (MnF3) manganesefluoride(mnf3) MnF3 MANGANESE(III) FLUORIDE 99% Manganese(III)fluoride,98%(metalsbasis) Manganese(III)fluoride,98% Manganese(III)fluoride99% Manganic fluoride Manganese(Ⅲ) Fluoride Manganese(III) fluoride 99.9% trace metals basis MANGANESE (III) FLUORIDEMANGANESE (III) FLUORIDEMANGANESE (III) FLUORIDE Manganese fluoride (III) 7783-53-1 3FMn F3Mn metal halide Manganese Salts Metal and Ceramic Science Salts