ChemicalBook >> CAS DataBase List >>ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

CAS No.
12245-39-5
Chemical Name:
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
Synonyms
NSC 240030;rh(acac)(cod);Acetylacetonato(1,5-;(ACETYLACETONATO)(1,5-CYCLOOCTADIENE)RH&;acetylacetonate-1,5-cyclooctadienerhodium;ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I);Acetylacetonato(cycloocta-1,5-diene)rhodium(I);(1,5-cyclooctadiene)(2,4-pentanedionato)rhodium;(1,5-cyclooctadiene)(2,4-pentanedionato)-rhodiu;RHODIUM (1,5-CYCLOOCTADIENE)-2,4-PENTANEDIONATE
CBNumber:
CB4469944
Molecular Formula:
C13H19O2Rh
Molecular Weight:
310.19
MDL Number:
MFCD00075046
MOL File:
12245-39-5.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Properties

Melting point 138-140 °C(lit.)
storage temp. Inert atmosphere,2-8°C
form Crystals
color Yellow to orange
Sensitive Air Sensitive
Hydrolytic Sensitivity 8: reacts rapidly with moisture, water, protic solvents
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChIKey WDIAJTWVVLHUJU-SUESZSCISA-N

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
RTECS  VI9292000
TSCA  No
HS Code  28439000
NFPA 704
3
2 1

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) price More Price(29)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 683108 (Acetylacetonato)(1,5-cyclooctadiene)rhodium(I) 99% 12245-39-5 2g $977 2024-03-01 Buy
Sigma-Aldrich 335029 (Acetylacetonato)(1,5-cyclooctadiene)rhodium(I) 99% 12245-39-5 100mg $125 2023-06-20 Buy
Sigma-Aldrich 8.24420 Acetylacetonato(1,5-cyclooctadiene)rhodium(I) for synthesis 12245-39-5 500mg $91.2 2023-01-07 Buy
Sigma-Aldrich 8.24420 Acetylacetonato(1,5-cyclooctadiene)rhodium(I) for synthesis 12245-39-5 100mg $139 2023-01-07 Buy
Alfa Aesar H26083 (1,5-Cyclooctadiene)rhodium(I) 2,4-pentanedionate 12245-39-5 250mg $198 2023-06-20 Buy
Product number Packaging Price Buy
683108 2g $977 Buy
335029 100mg $125 Buy
8.24420 500mg $91.2 Buy
8.24420 100mg $139 Buy
H26083 250mg $198 Buy

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Chemical Properties,Uses,Production

Reactions

  1. Precursor for asymmetric hydrogenation reactions.
  2. Rh-catalyzed carbozincation of ynamides. 
Reactions of 12245-39-5

Chemical Properties

Orange crystal

Uses

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

General Description

Atomic number of base material: 45 Rhodium

Safety Profile

Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Rh

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 163)Suppliers
Supplier Tel Email Country ProdList Advantage
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32957 60
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22963 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49374 58
career henan chemical co
+86-0371-86658258 +8613203830695 factory@coreychem.com China 29811 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9636 58
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17365 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34553 58
Xi'an MC Biotech, Co., Ltd.
029-89275612 +8618991951683 mcbio_sales@163.com China 2251 58
Alfa Chemistry
info@alfa-chemistry.com United States 2344 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com China 52849 58

View Lastest Price from ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) pictures 2021-07-02 ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
12245-39-5
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) pictures 2020-01-09 ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
12245-39-5
US $1.00 / KG 1KG 99% 100KG Career Henan Chemical Co
(1,5-Cyclooctadiene)rhodium(I) 2,4-pentanedionate (1,5-cyclooctadiene)(2,4-pentanedionato)rhodium(I) Acetylacetonato(1,5-cyclooctadiene)rhodium(I),97% Acetylacetonato(1,5- (Acetylacetonato)(1,5-cyclooctadiene)rhodium(Ⅰ) RHODIUM (1,5-CYCLOOCTADIENE)-2,4-PENTANEDIONATE ((1,2,5,6-eta)-1,5-cyclooctadiene)(2,4-pentanedionato-o,o’)-rhodiu (1,5-cyclooctadiene)(2,4-pentanedionato)-rhodiu (1,5-cyclooctadiene)(2,4-pentanedionato)rhodium acetylacetonate-1,5-cyclooctadienerhodium (ACETYLACETONATO)(1,5-CYCLOOCTADIENE)RH& Acetylacetonato(1,5-cyclooctadiene)rhodium(I),98% rh(acac)(cod) ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) (ACETYLACETONATO)(ETA-CYCLOOCTA-1,5-DIENE)RHODIUM (I) Acetylacetonato(cycloocta-1,5-diene)rhodium(I) NSC 240030 Bis(actetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 12245-39-5 RhCODacac RhC8H12C5H7O2 C13H19O2Rh C13H18O2Rh Catalysis and Inorganic Chemistry organometallic complex Rh