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(R)-VAPOL

CAS No.
147702-16-7
Chemical Name:
(R)-VAPOL
Synonyms
(S)-VAPOL;(R)-VAPOL;(R)-VAPOL 97%;(R)-VAPOL,99%e.e.;(S)-2,2'-DIPHENYL-(4-BIPHENANTHROL);(R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL);(R) -2,2'--diphenyl-3,3 '- (4-phenanthrenol;(3R)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol;(3R)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol;(3R)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol
CBNumber:
CB4450751
Molecular Formula:
C40H26O2
Molecular Weight:
538.63
MDL Number:
MFCD08459339
MOL File:
147702-16-7.mol
MSDS File:
SDS
Last updated:2023-07-14 17:45:36

(R)-VAPOL Properties

Melting point 225-229 °C
Boiling point 712.2±60.0 °C(Predicted)
alpha -123.4° (c 1.0, THF)
Density 1.286±0.06 g/cm3(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka 8.37±0.30(Predicted)
form Powder
color white to pale yellow
optical activity [α]20/D -144°, c = 1 in chloroform

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H315-H318-H335-H351
Precautionary statements  P201-P202-P280-P302+P352-P305+P351+P338-P308+P313
Hazard Codes  Xn
Risk Statements  37/38-40-41
Safety Statements  26-36/37/39
WGK Germany  3

(R)-VAPOL price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 675210 (R)-VAPOL 97% 147702-16-7 100mg $55.6 2024-03-01 Buy
Sigma-Aldrich 675210 (R)-VAPOL 97% 147702-16-7 500mg $264.8 2024-03-01 Buy
Strem Chemicals 08-1704 (3R)-(-)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (R)-VAPOL 147702-16-7 100mg $255 2024-03-01 Buy
Strem Chemicals 08-1704 (3R)-(-)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol dichloromethane adduct, min. 98% (R)-VAPOL 147702-16-7 500mg $1021 2024-03-01 Buy
American Custom Chemicals Corporation HCH0009280 (3R)-(-)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT 95.00% 147702-16-7 500MG $1109.06 2021-12-16 Buy
Product number Packaging Price Buy
675210 100mg $55.6 Buy
675210 500mg $264.8 Buy
08-1704 100mg $255 Buy
08-1704 500mg $1021 Buy
HCH0009280 500MG $1109.06 Buy

(R)-VAPOL Chemical Properties,Uses,Production

Reaction

  1. Chiral ligand used in catalytic asymmetric aziridination.
  2. Chiral ligand used in catalytic asymmetric imino aldol reaction.
  3. Chiral ligand used in catalytic asymmetric Petasis reaction. 
Reactions of 147702-16-7

Uses

VAPOL has proven to be an excellent ligand in catalytic asymmetric Diels-Alder, imine aldol, and aziridination reactions.

(R)-VAPOL Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-VAPOL Suppliers

Global( 27)Suppliers
Supplier Tel Email Country ProdList Advantage
Aladdin Scientific
+1-+1(833)-552-7181 sales@aladdinsci.com United States 57505 58
Shanghai Likang New Materials Co., Limited
+86-16631818819 +86-17736933208 3684455296@qq.com China 9300 58
Guangzhou CATO Research Chemicals Inc.
+86-020-81960175-617 +8615602392859 Intermediate@cato-chem.com China 8056 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 021-61259108 18621169109 market03@meryer.com China 40228 62
Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865 han_yajun@dctc.daicel.com China 7191 65
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51456 80
Shanghai Chiral bio-compound co., Ltd. 021-5068 3667/17749785980/1029026415; 17749785980 1029026415@qq.com China 3013 58
Zhengzhou Huiju Chemical Co., Ltd. 0371-55900031 18137872243 2853979815@qq.com China 10011 55
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2603 58
(R)-VAPOL 97% (R)-VAPOL,99%e.e. (S)-2,2'-DIPHENYL-(4-BIPHENANTHROL) (R)-VAPOL (S)-VAPOL (R)-2,2'-DIPHENYL-3,3'-(4-BIPHENANTHROL) (3R)-(-)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT (3S)-(+)-2,2'-DIPHENYL-[3,3'-BIPHENANTHRENE]-4,4'-DIOL DICHLOROMETHANE ADDUCT (3R)-(-)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-dioldichloromethaneadduct,min.98%(R)-VAPOL (3R)-(-)-2,2''-DIPHENYL-[3,3''-BIPHENANTHRENE]-4,4''-DIOL DICHLOROMETHANE ADDUCT (R)-VAPOL (R) -2,2'--diphenyl-3,3 '- (4-phenanthrenol (3R)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol 3,3'-Biphenanthrene]-4,4'-diol, 2,2'-diphenyl-, (3R)- (3R)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol (3R)-2,2'-Diphenyl-[3,3'-biphenanthrene]-4,4'-diol (3R)-2,2'- diphenyl [3,3'- phenanthrene ]-4,4'- diol 147702-16-7 C40H26O212CH2Cl2 BINOL Series Chiral Oxygen