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MERCUROUS BROMIDE

CAS No.
15385-58-7
Chemical Name:
MERCUROUS BROMIDE
Synonyms
Hg2Br2;Mercury(Ⅰ)bromide;MERCURY(I) BROMIDE;dimercury dibromide;mercury monobromide;Quecksilber(I)-bromid;mercurybromide(hg2br2);Mercury bromide (Hg2Br2);MERCURY(I) BROMIDE 99.9+%;MERCUROUS BROMIDE ISO 9001:2015 REACH
CBNumber:
CB4761354
Molecular Formula:
Br2Hg2
Molecular Weight:
560.99
MDL Number:
MFCD00053986
MOL File:
15385-58-7.mol
MSDS File:
SDS
Last updated:2024-05-31 15:13:05

MERCUROUS BROMIDE Properties

Melting point 445 °C(lit.)
Boiling point sublimes at 340–350℃ [HAW93]
Density 7.31 g/mL at 25 °C(lit.)
solubility insoluble in H2O, ethanol, ethyl ether
form white tetragonal crystals or powder
color white tetragonal crystals, crystalline or powder
Water Solubility g/L solution H2O: 3.9×10?5 (25°C) [KRU93]; insoluble alcohol, ether [MER06]; soluble in fuming HNO3, hot conc H2SO4 [HAW93]
Solubility Product Constant (Ksp) pKsp: 22.19
EPA Substance Registry System Mercury, dibromodi-, (Hg-Hg) (15385-58-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS08,GHS09,GHS06
Signal word  Danger
Hazard statements  H373-H300-H310-H330-H410
Precautionary statements  P260-P314-P501-P264-P270-P301+P310-P321-P330-P405-P501-P262-P264-P270-P280-P302+P350-P310-P322-P361-P363-P405-P501-P273-P391-P501-P260-P271-P284-P304+P340-P310-P320-P403+P233-P405-P501
Hazard Codes  T+,N
Risk Statements  26/27/28-33-50/53
Safety Statements  13-28-45-60-61
RIDADR  UN 1634 6.1/PG 2
WGK Germany  3
HazardClass  6.1(a)
PackingGroup  II

MERCUROUS BROMIDE Chemical Properties,Uses,Production

Description

Mercury(I) bromide or mercurous bromide, Hg2Br2, is a compound that changes color from white to yellow when heated and fluoresces a salmon color under UV light. It is used in acousto-optical devices. A very rare mineral is kuzminite, Hg2(Br,Cl)2. Mercury(I) bromide is formed through the oxidation of elemental mercury with elemental bromine or via the addition of sodium bromide to a solution of mercury(I) nitrate.

Chemical Properties

white, odorless, tasteless powder(s); tetr; sensitive to light (darkens); decomposed by hot HCl or alkali bromides; becomes yellow when heated, returns to white color when cooled; prepared by oxidation of Hg with Br2 or as a precipitate by addition of NaBr to HgNO3 solution [KIR81] [HAW93] [MER06]

General Description

White, odorless powder. Darkens on exposure to light. Sublimes at high temperatures.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

MERCUROUS BROMIDE is incompatible with the following: Acetylene, ammonia, chlorine dioxide, azides, calcium (amalgam formation), sodium carbide, lithium, rubidium, copper .

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.

MERCUROUS BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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Hg2Br2 Mercury bromide (Hg2Br2) mercurybromide(hg2br2) dimercury dibromide MERCURY(I) BROMIDE 99.9+% Mercury(Ⅰ)bromide Quecksilber(I)-bromid mercury monobromide MERCURY(I) BROMIDE MERCUROUS BROMIDE ISO 9001:2015 REACH 15385-58-7 HgBr