ZIRCONIUM IODIDE
- CAS No.
- 13986-26-0
- Chemical Name:
- ZIRCONIUM IODIDE
- Synonyms
- ZrI4;Einecs 237-780-9;ZIRCONIUM IODIDE;ZIRCONIUM(IV) IODIDE;ZIRCONIUM TETRAIODIDE;zirconiumiodide(zri4);Zirconium iodide (ZrI4);Zirconium(IV) tetraiodide;zirconium(4+),tetraiodide;ZIRCONIUM(IV) IODIDE: 99.5%
- CBNumber:
- CB5134410
- Molecular Formula:
- I4Zr
- Molecular Weight:
- 598.84
- MDL Number:
- MFCD00049641
- MOL File:
- 13986-26-0.mol
Melting point | 499°C |
---|---|
Boiling point | 431°C (estimate) |
Density | 4.85 |
storage temp. | under inert gas (nitrogen or Argon) at 2–8 °C |
solubility | very soluble in H2O |
form | powder |
color | Yellow |
Specific Gravity | 4.914 |
Water Solubility | Insoluble in water. |
Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
Sensitive | Air & Moisture Sensitive |
Merck | 14,10178 |
Exposure limits |
ACGIH: TWA 5 mg/m3; STEL 10 mg/m3 NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3 |
CAS DataBase Reference | 13986-26-0(CAS DataBase Reference) |
FDA UNII | H6NZC1810V |
EPA Substance Registry System | Zirconium iodide (ZrI4) (13986-26-0) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H314 | |||||||||
Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
Hazard Codes | C | |||||||||
Risk Statements | 34 | |||||||||
Safety Statements | 22-26-27-36/37/39-45 | |||||||||
RIDADR | UN 3260 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
TSCA | No | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | III | |||||||||
NFPA 704 |
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ZIRCONIUM IODIDE price More Price(5)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Alfa Aesar | 017400 | Zirconium(IV) iodide 99% | 13986-26-0 | 25g | $615 | 2023-06-20 | Buy |
Strem Chemicals | 93-4025 | Zirconium(IV) iodide (99.5%-Zr) | 13986-26-0 | 1g | $68 | 2024-03-01 | Buy |
Strem Chemicals | 93-4025 | Zirconium(IV) iodide (99.5%-Zr) | 13986-26-0 | 5g | $178 | 2024-03-01 | Buy |
American Custom Chemicals Corporation | ING0007364 | ZIRCONIUM(IV) IODIDE 95.00% | 13986-26-0 | 1G | $673.68 | 2021-12-16 | Buy |
American Custom Chemicals Corporation | ING0007364 | ZIRCONIUM(IV) IODIDE 95.00% | 13986-26-0 | 5G | $957.46 | 2021-12-16 | Buy |
ZIRCONIUM IODIDE Chemical Properties,Uses,Production
Description
Zirconium(IV) iodide, ZrI4, is the most readily available iodide of zirconium. It is an orange-colored solid that degrades in the presence of water. The compound was once renowned as an intermediate in the purification of zirconium metal. This compound is volatile, subliming as intact tetrahedral ZrI4 molecules.
Chemical Properties
orange crystal(s); fumes heavily in air; cub, a=1.179nm [KIR84] [MER06]
Uses
Used in the van Arkel-de Boer refining process.
Preparation
It is prepared by the direct reaction of powdered zirconium metal and iodine. Pyrolysis of zirconium(IV) iodide gas by contact of hot wire was the first industrial process for the commercial production of pure ductile metallic zirconium.
Structure and conformation
Like most binary metal halides, it has a polymeric structure. The compound exists as a polymer consisting of octahedral Zr(IV) centers, each with a pair of terminal iodide ligands and four doubly bridging iodide ligands. The Zr-I distances are 2.692 (terminal) and 3.030 A? .
ZIRCONIUM IODIDE Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52861 | 58 |
Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | 1026@dideu.com | China | 8672 | 58 |
PT CHEM GROUP LIMITED | peter68@ptchemgroup.com | China | 35426 | 58 | |
GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 50003 | 58 |
Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 57511 | 58 |
Mainchem Co., Ltd. | +86-0592-6210733 | sale@mainchem.com | China | 32360 | 55 |