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ChemicalBook >> CAS DataBase List >>N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Structure
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ structure
CAS No.
376355-58-7
Chemical Name:
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
Synonyms
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][;Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite;1,1'-Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite;N,N-bis[(1R)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine;N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;Dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, N,N-bis[(1S)-1-phenylethyl]-;N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine >=99.0%;BIPOL-A1(S), (S,S)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(S)-1-phenylethyl]phosphoramidite
CBNumber:
CB4497141
Molecular Formula:
C28H26NO2P
Molecular Weight:
439.49
MDL Number:
MFCD08277033
MOL File:
376355-58-7.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06
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N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Properties

Melting point 99-102 °C
Boiling point 578.4±53.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka -0.31±0.20(Predicted)
form Powder
color white
optical activity [α]/D -250±10°, c = 1 in toluene
Sensitive moisture sensitive

SAFETY

Risk and Safety Statements

WGK Germany  3

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 07033 N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine ≥99.0% 376355-58-7 100MG $94.3 2022-05-15 Buy
Strem Chemicals 15-0519 N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine 376355-58-7 100mg $117 2024-03-01 Buy
Strem Chemicals 15-0519 N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine 376355-58-7 500mg $470 2024-03-01 Buy
American Custom Chemicals Corporation CCH0004775 N,N-BIS-((S)-1-PHENYLETHYL)DIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN-6-AMINE 95.00% 376355-58-7 100MG $730.68 2021-12-16 Buy
American Custom Chemicals Corporation CCH0004775 N,N-BIS-((S)-1-PHENYLETHYL)DIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN-6-AMINE 95.00% 376355-58-7 1G $1379.7 2021-12-16 Buy
Product number Packaging Price Buy
07033 100MG $94.3 Buy
15-0519 100mg $117 Buy
15-0519 500mg $470 Buy
CCH0004775 100MG $730.68 Buy
CCH0004775 1G $1379.7 Buy

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Chemical Properties,Uses,Production

Reaction

  1. Ligand for the copper catalyzed, highly regioselective substitution reactions of a wide variety of aromatic substituted allylic halides to form branched chiral products from diverse Grignard reagents.
  2. Ligand for the copper catalyzed, highly enantioselective conjugate addition of diethylzinc to eneones and nitro olefins.
  3. Ligand for the nickel catalyzed, highly enantioselective hydrovinylation of alkenes.
  4. Ligand for the rhodium catalyzed, highly enantioselective hydroformylation of vinylarenes.
  5. Ligand for gold catalyzed asymmetric Intramolecular hydroamination of allenes
Reactions of 376355-58-7_1
Reactions of 376355-58-7_2

Uses

N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:

  • In the iridium catalyzed allylic arylation.
  • To prepare a copper complex (Cu2X2L3), which is used to detect the transmetalation intermediates in asymmetric addition reactions using ZnEt2.

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Preparation Products And Raw materials

Raw materials

Preparation Products

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Suppliers

Global( 32)Suppliers
Supplier Tel Email Country ProdList Advantage
CR Corporation Lomited 		fred.wen@crcorporation.cn CHINA 12069 58
Shaoxin Catsyn Co., Ltd. 		+undefined-0575-82040869 +86-0575-82040869; sales@catsyn.com China 6116 58
Aladdin Scientific 		+1-+1(833)-552-7181 sales@aladdinsci.com United States 57511 58
Amadis Chemical Company Limited 		571-89925085 sales@amadischem.com China 131980 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Tianjin Derchemist Science & Technology Co., Ltd. 22-58627059 13920586291 zdcomcon@126.com China 3166 50
Shanghai Incat Chemtech Co.,Ltd. 021-57603038 13601791340 307593986@qq.com China 475 58
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 41438 60
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Shanghai Chiral bio-compound co., Ltd. 021-5068 3667/17749785980/1029026415; 17749785980 1029026415@qq.com China 2884 58
Supplier Advantage
CR Corporation Lomited 		58
Shaoxin Catsyn Co., Ltd. 		58
Aladdin Scientific 		58
Amadis Chemical Company Limited 		58
J & K SCIENTIFIC LTD. 76
Tianjin Derchemist Science & Technology Co., Ltd. 50
Shanghai Incat Chemtech Co.,Ltd. 58
Bide Pharmatech Ltd. 60
Sigma-Aldrich 80
Shanghai Chiral bio-compound co., Ltd. 58

376355-58-7(N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][)Related Search:

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
N,N-bis[(1R)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ BIPOL-A1(S), (S,S)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(S)-1-phenylethyl]phosphoramidite N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine 1,1'-Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite Dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, N,N-bis[(1S)-1-phenylethyl]- N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine >=99.0% 376355-58-7 phosphine-amine ligand Chiral Phosphine CPN