METHYL 2-BROMO-2-BUTENOATE

CAS No.
17642-18-1
Chemical Name:
METHYL 2-BROMO-2-BUTENOATE
Synonyms
Einecs 241-627-1;METHYL A-BROMOCROTONATE;METHYL 2-BROMOCROTONATE;METHYL 2-BROMO-2-BUTENOATE;(Z)-Methyl 2-broMobut-2-enoate;2-Bromo-2-butenoic acid methyl ester;methyl 2-bromo-2-butenoate (cis+trans);2-Butenoic acid, 2-bromo-, methyl ester;Methyl 2-bromo-2-butenoate (cis+trans), >=95.0% (GC);METHYL 2-BROMOBUT-2-ENOATE (MIXTURE OF TRANS AND CIS)
CBNumber:
CB4715928
Molecular Formula:
C5H7BrO2
Molecular Weight:
179.01
MDL Number:
MFCD00042891
MOL File:
17642-18-1.mol
Last updated:2022-08-15 17:39:12

METHYL 2-BROMO-2-BUTENOATE Properties

Boiling point 178-182 °C (lit.)
Density 1.505 g/mL at 20 °C (lit.)
refractive index n20/D 1.486
Flash point 63 °C
storage temp. 2-8°C
BRN 1700999

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
8

METHYL 2-BROMO-2-BUTENOATE price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 16503 Methyl 2-bromo-2-butenoate (cis+trans), ≥95.0% (GC) 17642-18-1 5ml $239 2024-03-01 Buy
American Custom Chemicals Corporation HCH0014235 METHYL A-BROMOCROTONATE 95.00% 17642-18-1 5ML $861.17 2021-12-16 Buy
Crysdot CD13020308 Methyl2-bromobut-2-enoate 95+% 17642-18-1 5g $369 2021-12-16 Buy
Product number Packaging Price Buy
16503 5ml $239 Buy
HCH0014235 5ML $861.17 Buy
CD13020308 5g $369 Buy

METHYL 2-BROMO-2-BUTENOATE Chemical Properties,Uses,Production

General Description

Methyl 2-bromo-2-butenoate(Methyl (Z)-2-bromocrotonate) yields (S)-2-bromobutanoic acid by baker′s yeast fermentation. It undergoes biotransformation catalyzed by old yellow enzyme to yield methyl (S)-2-bromobutanoate, a key intermediate for the synthesis of chiral drugs. It is a biannelating reagent which participates in double Michael-additions.

METHYL 2-BROMO-2-BUTENOATE Preparation Products And Raw materials

Raw materials

Preparation Products

METHYL 2-BROMO-2-BUTENOATE Suppliers

Global( 27)Suppliers
Supplier Tel Email Country ProdList Advantage
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44688 61
Syntechem Co.,Ltd info@syntechem.com China 12984 57
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51456 80
SHANGHAI FDC-CHEMICAL CO.,LTD 021-61469567 13482353728 sales@fdc-chemical.com China 16510 58
Shanghai Changer Pharmaceutical Technology Co. Ltd. 15921595598 qd.yu@pharmachanger.com China 407 58
Henan Weituxi Chemical Technology Co., Ltd. 0371-63284658 18135795563 2885349392@qq.com China 10049 58
Zhenjiang Borun Bio-Technology Pharmaceutical Co., Ltd. 15862994627 2570984291@qq.com China 674 58
chemmole 400-168-9330 15013243073 597760450@qq.com China 2942 58
Bide Pharmatech Ltd. 400-1647117 13681763483 product02@bidepharm.com China 62075 58
METHYL 2-BROMO-2-BUTENOATE METHYL 2-BROMOCROTONATE METHYL A-BROMOCROTONATE methyl 2-bromo-2-butenoate (cis+trans) 2-Bromo-2-butenoic acid methyl ester Einecs 241-627-1 (Z)-Methyl 2-broMobut-2-enoate Methyl 2-bromo-2-butenoate (cis+trans), >=95.0% (GC) 2-Butenoic acid, 2-bromo-, methyl ester METHYL 2-BROMOBUT-2-ENOATE (MIXTURE OF TRANS AND CIS) 17642-18-1 CH3CHCBrCOOCH3 Building Blocks Carbonyl Compounds C2 to C5 Organic Building Blocks Esters