ChemicalBook >> CAS DataBase List >>GERMANIUM(IV) ETHOXIDE
GERMANIUM(IV) ETHOXIDE
- CAS No.
- 14165-55-0
- Chemical Name:
- GERMANIUM(IV) ETHOXIDE
- Synonyms
- GERMANIUM ETHYLATE;GERMANIUM ETHOXIDE;TETRAETHOXYGERMANE;TETRAETHYOXYGERMANE;Ethyl germanate(IV);Ethyl orthogermanate;TETRAETHOXYGERMANIUM;GermaniumEthylsulfate;Germanium(IV)-ethylat;TETRAMETHOXYGERMANIUM
- CBNumber:
- CB4683885
- Molecular Formula:
- C8H20GeO4
- Molecular Weight:
- 252.88
- MDL Number:
- MFCD00015121
- MOL File:
- 14165-55-0.mol
- MSDS File:
- SDS
Last updated:2024-07-05 16:40:08
| Melting point | -72°C |
|---|---|
| Boiling point | 185-6°C |
| Density | 1.14 g/mL at 25 °C(lit.) |
| refractive index |
n |
| Flash point | 121 °F |
| form | Liquid |
| Specific Gravity | 1.134 |
| color | Colorless |
| Water Solubility | Soluble in anhydrous alcohol and benzene. Hydrolyzes in water |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| Sensitive | Moisture Sensitive |
| BRN | 3661173 |
| CAS DataBase Reference | 14165-55-0(CAS DataBase Reference) |
| EPA Substance Registry System | Ethanol, germanium(4+) salt (14165-55-0) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H226-H315-H319-H335 | |||||||||
| Precautionary statements | P210-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | T,Xi | |||||||||
| Risk Statements | 10-36/37/38-23/24/25 | |||||||||
| Safety Statements | 26-36-45-36/37/39-27-16 | |||||||||
| RIDADR | UN 1993 3/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 2905190019 | |||||||||
| NFPA 704 |
|
GERMANIUM(IV) ETHOXIDE price More Price(23)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 339180 | Germanium(IV) ethoxide ≥99.95% trace metals basis | 14165-55-0 | 5g | $184 | 2024-03-01 | Buy |
| Sigma-Aldrich | 339180 | Germanium(IV) ethoxide ≥99.95% trace metals basis | 14165-55-0 | 25g | $614 | 2024-03-01 | Buy |
| Alfa Aesar | 014679 | Germanium(IV) ethoxide, 97% | 14165-55-0 | 5g | $132 | 2024-03-01 | Buy |
| Alfa Aesar | 014679 | Germanium(IV) ethoxide, 97% | 14165-55-0 | 1g | $38.6 | 2023-06-20 | Buy |
| Strem Chemicals | 93-3206 | Germanium(IV) ethoxide (99.99+%-Ge) PURATREM | 14165-55-0 | 1g | $45 | 2024-03-01 | Buy |
GERMANIUM(IV) ETHOXIDE Chemical Properties,Uses,Production
Chemical Properties
Water-clear liquid. B.p. 186°C. Hydrolyzes easily, yielding GeO2.
Uses
It is a sol-gel intermediate for optical fibers and photosensitive.
Preparation
A solution of 9.8 g. of metallic sodium in a considerable excess of absolute alcohol is prepared. A solution of 20 g. of GeCl4 in absolute ether is added with stirring and exclusion of moisture. The mixture is refluxed for several hours and then decanted from the NaCl which separates. The solid is washed with absolute ether. The washings are combined with the main solution and the solvent is then driven off in vacuum. Finally, the tetraethoxygermane is distilled. It is redistilled at atmospheric pressure.
Purification Methods
Distil it through a 10cm Vigreux column (p 11) under reduced pressure. Alternatively distil it through a Fenske glass helices (p 11) column fitted with a total condensation variable take-off stillhead. Fractionate it under reduced pressure using a reflux ratio of 10:1. [Johnson & Fritz J Am Chem Soc 75 718 1953, Bradley J Chem Soc 4916 1956, Beilstein 1 IV 1308.]
GERMANIUM(IV) ETHOXIDE Preparation Products And Raw materials
GERMANIUM(IV) ETHOXIDE Suppliers
Global( 73)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
| Xi'an MC Biotech, Co., Ltd. | 029-89275612 +8618991951683 | mcbio_sales@163.com | China | 2251 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 7724 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52849 | 58 |
| PT CHEM GROUP LIMITED | peter68@ptchemgroup.com | China | 35425 | 58 | |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 49979 | 58 |
| Shanghai Acmec Biochemical Technology Co., Ltd. | +undefined18621343501 | product@acmec-e.com | China | 33338 | 58 |
| SHANGHAI KEAN TECHNOLOGY CO., LTD. | +8613817748580 | cooperation@kean-chem.com | China | 40066 | 58 |
| Mainchem Co., Ltd. | +86-0592-6210733 | sale@mainchem.com | China | 32343 | 55 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
14165-55-0(GERMANIUM(IV) ETHOXIDE)Related Search:
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Germanium(IV) ethoxide, 99.95+% metals basis
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GERMANIUM(IV) ETHOXIDE ISO 9001：2015 REACH
Germanium(IV) ethoxide, 97%,
14165-55-0
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Catalysis and Inorganic Chemistry
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