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Hydrogenated bisphenol A (HBPA)

CAS No.
80-04-6
Chemical Name:
Hydrogenated bisphenol A (HBPA)
Synonyms
HYDROGENATED BISPHENOL A;2,2-BIS(4-HYDROXYCYCLOHEXYL)PROPANE;H-BPA;Maruzen H-BPA;PERHYDROBISPHENOL A;BISPHENOL A HYDROGENATED;4'-Isopropylidenedicyclohexanol;HYDROGENATED BISPHENOL A (HBPA);4,4'-ISOPROPYLIDENEDICYCLOHEXANOL;4,4'-Isopropylidinedicyclohexanol
CBNumber:
CB4669962
Molecular Formula:
C15H28O2
Molecular Weight:
240.38
MDL Number:
MFCD00019334
MOL File:
80-04-6.mol
MSDS File:
SDS
Last updated:2024-12-18 14:08:52

Hydrogenated bisphenol A (HBPA) Properties

Melting point 187 °C(Solv: benzene (71-43-2); ethanol (64-17-5))
Boiling point 230-234 °C14 mm Hg(lit.)
Density 1.048±0.06 g/cm3(Predicted)
vapor pressure 0.001Pa at 25℃
Flash point >230 °F
solubility Insoluble in water
form powder to lump
pka 15.01±0.40(Predicted)
color White to Almost white
Water Solubility 192mg/L at 20℃
LogP 2.5 at 25℃
CAS DataBase Reference 80-04-6(CAS DataBase Reference)
FDA UNII NXZ4H12R1Z
EPA Substance Registry System Cyclohexanol, 4,4'-(1-methylethylidene)bis- (80-04-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319
Precautionary statements  P305+P351+P338
Hazard Codes  Xi
Risk Statements  36
Safety Statements  26
WGK Germany  3
HS Code  2906.19.5000
NFPA 704
1
2 0

Hydrogenated bisphenol A (HBPA) price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 416517 4,4′-Isopropylidenedicyclohexanol, mixture of isomers 90% 80-04-6 250g $18.88 2024-03-01 Buy
TCI Chemical B0928 2,2-Bis(4-hydroxycyclohexyl)propane (mixture of isomers) >93.0%(GC) 80-04-6 25g $28 2024-03-01 Buy
TCI Chemical B0928 2,2-Bis(4-hydroxycyclohexyl)propane (mixture of isomers) >93.0%(GC) 80-04-6 500g $72 2024-03-01 Buy
TRC P835313 4,4''-(Propane-2,2-diyl)dicyclohexanol 80-04-6 500mg $75 2021-12-16 Buy
Usbiological 279787 Hydrogenated bisphenol A 80-04-6 25g $305 2021-12-16 Buy
Product number Packaging Price Buy
416517 250g $18.88 Buy
B0928 25g $28 Buy
B0928 500g $72 Buy
P835313 500mg $75 Buy
279787 25g $305 Buy

Hydrogenated bisphenol A (HBPA) Chemical Properties,Uses,Production

Description

2,2-Bis(4-hydroxycyclohexyl)propane, also known as 4,4'-Isopropylidenedicyclohexanol, is a crystalline, colorless, and odorless compound. The conformation of the cyclohexane rings gives rise to cis-cis, cis-trans and trans-trans isomers. The industrial product is a mixture of these stereoisomers. The physical properties depend on the relative amounts of the isomers present. The trans-trans compound has the lowest energy and is formed from the other isomers at higher temperature. It has the lowest solubility in solvents such as methanol, butanol, and acetone and has the highest melting point of these isomers.

Uses

4,4'-isopropylidenedicyclohexanol is unsaturated polyester resin, epoxy resin raw materials, especially as glass, steel, artificial marble bathtub, plating tank and other components, and has a water resistance, chemical resistance, thermal stability and light stability.

Production Methods

4,4'-Isopropylidenedicyclohexanol is produced by hydrogenation of bisphenol A, 2,2-bis(4-hydroxyphenyl)propane, an industrially important compound made from acetone and phenol (Phenol Derivatives). Bisphenol A is hydrogenated at about 10-30 MPa and at 150-250 ℃ on a nickel, cobalt, or ruthenium catalyst.

Flammability and Explosibility

Non flammable

Structure and conformation

4,4' -Isopropylidenedicyclohexanol (HBPA), hydrogenated from bisphenol A (BPA), is a promising and revealing alicyclic candidate to offer diamine or dianhydride monomers. Due to the different spatial conformations of hydroxyls, HBPA has three isomers, including H' BPA, H''BPA, and H'''BPA, and their contents are 47%, 45%, and 8%, respectively. However, few reports about nonplanar HBPA-based polyimides were found, probably because of the difficulty separating HBPA isomers[1-2].
4,4'-Isopropylidenedicyclohexanol

References

[1] Z. Hou. “Soluble copolyimides containing 4,4′-isopropylidenedicyclohexanol (HBPA) isomer units: Synthesis, characterization, thermal, mechanical, and optical properties.” High Performance Polymers 32 1 (2019): 406–417.
[2] Zhiming Mi. “Transparent and soluble polyimide films containing 4,4′-isopropylidenedicyclohexanol (Cis-HBPA) units: Preparation, characterization, thermal, mechanical, and dielectric properties.” Journal of Polymer Science Part A: Polymer Chemistry 56 18 (2018): 2115–2128.

Hydrogenated bisphenol A (HBPA) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 302)Suppliers
Supplier Tel Email Country ProdList Advantage
SHANGHAI T&W PHARMACEUTICAL CO., LTD.
+86-021-61551413 +8618813727289 contact@trustwe.com China 5738 58
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+8615531157085 abby@weibangbio.com China 8810 58
Puyang Huicheng Electronic Materials Co., Ltd.
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Hebei Mojin Biotechnology Co., Ltd
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+86-28792436-807 anna.lee66@139.com China 3 58
Hebei Zhuanglai Chemical Trading Co.,Ltd
+8613343047651 admin@zlchemi.com China 3002 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806 sales@capot.com China 29791 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18751 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55

View Lastest Price from Hydrogenated bisphenol A (HBPA) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4,4'-Isopropylidenedicyclohexanol pictures 2024-12-18 4,4'-Isopropylidenedicyclohexanol
80-04-6
US $70.00 / kg 1kg 99 5000 Hebei Zhuanglai Chemical Trading Co.,Ltd
Hydrogenated bisphenol A (HBPA) pictures 2024-12-18 Hydrogenated bisphenol A (HBPA)
80-40-6
US $99.00-35.00 / kg 1kg 99% 20ton Hebei Zhuanglai Chemical Trading Co.,Ltd
4,4'-Isopropylidenedicyclohexanol pictures 2024-11-28 4,4'-Isopropylidenedicyclohexanol
80-04-6
US $10.00 / KG 1KG 99% 10 mt Hebei Weibang Biotechnology Co., Ltd
BISPHENOL A HYDROGENATED 4,4'-ISOPROPYLIDENEDICYCLOHEXANOL 2,2-BIS(4-HYDROXYCYCLOHEXYL)PROPANONE P,P'-DIHYDROXY-2,2-DICYCLOHEXYLPROPANE PERHYDROBISPHENOL A 4,4’-(1-methylethylidene)bis-cyclohexano 4,4’-(1-methylethylidene)bis-Cyclohexanol 4,4’-isopropylidenedicyclohexanol,mixtureo 2,2-Bis(hydroxycyclohexyl)propanone 4,4-Isopropylidenedicyclohexanol,mixture of isomers 4,4'-ISOPROPYLIDENEDICYCLOHEXANOL, 90%,MIXTURE OF ISOMERS HYDROGENATED BISPHENOL A, 4,4'-ISOPROPYLIDENEDICYCLOHEXANOL 4,4'-Isopropylidinedicyclohexanol Cyclohexanol, 4,4-(1-methylethylidene)bis- 2,2-Bis(4-hydroxycyclohexyl)propane (mixture of isomers) Maruzen H-BPA H-BPA 4-[1-(4-hydroxycyclohexyl)-1-methyl-ethyl]cyclohexanol 4-[2-(4-hydroxycyclohexyl)propan-2-yl]cyclohexan-1-ol 2,2-Bis(4-hydroxycyclohexyl) propane OR Hydrogenated bisphenol A(HBPA) 2,2-Bis(4-hydroxycyclohexyl)propane  p,p'-Dihydroxy-2,2-dicyclohexylpropane Perhydrobisphenol A 4,4'-(Propane-2,2-diyl)dicyclohexanol 4,4'-Isopropylidenedicyclohexanol (HBPA) 4,4'-(Dimethylmethylene)bis(cyclohexane-1-ol) 4,4'-Isopropylidenebiscyclohexanol 4,4'-Isopropylidenedicyclohexanol, mixture of isomers 90% 4'-Isopropylidenedicyclohexanol 4-[2-(4-hydroxycyclohexyl)propan-2-yl]-1-cyclohexanol HYDROGENATED BISPHENOL A 2,2-BIS(4-HYDROXYCYCLOHEXYL)PROPANE 4,4'-Isopropylidenedicyclohexanol 4,4'-Isopropylidenedicyclohexanol, mixture of isomers 4,4'-(Propane-2,2-diyl)dicyclohexanol HYDROGENATED BISPHENOL A (HBPA) 80-04-6 1980-04-06 80-40-6 CH32CC6H10OH2 pharm intermediate Alcohols Monomers Polymer Science Medical Intermediates