ChemicalBook >> CAS DataBase List >>Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)

Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)

CAS No.
220114-03-4
Chemical Name:
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)
Synonyms
(S) -DM-BINAP RUCL2 (S.S)-DPEN;RuCl2[(S)-xylbinap][(S,S)-dpen];RuCl?[(S)-(DM-BINAP)][(S,S)-DPEN];RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN];-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II),RuCl2[(;Dichloro[(S)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl][(S,S)-1,2-diphenylethylenediamine]ruthenium(II);Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II);Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II);DICHLORO{(S)-(-)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL}[(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II),RUCL2[(;Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-xylbinap][(S,S)-dpen]
CBNumber:
CB51181075
Molecular Formula:
C66H64Cl2N2P2Ru
Molecular Weight:
0
MDL Number:
MFCD09753030
MOL File:
220114-03-4.mol
Last updated:2023-06-08 17:06:35

Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) Properties

storage temp. 2-8°C
form Powder
color yellow
Sensitive air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
WGK Germany  3
HS Code  2843.90.0000

Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 693251 RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN] 220114-03-4 100mg $60.4 2023-06-20 Buy
Sigma-Aldrich 693251 RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN] 220114-03-4 50mg $31.5 2023-01-07 Buy
TCI Chemical R0134 RuCl2[(S)-xylbinap][(S,S)-dpen] 220114-03-4 200mg $65 2024-03-01 Buy
TCI Chemical R0134 RuCl2[(S)-xylbinap][(S,S)-dpen] 220114-03-4 1g $221 2024-03-01 Buy
Strem Chemicals 44-0224 Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-xylbinap][(S,S)-dpen] 220114-03-4 250mg $64 2024-03-01 Buy
Product number Packaging Price Buy
693251 100mg $60.4 Buy
693251 50mg $31.5 Buy
R0134 200mg $65 Buy
R0134 1g $221 Buy
44-0224 250mg $64 Buy

Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) Chemical Properties,Uses,Production

Reactions

  1. Sequential asymmetric hydrogenation reactions with solution or polymer-bound BINAP/Diamine complexes.
  2. Asymmetic hydrogenation of imines.
  3. Catalysts for deracemization of benzylic alcohols. 
Reactions of 220114-03-4

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 45)Suppliers
Supplier Tel Email Country ProdList Advantage
career henan chemical co
+86-0371-86658258 +8613203830695 sales@coreychem.com China 29882 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
changzhou huayang technology co., ltd
+8615250961469 2571773637@qq.com China 9725 58
Shaoxin Catsyn Co., Ltd.
+undefined-0575-82040869 +86-0575-82040869; sales@catsyn.com China 6114 58
Aladdin Scientific
+1-+1(833)-552-7181 sales@aladdinsci.com United States 57505 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24529 81
BeiJing Hwrk Chemicals Limted 0757-86329057 18934348241 sales4.gd@hwrkchemical.com China 14063 55
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44689 61

View Lastest Price from Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) pictures 2019-08-09 Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)
220114-03-4
US $1.00 / KG 1KG 98% 1kg,5kg,100kg Career Henan Chemical Co
RuCl2[(S)-(DM-BINAP)][(S,S)-DPEN] Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-xylbinap][(S,S)-dpen] Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-xylbinap][(S,S)-dpen] -binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II),RuCl2[( DICHLORO{(S)-(-)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL}[(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II),RUCL2[( Dichloro[(S)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl][(S,S)-1,2-diphenylethylenediamine]ruthenium(II) (S) -DM-BINAP RUCL2 (S.S)-DPEN RuCl?[(S)-(DM-BINAP)][(S,S)-DPEN] Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II), RuCl2[(S)-xylbinap][(S,S)-dpen] 220114-03-4 Ru