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Bis(2,4-pentanedionato-O,O')palladium(II)

CAS No.
14024-61-4
Chemical Name:
Bis(2,4-pentanedionato-O,O')palladium(II)
Synonyms
PALLADIUM(II) ACETYLACETONATE;PALLADIUM ACETYLACETONATE;BIS(ACETYLACETONATO)PALLADIUM(II);BIS(2,4-PENTANEDIONATO)PALLADIUM(II);ACETYLACETONE, PALLADIUM(II) DERIVATIVE;34.7%Pd;Umicore, 99%;Palladium acet;PALLADIUM-ACETYLACETONAT;Palladous acetylacetonate
CBNumber:
CB4751427
Molecular Formula:
C10H14O4Pd
Molecular Weight:
304.64
MDL Number:
MFCD00000025
MOL File:
14024-61-4.mol
MSDS File:
SDS
Last updated:2024-12-18 14:08:52

Bis(2,4-pentanedionato-O,O')palladium(II) Properties

Melting point 190 °C
vapor pressure 0Pa at 25℃
storage temp. Store below +30°C.
solubility Soluble in benzene and chloroform.
form Solution
color Yellow to orange
Specific Gravity 1.862
Water Solubility INSOLUBLE
Hydrolytic Sensitivity 4: no reaction with water under neutral conditions
BRN 4136188
InChI InChI=1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
InChIKey RJJXYEQOOACRKP-LNKPDPKZSA-M
SMILES O([Pd]O/C(/C)=C\C(=O)C)/C(/C)=C\C(=O)C
LogP 2.6 at 25℃
NIST Chemistry Reference Bis(acetylacetonato)palladium(14024-61-4)
EPA Substance Registry System Palladium, bis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-4-1)- (14024-61-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319
Precautionary statements  P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  36-36/37/38-22
Safety Statements  26-37/39
RIDADR  3181
WGK Germany  2
TSCA  Yes
HS Code  28439090
NFPA 704
3
2 0

Bis(2,4-pentanedionato-O,O')palladium(II) price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 209015 Palladium(II) acetylacetonate 99% 14024-61-4 1g $102 2024-03-01 Buy
Sigma-Aldrich 209015 Palladium(II) acetylacetonate 99% 14024-61-4 5g $410 2024-03-01 Buy
Sigma-Aldrich 8.07103 Palladium(II) acetylacetonate ≥98% (ICP) 14024-61-4 5G $312.65 2021-12-16 Buy
Sigma-Aldrich 8.07103 Palladium(II) acetylacetonate ≥98% (ICP) 14024-61-4 1g $77.51 2021-12-16 Buy
TCI Chemical B2018 Bis(2,4-pentanedionato)palladium(II) >98.0%(T) 14024-61-4 1g $187 2024-03-01 Buy
Product number Packaging Price Buy
209015 1g $102 Buy
209015 5g $410 Buy
8.07103 5G $312.65 Buy
8.07103 1g $77.51 Buy
B2018 1g $187 Buy

Bis(2,4-pentanedionato-O,O')palladium(II) Chemical Properties,Uses,Production

Chemical Properties

yellow orange needles

Uses

Palladium(II) Acetylacetonate is an active anticancer agent. Exhibits growth inhibitory effect more than cisplatin in several cancer cells and treatment with Palladium(II) Acetylacetonate inhibits H460 cells. Palladium(II) Acetylacetonate is a catalyst for various organic transformations.

Uses

Palladium(II) acetylacetonate (Pd(acac)2) was used in the following studies:

  • Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs).
  • Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides.
  • As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.

General Description

Palladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium.

Flammability and Explosibility

Highly flammable

Purification Methods

It can be recrystallised from *C6H6/pet ether and sublimes in vacuo. It is soluble in heptane, *C6H6 (1.2% at 20o, 2.2 at 40o), toluene (0.56% at 20o, 1.4% at 40o) and acetylacetone (1.2% at 20o, 0.05% at 40o). [West & Riley J Inorg Nucl Chem 5 295 1957/8, Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3676.]

Bis(2,4-pentanedionato-O,O')palladium(II) Preparation Products And Raw materials

Global( 331)Suppliers
Supplier Tel Email Country ProdList Advantage
SHANGHAI KEAN TECHNOLOGY CO., LTD.
+8613817748580 cooperation@kean-chem.com China 40066 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12837 58
Hebei Zhuanglai Chemical Trading Co.,Ltd
+8613343047651 admin@zlchemi.com China 3002 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18751 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
Hangzhou FandaChem Co.,Ltd.
+8615858145714 FandaChem@Gmail.com China 9145 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32957 60
AB PharmaTech,LLC
323-480-4688 sales@acrospharmatech.com United States 989 55
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29880 58
Jinan Carbotang Biotech Co.,Ltd.
+8615866703830 figo.gao@foxmail.com China 8497 58

View Lastest Price from Bis(2,4-pentanedionato-O,O')palladium(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bis(2,4-pentanedionato-O,O')palladium(II) pictures 2024-12-18 Bis(2,4-pentanedionato-O,O')palladium(II)
14024-61-4
US $10.00 / kg 1kg 99% 20ton Hebei Zhuanglai Chemical Trading Co.,Ltd
Bis(2,4-pentanedionato-O,O')palladium(II) pictures 2024-03-26 Bis(2,4-pentanedionato-O,O')palladium(II)
14024-61-4
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Bis(2,4-pentanedionato-O,O 2021-07-13 Bis(2,4-pentanedionato-O,O")palladium(II)
14024-61-4
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
ACETYLACETONE PALLADIUM(II) SALT Palladium acetylacetonate or Palladium(II)2,4-pentanedionate Bis(acetylacetonato)palladium(II) dec. 205 halide free source of Pd bis(2,4-pentanedionato-o,o')palladium(ii) Bis(2,4-pentanedionato-O,O')palladium(II),99% Bis(acetylacetonato) palladium(II) ,99% Palladium(II) acetylacetonate,Palladium(II) 2,4-pentanedionate Bis(acetylacetonato) palladiuM(II) ,99% [C% :39.06%-39.66%] Bis(acetylacetonato)palladium(Ⅱ) Bis(acetylaceto)palladium(II) Bis(acetylacetonato)palladium(II)~Bis(2,4-pentanedionato)palladium(II)~Palladium(II) 2,4-pentanedionate palladium (II) di(4-oxopent-2-en-2-oate) bis (acetylacetonate) palladium (II) 34.7%Pd Palladous acetylacetonate Palladium(II) acetylacetonate, 35% Pd PALLADIUM-ACETYLACETONAT PALLADIUM (II) ACETYLACETONATE 99% Palladium(II)acetylacetonate,99% Palladium, bis(2,4-pentanedionato-.kappa.O,.kappa.O)-, (SP-4-1)- PalladiuM(II) acetylacetonate, 35% Pd 1GR PalladiuM(II) acetylacetonate,98% Acetylacetone Palladium(II) Salt Palladium(II) Acetylacetonate Bis(acetylacetonato)palladiuM(Ⅱ), 35% Pd, Product of UMicore PALLADIUM(II) ACETYLACETONATE FOR SYNTHE Palladium(II) acetylacetonate Vetec(TM) reagent grade, 98% Palladium(Ⅱ) Acetylacetonate PALLADIUM(II) 2,4-ACETYLACETONATE PALLADIUM (II) 2,4-PENTANEDIONATE PALLADIUM 2,4-PENTANEDIONATE 4-pentanedionato-o,o’)-bis((sp-4-1)-palladiu Bis(2,4-pentanedionato)palladium Palladium bis(2,4-pentanedionate) Palladium bis(acetoacetonate) Palladium bis(acetylacetonate) Palladium diacetylacetonate Palladium, bis(2,4-pentanedionato)- Palladium, bis(2,4-pentanedionato-O,O')-, (SP-4-1)- Bis(acetylacetonato)palladium(II), 35% Pd Bis(acetylacetonato)palladium(II), 35% Pd, Product of Umicore Palladium acet Bis(dibenzylidenaceton)palladium Palladium(II) Acetylacetonate (Pd(acac)2) Palladium(II) acetylacetonate,98%,Pd>34.9% Palladium, bis(2,4-pentanedionato-kO,kO')-, (SP-4-1)- Bis(2,4-pentanedionato-O,O')palladium(II) ISO 9001:2015 REACH Umicore, 99% Palladium (II) Acetylacetonate (Pd(acac)2) extrapure, 34.7% Pd (E)-4-oxopent-2-en-2-olate ACETYLACETONE, PALLADIUM(II) DERIVATIVE BIS(2,4-PENTANEDIONATO)PALLADIUM(II) BIS(ACETYLACETONATO)PALLADIUM(II) PALLADIUM ACETYLACETONATE PALLADIUM(II) ACETYLACETONATE Bis(2,4-pentanedionato-O,O')palladium(II) bis[(E)-1-acetyl-2-hydroxy-prop-1-enyl]palladium Palladium(II) 2,4-pentanedionate [“Palladium acetylacetonate” 14024-61-4