ChemicalBook >> CAS DataBase List >>CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
- CAS No.
- 92390-26-6
- Chemical Name:
- CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
- Synonyms
- Cp*RuCl(cod);Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II);Chloro(1,5-cyclooctadiene)(pentaMethylcyclopentadienyl)rutheniuM;1,5-Cyclooctadiene, ruthenium complex;CHLORO(PENTAMETHYLCYCLOPENTADIENYL)(CYC&;Chloro(1,5-cyclooctadiene)(pentamethylcyclopent...;Chloro(pentaMethylcyclopentadienyl)(cyclooctadiene)rutheniuM;Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium;(1,5-cyclooctadiene) (pentamethylcyclopentadiene) rubidium chloride;Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium (Ⅱ)
- CBNumber:
- CB4405539
- Molecular Formula:
- C18H27ClRu5*
- Molecular Weight:
- 379.93
- MDL Number:
- MFCD07369035
- MOL File:
- 92390-26-6.mol
Last updated:2023-05-11 17:26:00
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS02 |
---|---|
Signal word | Danger |
Hazard statements | H261 |
Precautionary statements | P231+P232-P422 |
Hazard Codes | F |
Risk Statements | 20/21/22-14/15 |
Safety Statements | 22-36/37/39-43 |
RIDADR | UN 3395 |
WGK Germany | 3 |
TSCA | No |
HazardClass | 4.3 |
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) price More Price(30)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 667234 | Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) | 92390-26-6 | 250mg | $131 | 2024-03-01 | Buy |
Sigma-Aldrich | 667234 | Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) | 92390-26-6 | 1g | $350 | 2024-03-01 | Buy |
Alfa Aesar | 046803 | Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II) | 92390-26-6 | 250mg | $113.65 | 2024-03-01 | Buy |
Alfa Aesar | 046803 | Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II) | 92390-26-6 | 1g | $394 | 2024-03-01 | Buy |
Strem Chemicals | 44-0113 | Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II), 98% | 92390-26-6 | 250mg | $121 | 2024-03-01 | Buy |
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Chemical Properties,Uses,Production
Reactions
- Catalyst for regio and stereo-specific ring opening via N-O bond cleavage.
- Catalyst for transformation of 1,6-enynes and diazoalkanes into alkenylbicyclo[3.1.0]hexane derivatives.
- Catalyst for ring closing enyne metathesis.
- Catalyst for [2 + 2 + 2] cocyclization of diene-yne, and cyclodimerization of allenynes.
- Catalyst for hydrovinylation of ynamides with ethylene.
- Catalyst for C–H insertion reactions of carbenes.
![Reactions of 92390-26-6](/NewsImg/2018-02-09/20182915224240647.jpg)
Uses
Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.
It can be used:
- To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.
- To catalyze C-C coupling of norbornenes and norbornadiene with alkynes?to form [2 + 2] cycloadducts.
- In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.
- To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.
- To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 129)Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 16914 | 58 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32760 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29894 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49391 | 58 |
Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
Neostar United (Changzhou) Industrial Co., Ltd. | +86-519-519-85557386 | marketing1@neostarunited.com | China | 11006 | 58 |
Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 13214 | 58 |
Shanghai Daeyeon Chemicals Co., Ltd | 021-64478606 +8615900664856 | daeyeon001@vip.163.com | China | 2062 | 58 |
Hubei Ipure Biology Co., Ltd | +8613367258412 | ada@ipurechemical.com | China | 10326 | 58 |
View Lastest Price from CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
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2020-11-16 | CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
92390-26-6
|
US $20.00 / KG | 1KG | 99% | 10000KG | Longyan Tianhua Biological Technology Co., Ltd | |
![]() |
2019-07-06 | CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
92390-26-6
|
US $1.00 / KG | 1KG | 99% | 200kg | Career Henan Chemical Co |
-
- CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
92390-26-6
- US $20.00 / KG
- 99%
- Longyan Tianhua Biological Technology Co., Ltd
-
- CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
92390-26-6
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
92390-26-6(CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II))Related Search:
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CHLORO(PENTAMETHYLCYCLOPENTADIENYL)(CYC&
CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)
(1,5-cyclooctadiene) (pentamethylcyclopentadiene) rubidium chloride
Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium(Ⅱ)
Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium (Ⅱ)
Cp*RuCl(cod)
Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II)
Chloro(1,5-cyclooctadiene)(pentaMethylcyclopentadienyl)rutheniuM
Ruthenium, chloro[(1,?2,?5,?6-?η)?-?1,?5-?cyclooctadiene]?[(1,?2,?3,?4,?5-?η)?-?1,?2,?3,?4,?5-?pentamethyl-?2,?4-?cyclopentadien-?1-?yl]?-
chloro-[(1E,5Z)-cycloocta-1,5-dien-1-yl]ruthenium 1,2,3,4,5-pentamethylcyclopenta-1,3-diene
Chloro(pentamethylcyclopentadienyl)(1,5-cyclooctadiene)ruthenium(II)
92390-26-6
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