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Benzenesulfonyl hydrazide

CAS No.
80-17-1
Chemical Name:
Benzenesulfonyl hydrazide
Synonyms
BSH;BENZENESULFONOHYDRAZIDE;Porofor;POROFOR BSH;Phenylsulfonylhydrazine;Phenylsulfonyl hydrazide;BENZENESULPHONYL HYDRAZIDE;chkhz9;ChKhZ 9;celogenbsh
CBNumber:
CB4711849
Molecular Formula:
C6H8N2O2S
Molecular Weight:
172.2
MDL Number:
MFCD00007583
MOL File:
80-17-1.mol
Last updated:2023-12-25 13:23:17

Benzenesulfonyl hydrazide Properties

Melting point 101-103 °C(lit.)
Boiling point 333.5±25.0 °C(Predicted)
Density 1.303 (estimate)
refractive index 1.6490 (estimate)
Flash point 110 °C
storage temp. Flammables area
solubility soluble in Methanol
pka 9.30±0.50(Predicted)
form solid
color White to Almost white
Merck 14,7598
BRN 640079
InChIKey VJRITMATACIYAF-UHFFFAOYSA-N
CAS DataBase Reference 80-17-1(CAS DataBase Reference)
NCI Dictionary of Cancer Terms BSH
FDA UNII AC8C87U2TA
NIST Chemistry Reference Benzenesulfonic acid, hydrazide(80-17-1)
EPA Substance Registry System Benzenesulfonic acid, hydrazide (80-17-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Danger
Hazard statements  H302-H242
Precautionary statements  P280a-P411a-P501a-P210-P220-P234-P264-P270-P280-P301+P312+P330-P403+P235-P420-P501
Hazard Codes  F
Risk Statements  11
Safety Statements  15-16-22-24/25
RIDADR  UN 3226 4.1
WGK Germany  3
RTECS  DB6888000
4.9-16
TSCA  Yes
HazardClass  4.1
PackingGroup  II
HS Code  29350090
Toxicity LDLo orl-rat: 50 mg/kg IPSTB3 3,93,76
NFPA 704
2
0 1

Benzenesulfonyl hydrazide price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B3809 Benzenesulfonyl hydrazide 98% 80-17-1 25g $185 2024-03-01 Buy
TCI Chemical B0038 Benzenesulfonyl Hydrazide >98.0%(T) 80-17-1 25g $27 2024-03-01 Buy
TCI Chemical B0038 Benzenesulfonyl Hydrazide >98.0%(T) 80-17-1 100g $71 2024-03-01 Buy
Alfa Aesar B23971 Benzenesulfonyl hydrazide, 98% 80-17-1 25g $46.65 2024-03-01 Buy
Alfa Aesar B23971 Benzenesulfonyl hydrazide, 98% 80-17-1 100g $140 2024-03-01 Buy
Product number Packaging Price Buy
B3809 25g $185 Buy
B0038 25g $27 Buy
B0038 100g $71 Buy
B23971 25g $46.65 Buy
B23971 100g $140 Buy

Benzenesulfonyl hydrazide Chemical Properties,Uses,Production

Chemical Properties

Benzenesulfonohydrazides,unlike the benzenesulfonamides, are thermally unstable. They decompose, when heated in water in some cases, to form sulfides, thiosulfonates, and nitrogen; for this reason they are used as blowing agents in the production of foams.

Chemical Properties

Benzenesulfonyl hydrazide is WHITE POWDER

Uses

Benzenesulfonyl hydrazide is used in making foam rubber and foam plastics.

Production Methods

Benzenesulfonyl hydrazides are produced by treating benzenesulfonyl chlorides with hydrazine in dioxane, alcohol, or water and in the presence of a second equivalent of hydrazineoranotherbase. They react with nitrous acid to form benzenesulfonyl azides according to the following equation:
ArSO2NHNH2 +HNO2→RSO2N3 +2H2O

General Description

Benzenesulfonyl hydrazide is a white to light-colored crystalline solid. Insoluble in water and denser than water. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Readily ignited by sparks or flames and burns vigorously. Used to make other chemicals.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Self-decomposition or self-ignition may be triggered by heat, chemical reaction, friction or impact. May be ignited by heat, sparks or flames.

Safety Profile

Poison by ingestion. A flammable solid. When heated to decomposition it emits toxic vapors of NOx and SOx.

98-09-9
80-17-1
Synthesis of Benzenesulfonyl hydrazide from Benzenesulfonyl chloride
Global( 188)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
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Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18777 58
Dalian Richfortune Chemicals Co., Ltd
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Henan Tianfu Chemical Co.,Ltd.
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career henan chemical co
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Hubei xin bonus chemical co. LTD
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Shandong chuangyingchemical Co., Ltd.
18853181302 sale@chuangyingchem.com CHINA 5906 58
Chongqing Chemdad Co., Ltd
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CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49374 58
Shouguang Nuomeng Chemical Co Ltd.
536-5119508 18363669993; export@nuomengchem.com China 44 58

View Lastest Price from Benzenesulfonyl hydrazide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Benzenesulfonyl hydrazide, BSH, Blowing Agent BSH pictures 2024-08-28 Benzenesulfonyl hydrazide, BSH, Blowing Agent BSH
80-17-1
US $6200.00 / T 1KG 98% 200 tons per month Shouguang Nuomeng Chemical Co Ltd.
Benzenesulfonyl hydrazide pictures 2023-12-26 Benzenesulfonyl hydrazide
80-17-1
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Benzenesulfonyl hydrazide pictures 2022-02-19 Benzenesulfonyl hydrazide
80-17-1
US $0.00 / KG 1KG 97.8% 100 tons Honest Joy Holdings Limited
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