(R)-(+)-Glycidol
- CAS No.
- 57044-25-4
- Chemical Name:
- (R)-(+)-Glycidol
- Synonyms
- (R)-Oxiran-2-ylMethanol;(R)-GLYCIDOL;(R)-Oxiranemethanol;EOS-60676;R-Glycidoe;(R)-(+)-GL;(+)-Glycidol;(R)-(+)-GLYCIDOL;(R)-GLYCIDOL,99%;(r)-oxiranemethano
- CBNumber:
- CB5205831
- Molecular Formula:
- C3H6O2
- Molecular Weight:
- 74.08
- MDL Number:
- MFCD00074873
- MOL File:
- 57044-25-4.mol
- MSDS File:
- SDS
Boiling point | 56-57 °C11 mm Hg(lit.) |
---|---|
Density | 1.116 g/mL at 20 °C(lit.) |
refractive index |
n |
Flash point | 178 °F |
storage temp. | -20°C |
Water Solubility | Completely miscible in water |
solubility | Chloroform (Slightly), DMSO (Slightly) |
pka | 14.62±0.10(Predicted) |
color | Colorless to Light yellow |
optical activity | [α]23/D +15°, neat |
BRN | 79782 |
Stability | Moisture Sensitive |
InChIKey | CTKINSOISVBQLD-GSVOUGTGSA-N |
CAS DataBase Reference | 57044-25-4(CAS DataBase Reference) |
NIST Chemistry Reference | Oxiranemethanol, (R)-(57044-25-4) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02,GHS05,GHS06,GHS07,GHS08 |
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Signal word | Danger | |||||||||
Hazard statements | H227-H315-H319-H335-H361-H370-H373-H242-H302-H312-H314-H331-H341-H350-H360F-H302+H312-H330 | |||||||||
Precautionary statements | P201-P280-P305+P351+P338-P310-P260-P284-P202-P210-P264-P270-P271-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P311-P305+P351+P338+P337+P313-P307+P311-P403+P233-P405-P501 | |||||||||
Hazard Codes | T,E | |||||||||
Risk Statements | 45-60-2-21/22-23-34-68-41-37/38 | |||||||||
Safety Statements | 53-45-36/37/39-26 | |||||||||
RIDADR | UN 2922 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | RR0508000 | |||||||||
F | 10-21 | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | Ⅲ | |||||||||
HS Code | 29109000 | |||||||||
NFPA 704 |
|
(R)-(+)-Glycidol price More Price(27)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 480819 | (R)-(+)-Glycidol 97%, optical purity ee: 98% (GLC) | 57044-25-4 | 1g | $50.1 | 2023-06-20 | Buy |
TCI Chemical | G0363 | (R)-(+)-Glycidol >98.0%(GC) | 57044-25-4 | 5g | $86 | 2024-03-01 | Buy |
TCI Chemical | G0363 | (R)-(+)-Glycidol >98.0%(GC) | 57044-25-4 | 25g | $291 | 2024-03-01 | Buy |
TRC | G615695 | (R)-(+)-Glycidol | 57044-25-4 | 10g | $215 | 2021-12-16 | Buy |
TRC | G615695 | (R)-(+)-Glycidol | 57044-25-4 | 5g | $135 | 2021-12-16 | Buy |
(R)-(+)-Glycidol Chemical Properties,Uses,Production
Chemical Properties
Colorless to light yellow liqui
Uses
(R)-(+)-Glycidol may be used in the following synthesis:
- heteroarylpropane-2,3-diols, useful for combinatorial oligomer synthesis
- enantiomerically pure (2S,3S)- and (2S,3R)-threoninol and -hydroxyphenylalaninol
- 2-amino-1,4-anhydro-pentitol and 3-amino-1,5-anhydro-4-deoxy-hexitol with the arabino configuration
- (S)-4-tosyloxymethyl-2-oxazolidinone, required for the synthesis of protected amino alcohol derivatives
- 1-(S)-[3-hydroxy-2-(phosphonomethoxy)propyl]cytosine [(S)-HPMPC]
- chiral building block used to construct an epoxyvinyl iodide intermediate in a synthesis of a furanocembrane, a marine natural product
Uses
(R)-(+)-Glycidol can be used to construct chiral building blocks of epoxyvinyl iodide intermediates in the synthesis of furanocembrane, a marine natural product.
Definition
ChEBI: (R)-glycidol is a glycidol. It is functionally related to a (R)-1,2-epoxypropane. It is an enantiomer of a (S)-glycidol.
General Description
Enantioselective esterification of (R)-(+)-glycidol with n-butyric acid in organic media using hybrid gel-entrapped lipase on Celite has been reported.
Purification Methods
[S(-)-isomer, § also available on polymer support, has b 49-50o/7mm, 66-67o/19mm, [ ] D -1 5o(neat)], [R(+)-isomer has b 56 -5 6 . 5o/11mm, d 4 1.117, n D 1.429, [ ] D +15o (neat)]. Purify glycidol by fractional distillation.
(R)-(+)-Glycidol Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29880 | 58 |
Shanghai Arbor Chemical Co., Ltd. | 021-60451682 | act@arborchemical.com | CHINA | 904 | 58 |
Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 8497 | 58 |
Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 17777 | 58 |
Changzhou Ditong Chemical Co.,Ltd | +86-0519-88299272 | info@edengenechem.com | China | 2158 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39894 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49374 | 58 |
View Lastest Price from (R)-(+)-Glycidol manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2021-07-02 | (R)-(+)-Glycidol
57044-25-4
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | ||
2019-08-06 | (R)-(+)-Glycidol
57044-25-4
|
US $1.00 / KG | 1KG | 95%-99% | 2000kg | Career Henan Chemical Co |
- (R)-(+)-Glycidol
57044-25-4
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
- (R)-(+)-Glycidol
57044-25-4
- US $1.00 / KG
- 95%-99%
- Career Henan Chemical Co
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