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Allyltriphenylphosphonium bromide

Allyltriphenylphosphonium bromide structure

CAS No.: 1560-54-9

Chemical Name:: Allyltriphenylphosphonium bromide

Synonyms: TAL;triphenyl(prop-2-en-1-yl)phosphaniuM broMide;NSC 59815;NSC 110609;allyltriphenylphosphonium;allyltriphenyl-phosphoniubromide;Allytriphenylphosphonium bromide;allyl triphenylphosphine bromide;Triphenylallylphosphonium bromide;ALLYLTRIPHENYLPHOSPHONIUM BROMIDE

CBNumber:: CB4381501

Molecular Formula:: C21H20BrP

Molecular Weight:: 383.26

MDL Number:: MFCD00011808

MOL File:: 1560-54-9.mol

MSDS File:: SDS

Last updated:2023-04-23 13:52:06

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Allyltriphenylphosphonium bromide Properties

Melting point	222-225 °C (lit.)
storage temp.	Sealed in dry,Room Temperature
form	Powder
color	White
Water Solubility	decomposes
Sensitive	Hygroscopic
BRN	3579053
InChI	InChI=1S/C21H20P.BrH/c1-2-18-22(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h2-17H,1,18H2;1H/q+1;/p-1
InChIKey	FWYKRJUVEOBFGH-UHFFFAOYSA-M
SMILES	[P+](CC=C)(C1C=CC=CC=1)(C1=CC=CC=C1)C1C=CC=CC=1.[Br-]
CAS DataBase Reference	1560-54-9(CAS DataBase Reference)
FDA UNII	QT9PR2Z47K

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319-H335

Precautionary statements

P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-37/39

WGK Germany

RTECS

TA1843000

HS Code

29310095

Toxicity

mouse,LD50,intravenous,22mg/kg (22mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#01708,

NFPA 704

	0
2		0

Allyltriphenylphosphonium bromide price More Price(24)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	S280178	ALLYL-TRIPHENYL-PHOSPHONIUM, BROMIDE AldrichCPR	1560-54-9	25MG	$29.8	2024-03-01	Buy
Sigma-Aldrich	A36603	Allyltriphenylphosphonium bromide 99%	1560-54-9	100g	$63	2024-03-01	Buy
TCI Chemical	A1007	Allyltriphenylphosphonium Bromide >98.0%(T)	1560-54-9	25g	$126	2024-03-01	Buy
Alfa Aesar	A14490	Allyltriphenylphosphonium bromide, 99%	1560-54-9	50g	$47.65	2024-03-01	Buy
Alfa Aesar	A14490	Allyltriphenylphosphonium bromide, 99%	1560-54-9	250g	$160.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
S280178	25MG	$29.8	Buy
A36603	100g	$63	Buy
A1007	25g	$126	Buy
A14490	50g	$47.65	Buy
A14490	250g	$160.65	Buy

Allyltriphenylphosphonium bromide Chemical Properties,Uses,Production

Chemical Properties

white crystalline powder

Uses

Allyltriphenylphosphonium bromide is used for the first time in the preparation of DES. It has been shown to be part of Phosphonium salts, having antiviral activity against influenza virus A. It can be used in witting olefination of aldehydes for preparation of conjugated dienes.

Preparation

Allyltriphenylphosphonium bromide was synthesized from the reaction of triphenylphosphine and allyl bromide in dry toluene.

Application

Reactant for:
Preparation of a diol and carbamate chemistry library for common functional groups
Regioselective synthesis of alkenes via semihydrogenation and semihydrogenation-oxidation of dienes
Alkene addition of frustrated Lewis pairs
Olefination of N-sulfonyl imines for stereoselective synthesis of vinyl arenes
Wittig olefination of aldehydes for preparation of conjugated dienes
Tandem Michael addition / ylide olefination reactions for the synthesis of highly functionalized cyclohexadienes
Reaction of allyltriphenylphosphonium bromide and Garner's aldehyde in basic media provided β- hydroxy-1,3-dienes.
Methyl 3-(buta-1,3-dienyl)benzoate
1-(Buta-1,3-dienyl)-4-(trifluoromethyl)benzene
1-(Buta-1,3-dienyl)-2-chlorobenzene
1-Bromo-4-(buta-1,3-dienyl)benzene
Buta-1,3-dienylbenzene

Allyltriphenylphosphonium bromide Preparation Products And Raw materials

Raw materials

Triphenylphosphine Allyl bromide Toluene

Preparation Products

1,3-Hexadien-5-yne. (7Z,9E)-dodeca-7,9-dienyl acetate

Allyltriphenylphosphonium bromide Suppliers

Global( 222)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
TCI Europe	320-37350700	sales@tcieurope.eu	Europe	23671	75
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	32957	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29882	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22963	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39894	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49374	58
Shaanxi Dideu Medichem Co. Ltd	18192627656	1012@dideu.com	China	3002	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	10032	58
SIMAGCHEM CORP	+86-13806087780	sale@simagchem.com	China	17365	58

Supplier	Advantage
TCI Europe	75
ATK CHEMICAL COMPANY LIMITED	60
career henan chemical co	58
Hubei xin bonus chemical co. LTD	58
Chongqing Chemdad Co., Ltd	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
Shaanxi Dideu Medichem Co. Ltd	58
Fuxin Pharmaceutical	58
SIMAGCHEM CORP	58

View Lastest Price from Allyltriphenylphosphonium bromide manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2022-10-11	Allyltriphenylphosphonium bromide 1560-54-9	US $0.00-0.00 / kg	1kg	98%	1Ton	Henan Aochuang Chemical Co.,Ltd.
2020-03-16	Allyltriphenylphosphonium bromide 1560-54-9	US $1.00-0.00 / KG	1KG	99%	20 tons	Shaanxi Dideu Medichem Co. Ltd
2019-07-06	Allyltriphenylphosphonium bromide 1560-54-9	US $8.00 / kg	1kg	99%	10TON	Career Henan Chemical Co

Allyltriphenylphosphonium bromide
1560-54-9
US $0.00-0.00 / kg
98%
Henan Aochuang Chemical Co.,Ltd.

Allyltriphenylphosphonium bromide
1560-54-9
US $1.00-0.00 / KG
99%
Shaanxi Dideu Medichem Co. Ltd

Allyltriphenylphosphonium bromide
1560-54-9
US $8.00 / kg
99%
Career Henan Chemical Co

Allyltriphenylphosphonium bromide Spectrum

Allyltriphenylphosphonium bromide(1560-54-9)MS Allyltriphenylphosphonium bromide(1560-54-9)¹HNMR Allyltriphenylphosphonium bromide(1560-54-9)IR1 Allyltriphenylphosphonium bromide(1560-54-9)IR2 Allyltriphenylphosphonium bromide(1560-54-9)Raman

1560-54-9(Allyltriphenylphosphonium bromide)Related Search:

Triphenylphosphine hydrobromide Dimidium bromide TETRAPHENYLPHOSPHINE IMIDE Triphenylphosphine Rocuronium bromide

Tetraphenylphosphonium bromide Triphenylphosphine oxide Tris(triphenylphosphine)rhodiu Tetrakis(triphenylphosphine)palladium Sodium bromate

Vecuronium bromide Tetrapropylammonium bromide Allyl bromide Methyltriphenylphosphonium bromide Ethidium bromide

Allyl triphenylphosphonium chloride ALLYLTRIPHENYLTIN Allyltrimethylsilane

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NSC 59815 Allyltriphenylphosphonium bromide 99% ALLYLTRIPHENYLPHOSPHONIUM BROMIDE allyltriphenyl-phosphoniubromide allyltriphenylphosphonium Allyltriphenylphosphoniumbromide,99% Phosphonium, triphenyl-2-propenyl-, bromide 2-Propenyltriphenylphosphonium bromide Triphenyl(2-propenyl)phosphonium bromide Triphenylallylphosphonium bromide Triphenyl-prop-2-enylphosphanium bromide ALLYLTRIPHENYLPHOSPHONIUM BROMIDE (TAL) Allytriphenylphosphonium bromide ALLYLTRIPHENYLPHOSPHONIUM BROMIDE FOR SY NSC 110609 AllyltriphenylphosphoniumBromide> allyl triphenylphosphine bromide Phosphonium, triphenyl-2-propen-1-yl-, bromide (1:1) triphenyl(prop-2-enyl)phosphanium Phosphonium,triphenyl-2-propen-1-yl-, bromide triphenyl(prop-2-enyl)phosphonium bromide triphenyl(prop-2-en-1-yl)phosphaniuM broMide TAL 1560-54-9 C21H20BrP CH2CHCH2C6H53PBr H2CCHCH2PC6H53Br C21H20P Wittig Reaction Wittig & Horner-Emmons Reaction Phosphonium Compounds C-C Bond Formation Synthetic Reagents Wittig Reagents Olefination organophosphorus compound Pharmaceutical Intermediates Phosphonium Compounds Synthetic Organic Chemistry Wittig & Horner-Emmons Reaction Wittig Reaction C-C Bond Formation Olefination Wittig Reagents