ChemicalBook >> CAS DataBase List >>CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)

CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)

CAS No.
14871-41-1
Chemical Name:
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
Synonyms
IrCl(CO)(PPh3)2;vaska's catalyst;carbonylchlorobis(triphenylphosphine)iridium;iridium(I);chloroiridium;VASKA'S COMPLEX;Carbonylchloro bis(triphenylphosphine);Dicarbonyl (triphenylphosphine) ruthenium;carbonylchlorobis(triphenylphosphine)-iridiu;CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
CBNumber:
CB4709064
Molecular Formula:
C37H30ClIrOP2
Molecular Weight:
780.25
MDL Number:
MFCD00009590
MOL File:
14871-41-1.mol
Last updated:2023-06-08 17:06:35

CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Properties

Melting point 215°C
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in chloroform, toluene. Slightly soluble in acetone, alcohol
form crystal
color lemon yellow
λmax 385nm(lit.)
InChIKey KMVALWICXMGTQO-UHFFFAOYSA-M
CAS DataBase Reference 14871-41-1(CAS DataBase Reference)
FDA UNII J8AO572UZW
EPA Substance Registry System Iridium, carbonylchlorobis(triphenylphosphine)- (14871-41-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS06,GHS07
Signal word  Danger
Hazard statements  H301+H311+H331-H315-H319-H302-H312-H331
Precautionary statements  P280h-P304+P340-P311a-P501a-P261-P264-P270-P271-P280-P301+P310+P330-P302+P352+P312+P361+P364-P304+P340+P311-P305+P351+P338+P337+P313-P403+P233-P405-P501
Risk Statements  20/21/22
Safety Statements  22-24/25
RIDADR  UN2811
WGK Germany  3
TSCA  Yes
HS Code  2931.90.6000
HazardClass  6.1
PackingGroup  III
NFPA 704
0
2 0

CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) price More Price(41)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical C2252 Carbonylchlorobis(triphenylphosphine)iridium(I) >95.0%(T) 14871-41-1 1g $396 2024-03-01 Buy
TCI Chemical C2252 Carbonylchlorobis(triphenylphosphine)iridium(I) >95.0%(T) 14871-41-1 200mg $112 2024-03-01 Buy
Alfa Aesar 039413 Carbonylchlorobis(triphenylphosphine)iridium(I) 14871-41-1 0.25g $67.4 2023-06-20 Buy
Alfa Aesar 039413 Carbonylchlorobis(triphenylphosphine)iridium(I) 14871-41-1 1g $215 2023-06-20 Buy
Strem Chemicals 77-0300 Chlorocarbonylbis(triphenylphosphine)iridium(I), 99% VASKA'S COMPLEX 14871-41-1 250mg $55 2024-03-01 Buy
Product number Packaging Price Buy
C2252 1g $396 Buy
C2252 200mg $112 Buy
039413 0.25g $67.4 Buy
039413 1g $215 Buy
77-0300 250mg $55 Buy

CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Chemical Properties,Uses,Production

Reaction

  1. Catalyst for the intramolecular carbonylative [2+2+1] cycloaddition of allenynes.
  2. Catalyst for the selective hydrogenation of myrcene.
  3. Catalyst for silylation of ortho-functionalized aryl halides with hydrosilanes.
  4. Catalyst for synthesis of aldenamines from carboxamides by silane-reduction/dehydration under mild conditions.
  5. Hydrogen atom transfer catalyst for radical cyclizations.
  6. Complex for photocatalytic alkane dehydrogenation.
  7. Catalyst for chemoselective reductive nucleophilic addition to N-methoxyamides.
  8. Catalyst for chemoselective reductive alkynylation of tertiary amides.
Reactions of 14871-41-1_1
Reactions of 14871-41-1_2
Reactions of 14871-41-1_3

Chemical Properties

GREEN FINE CRYSTALLINE POWDER

Uses

Carbonylchlorobis(triphenylphosphine)iridium(I) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.

CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Preparation Products And Raw materials

Raw materials

Preparation Products

CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) Suppliers

Global( 124)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29881 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
Hubei Ipure Biology Co., Ltd
+8613367258412 ada@ipurechemical.com China 10319 58
Shanghai Bosheng Metal Materials Co. LTD
18601346310 CHINA 153 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
HONG KONG IPURE BIOLOGY CO.,LIMITED
86 18062405514 18062405514 ada@ipurechemical.com CHINA 3461 58
Xi'an MC Biotech, Co., Ltd.
029-89275612 +8618991951683 mcbio_sales@163.com China 2251 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-89586680 +86-18192503167 1026@dideu.com China 7724 58

View Lastest Price from CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
	CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) pictures 2022-09-24 CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
14871-41-1
US $0.00 / kg 1kg 99% 1000kg henan kanbei chemical co.,ltd
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) pictures 2019-07-06 CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
14871-41-1
US $1.00 / KG 1KG 99% Customized Career Henan Chemical Co
CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CHLORIDE BIS(TRIPHENYLPHOSPHINE)IRIDIUMCARBONYL CHLORIDE BIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) CARBONYL CHLORIDE IRIDIUM(I)BIS(TRIPHENYLPHOSPHINE)CARBONYL CHLORIDE CHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM (I) VASKA'S COMPLEX carbonylchlorobis(triphenylphosphine)-iridiu CARBONYLBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I ) CHLORIDE, 99.99% Chlorocarbonylbis(triphenylphosphine)iridium(I),99%VASKA'SCOMPLEX Bis-(triphenylphosphino)-iridium carbonyl chloride Chlorocarbonylbis(triphenylphosphine)iridium(I), Iridium(I)bis(triphenylphosphine)carbonyl chloride Carbonylchlorobis(triphenylphosphine)iridium(Ⅰ) Carbonylchloro bis(triphenylphosphine)iridium(I),99% Carbonylchloro bis(triphenylphosphine)iridiuM(I),98% Carbonylchloro bis(triphenylphosphine) iridium(I) Chlorocarbonylbis(triphenylphosphine)iridiuM(I) VASKA'S COMPLEX Dicarbonyl (triphenylphosphine) ruthenium Carbonylchlorobis(triphenylphosphine)iridium(I) > IRIDIUM, CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)- CARBONYLCHLOROBIS(TRIPHENYLPHOSPHINE)IRIDIUM(I) ISO 9001:2015 REACH carbonylchlorobis(triphenylphosphine)iridium vaska's catalyst IrCl(CO)(PPh3)2 chloroiridium 14871-41-1 IrClCOPC6H532 C6H53P2IrClCO C37H30ClIrOP2 IrClCOC6H53P2 C37H31ClIrOP2 Iridium Catalysis and Inorganic Chemistry Ir