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3-Bromoanisole

3-Bromoanisole structure

CAS No.: 2398-37-0

Chemical Name:: 3-Bromoanisole

Synonyms: 1-BROMO-3-METHOXYBENZENE;META BROMO ANISOLE;M-BROMOANISOLE;3-Methoxybromobenzene;3-Methoxyphenyl bromide;M-Bro;NSC 82293;3-BROMOANISOLE;3-BROMO ANISOL;5-bromoanisole

CBNumber:: CB4384971

Molecular Formula:: C7H7BrO

Molecular Weight:: 187.03

MDL Number:: MFCD00000081

MOL File:: 2398-37-0.mol

MSDS File:: SDS

Last updated:2025-01-27 09:38:02

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3-Bromoanisole Properties

Melting point	2 °C
Boiling point	210-211 °C(lit.)
Density	1.490 g/mL at 20 °C
vapor pressure	38.39Pa at 25℃
refractive index	n20/D 1.563(lit.)
Flash point	200 °F
storage temp.	Sealed in dry,Room Temperature
solubility	DMSO (Sparingly), Methanol (Slightly)
form	Liquid
Specific Gravity	1.477
color	Clear colorless to slightly yellow-brown
PH	5.5 (H2O, 20℃)
Water Solubility	Miscible in methanol, benzene, hexane, toluene and dichloromethane. Practically insoluble in water.
BRN	1524687
Stability	Stable. Combustible. Incompatible with strong oxidising agents, strong acids reducing agents.
InChIKey	PLDWAJLZAAHOGG-UHFFFAOYSA-N
LogP	3.03
CAS DataBase Reference	2398-37-0(CAS DataBase Reference)
FDA UNII	7ZO6TY38WY
NIST Chemistry Reference	Benzene, 1-bromo-3-methoxy-(2398-37-0)
EPA Substance Registry System	m-Bromoanisole (2398-37-0)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H412

Precautionary statements

P273

Hazard Codes

Safety Statements

23-24/25

WGK Germany

Hazard Note

Irritant

TSCA

HS Code

29093038

NFPA 704

	1
0		0

3-Bromoanisole price More Price(32)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	B56498	3-Bromoanisole ≥98%	2398-37-0	25g	$54.8	2024-03-01	Buy
Sigma-Aldrich	B56498	3-Bromoanisole ≥98%	2398-37-0	100g	$130	2024-03-01	Buy
TCI Chemical	B0545	3-Bromoanisole >98.0%(GC)	2398-37-0	25g	$33	2024-03-01	Buy
TCI Chemical	B0545	3-Bromoanisole >98.0%(GC)	2398-37-0	250g	$100	2024-03-01	Buy
Alfa Aesar	A15625	3-Bromoanisole, 98+%	2398-37-0	25g	$37.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
B56498	25g	$54.8	Buy
B56498	100g	$130	Buy
B0545	25g	$33	Buy
B0545	250g	$100	Buy
A15625	25g	$37.65	Buy

3-Bromoanisole Chemical Properties,Uses,Production

Chemical Properties

3-Bromoanisole, also known as m-Bromoanisole, is a clear colorless to pale yellow oily liquid. The boiling point is 210-211°C (100kPa), 105°C (2.13kPa), the relative density is 1.477, the refractive index is 1.5635, and the flash point is 93°C. It is soluble in alcohol, ether, benzene, and carbon disulfide, but insoluble in water. It is commonly used as a raw material for organic synthesis.

Uses

3-Bromoanisole used in chemical reaction as intermediates to obtain target materials such as dyes, pharmaceuticals, perfumes, photoinitiators and agrochemicals.

Preparation

3-Bromoanisole is synthesized through a reaction between m-bromophenol and dimethyl sulfate. The synthesis method involves the following steps:
Dissolve m-bromophenol in a sodium hydroxide solution.
Slowly add dimethyl sulfate dropwise to the solution while stirring.
Heat the mixture and allow it to react for 1 hour.
Cool the reaction mixture to separate the colorless oil formed.
Extract the water layer with ether.
Dry the ether extract and then distill it to recover the ether.
Distill the residue obtained after recovering the ether, along with the colorless oil, under reduced pressure.
This distillation process results in the production of m-bromoanisole as the final product.
The overall yield of m-bromoanisole achieved through this process is 90%.

References

Application of Anisole, 2-Bromoanisole and 3-Bromoanisole as Overcharge Protection Additives in Lithium-Ion Batteries DOI:10.6023/A12110964
S. Ramalingam; S. Periandy. Spectroscopic investigation, computed IR intensity, Raman activity and vibrational frequency analysis on 3-bromoanisole using HF and DFT (LSDA/MPW1PW91) calculations. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2011, 78 (2), 835-843. DOI:10.1016/j.saa.2010.12.043
Bobby Glover; Kimberly A. Harvey; Bing Liu; Matthew J. Sharp; and Maria F. Tymoschenko. Regioselective Palladium-Catalyzed Arylation of 3-Carboalkoxy Furan and Thiophene. Org. Lett. 2003, 5 (3), 301-304. DOI:10.1021/ol027266q

3-Bromoanisole Preparation Products And Raw materials

Raw materials

Sodium bromate Benzene Hydrogen Government regulation Methanol

Sulfuric acid 3-Bromophenol

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Preparation Products

Tramadol hydrochloride 3-Methoxyphenylboronic acid 2-Chloro-5-methoxyphenylboronic acid Tramadol ETHYL 3-METHOXYPHENYLACETATE

2-(3-METHOXYPHENYL)CYCLOHEXANONE 3-Methoxybenzoylacetonitrile 3-PHENOXYPHENOL Bromobenzene 3'-METHOXY-2,2,2-TRIFLUOROACETOPHENONE

3-(3-METHOXY-PHENYL)-THIOPHENE 1-(3-METHOXYPHENYL)CYCLOHEXANOL

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3-Bromoanisole Suppliers

Global( 681)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Beijing Wisdom Chemicals Co., Ltd.	+8613701363759	market@wisdomchem.com	China	254	58
Hebei Weibang Biotechnology Co., Ltd	+8615531157085	abby@weibangbio.com	China	8804	58
Hebei Mujin Biotechnology Co.,Ltd	+86 13288715578 +8613288715578	sales@hbmojin.com	China	12827	58
Hebei Chuanghai Biotechnology Co,.LTD	+86-13131129325	sales1@chuanghaibio.com	China	5887	58
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD	+8615350851019	admin@86-ss.com	China	1001	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29792	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21632	55
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1803	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29871	58
NINGBO INNO PHARMCHEM CO., LTD.	13867897135	sales@nbinno.com	CHINA	923	58

Supplier	Advantage
Beijing Wisdom Chemicals Co., Ltd.	58
Hebei Weibang Biotechnology Co., Ltd	58
Hebei Mujin Biotechnology Co.,Ltd	58
Hebei Chuanghai Biotechnology Co,.LTD	58
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD	58
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55
Shanghai Time Chemicals CO., Ltd.	55
career henan chemical co	58
NINGBO INNO PHARMCHEM CO., LTD.	58

View Lastest Price from 3-Bromoanisole manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-02-18	1-Bromo-3-Methoxybenzene 3-Bromoanisole 2398-37-0	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mujin Biotechnology Co.,Ltd
2025-02-14	3-Bromoanisole 2398-37-0	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mujin Biotechnology Co.,Ltd
2025-02-13	3-Bromoanisole 2398-37-0	US $99.00-66.00 / kg	0.00100000kg	99%	5000	HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD

1-Bromo-3-Methoxybenzene 3-Bromoanisole
2398-37-0
US $0.00 / KG
99%
Hebei Mujin Biotechnology Co.,Ltd

3-Bromoanisole
2398-37-0
US $0.00 / KG
99%
Hebei Mujin Biotechnology Co.,Ltd

3-Bromoanisole
2398-37-0
US $99.00-66.00 / kg
99%
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD

3-Bromoanisole Spectrum

3-Bromoanisole(2398-37-0)MS 3-Bromoanisole(2398-37-0)¹HNMR 3-Bromoanisole(2398-37-0)¹³CNMR 3-Bromoanisole(2398-37-0)IR1 3-Bromoanisole(2398-37-0)IR2 3-Bromoanisole(2398-37-0)Raman

2398-37-0(3-Bromoanisole)Related Search:

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5-bromoanisole 3-BROMO ANISOL 3-BROMOANISOLE TIMTEC-BB SBB007886 BROMOANISOLE(3-) 3-Methoxy-1-bromobenzene Anisole, m-bromo- m-Anisyl bromide m-Bromomethoxybenzene m-Bromophenyl methyl ether 1-bromo-3-methoxy-benzen 1-Bromo-3-methoxybenzene, 3-Bromophenyl methyl ether BroMobenzene between Methyl ether M-BROMO ANISOLE (3-BROMO ANISOLE) 3-Bromoanisole≥ 99.5% (GC) m-BROMOANISOLE pure 3-Bromoanisole,1-Bromo-3-methoxybenzene m-Bromoanisole 1g [2398-37-0] 3-BromoanisoleDISC 05/08/02 m-bromoanisole(MBA) 3-BROMOANISOLE, 98+% 3-Bromoanisole99% 3-BROMO ANISOLE FOR SYNTHESIS NSC 82293 Benzene, 1-bromo-3-methoxy- m-Bromophenyl methyl ethe m-Bromophenylmethylether m-Methoxybromobenzene m-Methoxyphenyl bromide m-Bromoanisoles 3-BroMoanisole, 99+% 100ML 3-BroMoanisole, 99+% 25ML M-Bro m-bromonisole(3-bromoanisole) M-Bromoanisole (3-Bromoanisole) 99.5% 3-Bromoanisole > 3-Bromoanisole ISO 9001：2015 REACH Meta Bromo Anisole (3-Bromo Anisole) Meta Bromo Anisole (MBA) 3-Bromoanisole pure, 98% M-BROMOANISOLE META BROMO ANISOLE 1-BROMO-3-METHOXYBENZENE 3-Methoxybromobenzene 1-Bromo-3-Methoxybenzene 3-Bromoanisole 3-Methoxyphenyl bromide M-bromophenyl ether 3-Bromoanisole 98% For Synthesis 3-Bromoanisol in isopropanol Meta bromobenzyl ether Phloroglucinol Impurity 242 2398-37-0 2938-37-0 2398-38-0 ARYL HALIDE Ethers Organic Building Blocks Oxygen Compounds